Achieving stable lithium metal anodes via the synergy of electrostatic shielding and the high Li+ flux inorganic interphase

Jiangtao Yu, Xinyu Ma, Xiuyang Zou, Yin Hu, Mingchen Yang, Jinhua Yang, Shipeng Sun and Feng Yan

Energy Environ. Sci., 2024, 17, 4519
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Engineering the solid electrolyte interphase for enhancing high-rate cycling and temperature adaptability of lithium-ion batteries

Zhongming Wang, Zhiyuan He, Zhongsheng Wang, Kecheng Long, Jixu Yang, Shaozhen Huang, Zhibin Wu, Lin Mei and Libao Chen

Chem. Sci., 2025, 16, 3571
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Optimizing interface concentration and electric fields for enhanced lithium deposition behavior in lithium metal anodes

Jiaxiang Liu, Haiming Hua, Jie Lin, Yongliang Deng, Nanbiao Pei, Peng Zhang, Jin-Chao Dong, Jian-Feng Li and Jinbao Zhao

Energy Environ. Sci., 2024, 17, 5993
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Contriving a gel polymer electrolyte to drive quasi-solid-state high-voltage Li metal batteries at ultralow temperatures

Xuanfeng Chen, Chunhao Qin, Fulu Chu, Fangkun Li, Jun Liu and Feixiang Wu

Energy Environ. Sci., 2025, 18, 910
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Understanding and applying the donor number of electrolytes in lithium metal batteries

Pan Zhou, Yong Xiang and Kai Liu

Energy Environ. Sci., 2024, 17, 8057
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Concurrent electrode–electrolyte interfaces engineering via nano-Si3N4 additive for high-rate, high-voltage lithium metal batteries

Jinuk Kim, Dong Gyu Lee, Ju Hyun Lee, Saehun Kim, Cheol-Young Park, Jiyoon Lee, Hyeokjin Kwon, Hannah Cho, Jungyoon Lee, Donghyeok Son, Hee-Tak Kim, Nam-Soon Choi, Tae Kyung Lee and Jinwoo Lee

Energy Environ. Sci., 2025, 18, 3148
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An integrated dual-gradient host facilitates oriented bottom-up lithium growth in lithium metal anodes

Zhuzhu Du, Xin Chen, Ying Zhao, Yuhang Liu and Wei Ai

Nanoscale, 2024, 16, 18375
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Molecular design of electrolyte additives for high-voltage fast-charging lithium metal batteries

Yu Ou, Wenhui Hou, Da Zhu, Changjian Li, Pan Zhou, Xuan Song, Yingchun Xia, Yang Lu, Shuaishuai Yan, Hangyu Zhou, Qingbin Cao, Haiyu Zhou, Hao Liu, Xiao Ma, Zhi Liu, Hong Xu and Kai Liu

Energy Environ. Sci., 2025, 18, 1464
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Solvating lithium and tethering aluminium using di-coordination-strength anions for low-temperature lithium metal batteries

Jin-Xiu Chen, Jin-Hao Zhang, Xiao-Zhong Fan, Fang-Fang Wang, Wen Tang, Wei Xia, Yusheng Zhao and Long Kong

Energy Environ. Sci., 2024, 17, 4036
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Moderate solvation structures of lithium ions for high-voltage lithium metal batteries at −40 °C

Ying Wei, Han Wang, Xing Lin, Tianyu Wang, Yanming Cui, Yu Huang, Jiayi Yang, Te-Huan Liu, Yang Ren, Xiulin Fan, Henghui Xu and Yunhui Huang

Energy Environ. Sci., 2025, 18, 786
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“Pseudo‐Charge‐Transfer Complex” Electrolyte Enables 490 Wh Kg−1 Lithium Metal Battery Operated From −40 to 80 °C

Shengwei Dong, Lingfeng Shi, Yan Zhang, Shenglu Geng, Zhuomin Qiang, Biao Deng, Fei Sun, Hua Huo, Geping Yin and Shuaifeng Lou

