DOI: 10.1039/A605732B
(Paper)
Reference Section for: Chem. Commun., 1997, 139-140
Perfluorovinyl–metal derivatives: a new one-pot synthesis
(Note: The full text of this document is currently only available in the PDF Version )
Kulbinder K. Banger, Alan K. Brisdon and Arti Gupta
Abstract
The one-pot reaction of the CFC replacement 1,1,1,2-tetrafluoroethane (CF3CFH2, HFC-134a) with 2 equiv. of butyllithium in diethyl ether at -78 °C followed by the addition of main-group or transition-metal halides results in good yields of the corresponding metal–perfluorovinyl compounds of high purity.
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