Right- and left-handedness of 21 symmetrical herringbone assemblies of benzene

Ichiro Hisaki; Toshiyuki Sasaki; Kazuaki Sakaguchi; Wen-Tzu Liu; Norimitsu Tohnai; Mikiji Miyata

doi:10.1039/C2CC17719F

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Right- and left-handedness of 2₁ symmetrical herringbone assemblies of benzene†

Ichiro Hisaki,*^a Toshiyuki Sasaki,^a Kazuaki Sakaguchi,^a Wen-Tzu Liu,^a Norimitsu Tohnai^a and Mikiji Miyata*^a

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* Corresponding authors

^a 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: hisaki@mls.eng.osaka-u.ac.jp, miyata@mls.eng.osaka-u.ac.jp
Fax: +81-6-6879-7404
Tel: +81-6-6879-7404

Abstract

A universal method to determine handedness of 2₁ helical assemblies composed of planar aromatic molecules is proposed and demonstrated by taking P2₁/c and Pbca crystals of benzene, the simplest aromatic molecule, as examples.

This article is part of the themed collection: Chirality

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Article information

DOI: https://doi.org/10.1039/C2CC17719F
Article type: Communication
Submitted: 09 Dec 2011
Accepted: 04 Jan 2012
First published: 10 Jan 2012

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Chem. Commun., 2012,48, 2219-2221

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Right- and left-handedness of 2₁ symmetrical herringbone assemblies of benzene

I. Hisaki, T. Sasaki, K. Sakaguchi, W. Liu, N. Tohnai and M. Miyata, Chem. Commun., 2012, 48, 2219 DOI: 10.1039/C2CC17719F

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