Angewandte Chemie, 2025, 137
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Electrolyte Formulation with Improved Ion Desolvation and Diffusion Kinetics, and Superior Anti-Corrosion Properties for Ultrawide-Temperature Supercapacitors (–70∼100°C)

Yiheng Qi, Chuang Bao, Juan Qiu, Zhongkai Hu, Shuo Lu, Jianhua Yan, Kefa Cen, Zheng Bo and Huachao Yang

Energy Storage Materials, 2024, 72, 103782
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Tuning the Nucleophilicity of Anion in Lithium Salt to Enable an Anion‐Rich Solvation Sheath for Stable Lithium Metal Batteries

Pan Zhou, Yu Ou, Qingqing Feng, Yingchun Xia, Haiyu Zhou, Wen‐hui Hou, Xuan Song, Yang Lu, Shuaishuai Yan, Weili Zhang, Yun He and Kai Liu

Adv Funct Materials, 2025, 35
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A Bipolar Solvent Molecule Design for Wide‐Temperature High‐Voltage Lithium Metal Batteries

WuJie Yang, Jianfeng Cai, Chengrong Xu, Aoyuan Chen, Yigang Wang, Yu Shi, Ping He and Haoshen Zhou

Advanced Materials, 2025
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Electrolyte Design via Hydrogen Bonding Between Solvent and Non‐Solvating Cosolvent Enabling Stable Lithium Metal Batteries at −20°C

Chuncheng Yan, Houzhen Li, Xiaoru Zhao, Xinrui Ma, Hao Chen, Yuanhua Sang, Hong Liu and Shuhua Wang

Carbon Neutralization, 2025, 4
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Developing a lithiophilic, solvent-phobic dual-functionality film for dendrite-free Li metal anodes

Xiaochen Yang, Ben Chen, Junhui Li, Jiaqi Wang, Zhuzhu Du and Wei Ai

Chemical Engineering Journal, 2024, 500, 156845
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Single-Ion Polymer-in-Salt Electrolytes Enabling Percolating Ionic Nanoaggregates for Ambient-Temperature Solid-State Batteries

Huaijiao Wang, Peng Wen, Yixuan Liu, Shantao Han, Zexi Zhang, Yifei Xu, Mao Chen and Xinrong Lin

J. Am. Chem. Soc., 2025, 147, 14554
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Design Nicht‐Fluorierter, Schwach Koordinierender Elektrolyt‐ Lösungsmittel mit erhöhter Oxidativer Stabilität

Lennart Wichmann, Adil Aboobacker, Steffen Heuvel, Felix Pfeiffer, Robert‐Tobias Hinz, Frank Glorius, Isidora Cekic‐Laskovic, Diddo Diddens, Martin Winter and Gunther Brunklaus

Angewandte Chemie, 2025
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Inorganic-Dominated Interphase Enabled by Tuning Solvation Configuration for 4.8 V Lithium-Ion Batteries

Haoliang Wang, Yan Zhao, Lu Wang, Hao Zhang, Shiming Chen, Wenguang Zhao, Xiangming Yao, Yuxiang Huang, Aimin Cao, Yongli Song, Luyi Yang and Feng Pan

J. Phys. Chem. Lett., 2024, 15, 12234
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Lithium Batteries Operating at Wide Temperatures: Opportunities and Challenges

Qian Chen, Zhilin Yang, Pengbo Zhai, Wenlei Luo and Yongji Gong

Adv Funct Materials, 2025, 35
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Advanced Liquid Electrolyte Design for High‐Voltage and High‐Safety Lithium Metal Batteries

Junhua Zhou, Huimin Wang, Yongqiang Yang, Xinyan Li, Can Guo, Zhibo Li, Shujing Wen, Jiehua Cai, Zhaokun Wang, Yufei Zhang, Qiyao Huang and Zijian Zheng

Advanced Energy Materials, 2025
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Geometric Design of Interface Structures and Electrolyte Solvation Chemistry for Fast Charging Lithium‐Ion Batteries

Chaeeun Song, Seung Hee Han, Youngwoo Choi, Hong Rim Shin, Min Kyu Kim, Chaewon Gong, Dongyan Chen, Jong‐Won Lee, Seungbum Hong and Nam‐Soon Choi

Advanced Materials, 2025, 37
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Amphiphilic molecule-assisted perfluoro-alkanes electrolyte for low temperature lithium metal batteries

Jian Qin, Yali Zhao, Xianjiao Meng, Mengfan Wang, Zhiping Song, Xinping Ai and Hui Zhan

Chemical Engineering Journal, 2024, 496, 153818
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Using Acetone as a Monosolvent for Ultralow Temperature Supercapacitors at −70 °C

Yiheng Qi, Chuang Bao, Xuanchi Li, Jianhua Yan, Huachao Yang and Zheng Bo

ChemPlusChem, 2025, 90
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A Low‐Cost, Fluorine‐Free Localized Highly Concentrated Electrolyte Toward Ultra‐High Loading Lithium Metal Batteries

Feng Hai, Yikun Yi, Zichun Xiao, Jingyu Guo, Xin Gao, Wenting Chen, Weicheng Xue, Weibo Hua, Wei Tang and Mingtao Li

Advanced Energy Materials, 2024, 14
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Realizing Persistent Lithium Protection and Revival with Dissolution‐Equilibrium‐Driven Sustainable Additives Reservoir

Xiao‐Xi Luo, Shuang‐Jie Tan, Juan Zhang, Jun‐Chen Guo, Chao‐Hui Zhang, Yu‐Hao Wang, Wan‐Li Wang, Jian‐Song Wu, Xing‐Long Wu and Yu‐Guo Guo

Angewandte Chemie, 2025
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Reversing nitride/fluoride distribution in the solid electrolyte interphase enables a highly reversible lithium metal anode

Linlin Zheng, Ruilin Hou, Tianze Shi, Xinyi Sun, Aoyuan Chen, Haoshen Zhou and Shaohua Guo

Nano Energy, 2025, 138, 110849
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Electrolyte Engineering via Fluorinated Siloxane Solvent for Achieving High-Performance Lithium-Metal Batteries

Gaoxu Huang, Yaqi Liao, Honghao Liu, Xiaopan Jin, Mengjia Guan, Feng Yu, Bin Dai and Yongsheng Li

ACS Nano, 2024, 18, 15802
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Li-current collector interface in lithium metal batteries

Tian-Yu Wang, Dingyi Zhao, Keyue Liang and Yuzhang Li

Nano Res., 2024, 17, 8706
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Hybrid solvating electrolytes for practical sodium-metal batteries

Weiyin Chen, Jin-Sung Park, Choah Kwon, Christian O. Plaza-Rivera, Chia-Wei Hsu, Jason Khoi Phong, Landon James Kilgallon, Daniel Wang, Tao Dai, So Yeon Kim, Guanzhou Zhu, Yifan Gao, Zhichu Ren, Zhen Zhang, Hyojun Lim, Yang Shao-Horn, Jeremiah A. Johnson and Ju Li

Joule, 2025, 9, 101811
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Weak traction effect modulates anionic solvation transition for stable-cycling and fast-charging lithium metal batteries

Zhen Wang, Chunbo Su, Ruizhe Xu, Kun Li, Borui Yang, Ting Li, Kai Chen, Wang Xu, Jingze Chen, Fei Li, Baihai Li, Anjun Hu and Jianping Long

Energy Storage Materials, 2025, 75, 104105
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Side Reactions/Changes in Lithium‐Ion Batteries: Mechanisms and Strategies for Creating Safer and Better Batteries

Hao Du, Yadong Wang, Yuqiong Kang, Yun Zhao, Yao Tian, Xianshu Wang, Yihong Tan, Zheng Liang, John Wozny, Tao Li, Dongsheng Ren, Li Wang, Xiangming He, Peitao Xiao, Eryang Mao, Naser Tavajohi, Feiyu Kang and Baohua Li

Advanced Materials, 2024, 36
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Minimizing Solvent‐Coordination in Ether Electrolytes for Lithium Metal Batteries under Extreme Operating Conditions

Haipeng Zhu, Qiangfeng Zhang, Kefei Wang, Gang Zhou, Pei Huang, Zhao Chen, Libao Chen, Chunxiao Zhang and Weifeng Wei

Advanced Materials, 2025
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Design of Fluorine‐Free Weakly Coordinating Electrolyte Solvents with Enhanced Oxidative Stability

Lennart Wichmann, Adil Aboobacker, Steffen Heuvel, Felix Pfeiffer, Robert‐Tobias Hinz, Frank Glorius, Isidora Cekic‐Laskovic, Diddo Diddens, Martin Winter and Gunther Brunklaus

Angew Chem Int Ed, 2025
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Restructuring Electrolyte Solvation by a Partially and Weakly Solvating Cosolvent toward High-Performance Potassium-Ion Batteries

Weijie Chen, Dianwei Zhang, Hongwei Fu, Jinfan Li, Xinzhi Yu, Jiang Zhou and Bingan Lu

ACS Nano, 2024, 18, 12512
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Solvation Structure Engineering via Inorganic–Organic Composite Layer for Corrosion‐Resistant Lithium Metal Anodes in High‐Concentration Electrolyte

Youngil Roh, Hyeokjin Kwon, Jaewon Baek, Changhoon Park, Seongyeong Kim, Kahee Hwang, A Reum Ha, Seongmin Ha, Jongchan Song and Hee‐Tak Kim

Advanced Energy Materials, 2025, 15
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Interface Engineered Electrolyte Design Strategy for Ultralong‐Cycle Solid‐State Lithium Batteries Over Wide Temperature Range

Yunpeng Qu, Chang Su, Lin Wang, Borui Li, Wanyuan Jiang, Runyang Li, Mengfan Pei, Wenkai Song, Shuo Zhuo, Xin Jin, Dongming Liu, Xigao Jian and Fangyuan Hu

Angewandte Chemie, 2025, 137
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Weakly Solvating Electrolytes for Lithium and Post‐Lithium Rechargeable Batteries: Progress and Outlook

Xue Li, Fei Luo, Naigen Zhou, Henry Adenusi, Shan Fang, Fanglin Wu and Stefano Passerini

Advanced Energy Materials, 2025, 15
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Unlocking fast‐charging capabilities of lithium‐ion batteries through liquid electrolyte engineering

Chaeeun Song, Seung Hee Han, Hyeongyu Moon and Nam‐Soon Choi

EcoMat, 2024, 6
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Enhancing Cycling Stability of Lithium Metal Batteries by a Bifunctional Fluorinated Ether

Thanh‐Nhan Tran, Xia Cao, Yaobin Xu, Peiyuan Gao, Hui Zhou, Fenghua Guo, Kee Sung Han, Dianying Liu, Phung ML Le, J. Mark Weller, Mark H. Engelhard, Chongmin Wang, M. Stanley Whittingham, Wu Xu and Ji‐Guang Zhang

Adv Funct Materials, 2024, 34
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An Amphiphilic Molecule Induced Anion‐Enrichment Interface for Next‐Generation Lithium Metal Batteries

Sheng Liu, Yu Yan, Ruixin Zheng, Guilei Tian, Xinxiang Wang and Chaozhu Shu

Small, 2025, 21
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Succinonitrile‐Rich Electrolyte Solvation Structure Enables Wide‐Temperature‐Range Operation of Lithium‐Metal Batteries

Boguen Kim, Saehun Kim, Dong Gyu Lee, Donghyun Lee, Junsu Son, Hyeonseok Seong, Bumjoon J. Kim, Tae Kyung Lee and Nam‐Soon Choi

Small Methods, 2025
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“Pseudo‐Charge‐Transfer Complex” Electrolyte Enables 490 Wh Kg−1 Lithium Metal Battery Operated From −40 to 80 °C

Shengwei Dong, Lingfeng Shi, Yan Zhang, Shenglu Geng, Zhuomin Qiang, Biao Deng, Fei Sun, Hua Huo, Geping Yin and Shuaifeng Lou

Angew Chem Int Ed, 2025, 64
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Research progress on wide-temperature-range liquid electrolytes for lithium-ion batteries

Xuerui Yang, Puyan Li, Chuanzhu Guo, Wen Yang, Naigen Zhou, Xiaowei Huang and Yong Yang

Journal of Power Sources, 2024, 624, 235563
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A review of recent developments in the design of electrolytes and solid electrolyte interphase for lithium metal batteries

Hyeonmuk Kang, Heechan Kang, Mikyeong Lyu and EunAe Cho

EcoMat, 2024, 6
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Advancing lithium metal electrode beyond 99.9% coulombic efficiency via super-saturated electrolyte with compressed solvation structure

Wujie Yang, Aoyuan Chen, Ping He and Haoshen Zhou

Nat Commun, 2025, 16
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Anion/Cation Solvation Engineering for a Ternary Low‐Concentration Electrolyte toward High‐Voltage and Long‐Life Sodium‐Ion Batteries

Xinyu Wang, Cheng Yang, Lingbo Yao, Yichao Wang, Ning Jiang and Yu Liu

Adv Funct Materials, 2024, 34
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Regulating Electrolyte Solvation Structures via Diluent‐Solvent Interactions for Safe High‐Voltage Lithium Metal Batteries

Yuqi Liu, Jin Li, Xiaolan Deng, Shang‐Sen Chi, Jun Wang, Huipeng Zeng, Yidong Jiang, Tingting Li, Zhongbo Liu, Hui Wang, Guangzhao Zhang, Yonghong Deng and Chaoyang Wang

Small, 2024, 20
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Realizing Persistent Lithium Protection and Revival with Dissolution‐Equilibrium‐Driven Sustainable Additives Reservoir

Xiao‐Xi Luo, Shuang‐Jie Tan, Juan Zhang, Jun‐Chen Guo, Chao‐Hui Zhang, Yu‐Hao Wang, Wan‐Li Wang, Jian‐Song Wu, Xing‐Long Wu and Yu‐Guo Guo

Angew Chem Int Ed, 2025
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In Situ Polymerized Localized High‐Concentration Electrolytes for Ultrahigh‐Rate Sodium Metal Batteries

Xue Wang, Yuzhou Bai, Zhuoran Lv, Yuan Liu, Wujie Dong, Hui Bi and Fuqiang Huang

Advanced Energy Materials, 2025, 15
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Long‐Life High‐Voltage Sodium‐Ion Batteries Enabled by Electrolytes with Cooperative Na+‐Solvation

Yumei Liu, Yongqing Gong, Ke Chen, Lujun Zhu, Yun An, Kenneth I. Ozoemena, Weibo Hua, Menghao Yang and Quanquan Pang

Adv Funct Materials, 2024, 34
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Electrolyte Chemistry Modulation Toward High‐Performance and Ultralow‐Temperature Silicon Anode

Yaozong Yang, Zhaolin Li, Min Zhang, Jie Wang, Yue Wang, Jingyi Qiu and Hailei Zhao

Advanced Materials, 2025, 37
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Enhancing low-temperature electrolyte performance through intermittent discharge for improved LiODFB additive film formation

Li-Juan Zhang, Jin-Zuo He, Xiao Yan, Lu-Fang Luo, Hao-Dong Qiu, Jian-Hong Peng, Qing-Qing Ma and Ning-Shuang Zhang

Journal of Electroanalytical Chemistry, 2024, 957, 118124
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Janus-structured graphene scaffold for bottom-up lithium deposition: A progressive gradient approach

Zhuzhu Du, Xin Chen, Ying Zhao, Yuhang Liu and Wei Ai

Applied Materials Today, 2024, 40, 102421
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Interface Engineered Electrolyte Design Strategy for Ultralong‐Cycle Solid‐State Lithium Batteries Over Wide Temperature Range

Yunpeng Qu, Chang Su, Lin Wang, Borui Li, Wanyuan Jiang, Runyang Li, Mengfan Pei, Wenkai Song, Shuo Zhuo, Xin Jin, Dongming Liu, Xigao Jian and Fangyuan Hu

Angew Chem Int Ed, 2025, 64
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Gibbs Free Energy Regulation to Decrease Desolvation Barrier for Ultralow‐Temperature Lithium Metal Batteries at −40°C

Ke‐Feng Ren, Yun‐Fei Du, Jia‐Xin Guo, Zhong‐Yu Li, Zhen‐Hui Luo, Xin Sun, En‐Hao Zhang, Cong Guo, Weizhai Bao, Feng Yu, Xin Shen, He Liu, Xin‐Bing Cheng and Jingfa Li

Small, 2025
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Anion-diluent synergistic strategy for improved interfacial stability in lithium metal batteries

Xinjing Huang, Xiaozhi Jiang, Chenyang Shi, Mengran Wang, Yangen Zhou, Bo Hong, Jie Li and Yanqing Lai

Energy Storage Materials, 2025, 78, 104239
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Decreased Electrically and Increased Ionically Conducting Scaffolds for Long‐Life, High‐Rate and Deep‐Capacity Lithium‐Metal Anodes

Chuanfa Li, Jiaqi Wang, Qian Ye, Pengzhou Li, Kun Zhang, Jiaxin Li, Yanan Zhang, Lei Ye, Tianbing Song, Yue Gao, Bingjie Wang and Huisheng Peng

Small, 2024, 20
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Unveiling degradation mechanisms of anode-free Li-metal batteries

Jeong-A. Lee, Haneul Kang, Saehun Kim, Kyungho Lee, Jeong Hwan Byun, Eunji Kwon, Samuel Seo, Kyuju Kwak, Kyoung Han Ryu and Nam-Soon Choi

Energy Storage Materials, 2024, 73, 103826
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Solvation chemistry in liquid electrolytes for rechargeable lithium batteries at low temperatures

Houzhen Li, Chuncheng Yan and Shuhua Wang

EcoEnergy, 2025, 3, 387
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Strong association dual lithium salts for ether-based electrolyte enable 4.5 V high-voltage lithium metal battery

Lipu Sun, Nan Chen, Yifan Li, Jianing Tian, Binbin Yang, Ziyi Chen, Nuo Chen, Feng Wu, Yuejiao Li and Renjie Chen

Energy Storage Materials, 2025, 78, 104264
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Regulating interfacial chemistry of layered lithium-rich oxide by weakly solvating electrolyte

Huinan Yu, Yanru Yang, Runjing Xu, Jiayun Zhang, Jinyu Yang, Jiafeng Ruan, Fei Zhang, Yang Liu, Dalin Sun and Fei Wang

Nano Energy, 2025, 138, 110850
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High-Voltage and Ultralow-Temperature Lithium Metal Batteries Achieved by Methyl Acetate-Based Locally High-Concentration Electrolyte

Song Gao, Liying Wang, Xijia Yang, Yue Yang, Yang Gao, Xiaohan Zhang, Xuesong Li and Wei Lü

ACS Appl. Mater. Interfaces, 2025, 17, 33998
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Engineering multifunctional conductive carbon-based cathode additives to stabilize high-performance all-solid-state lithium metal batteries

Ya Chen, Zhifeng Xia, Ling Huang, Lifeng Cui, Xin Gao, Meixuan Niu, Xiao Chen, Deli Zhou, Ziyang Guo, Tengfei Hu, Xiaodong Chen, Ortal Breuer, Miryam Fayena-Greenstein, Duu-Jong Lee, Doron Aurbach and Guoxiu Wang

Materials Today, 2025
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The challenges and solutions for low-temperature lithium metal batteries: Present and future

Qimeng Sheng, Yiyu Huang, Qingyue Han, Hongyan Li, Xinyong Tao, Ouwei Sheng and Chengbin Jin

Energy Storage Materials, 2024, 73, 103783
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