Catalytic H/D exchange of (hetero)arenes with early–late polyhydride heterobimetallic complexes: impact of transition metal pairs

Abdelhak Lachguar, Till Neumann, Andrey V. Pichugov, Erwann Jeanneau, Laurent Veyre, Chloé Thieuleux and Clément Camp

Dalton Trans., 2025, 54, 3804
DOI: 10.1039/D4DT03171G

Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Z. Ye, Iker Del Rosal, Sheridon N. Kelly, I. Joseph Brackbill, Laurent Maron, Clément Camp and John Arnold

Chem. Sci., 2024, 15, 9784
DOI: 10.1039/D4SC02380C

Bimetallic Al–M complexes derived from low-valent aluminium sources (M = s-/p-block metal)

Martyn P. Coles

Chem. Commun., 2025, 61, 15125
DOI: 10.1039/D5CC03764F

CO2 cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Abdelhak Lachguar, Christopher Z. Ye, Sheridon N. Kelly, Erwann Jeanneau, Iker Del Rosal, Laurent Maron, Laurent Veyre, Chloé Thieuleux, John Arnold and Clément Camp

Chem. Commun., 2024, 60, 7878
DOI: 10.1039/D4CC02207F

Visible-light driven H2 reductive elimination unlocks reactivity in polyhydrido niobium iridium clusters

Zachary Dubrawski, Samy Aïssiou, Erwann Jeanneau, Chloé Thieuleux and Clément Camp

Dalton Trans., 2026, 55, 620
DOI: 10.1039/D5DT02432C

PuCl3{CoCp[OP(OEt)2]3}: transuranic elements entering the field of heterometallic molecular chemistry

Thomas E. Shaw, Zachary R. Jones, Sara L. Adelman, Nickolas H. Anderson, Eric G. Bowes, Eric D. Bauer, David Dan, Jan Klouda, Karah E. Knope, Stosh A. Kozimor, Molly M. MacInnes, Veronika Mocko, Francisca R. Rocha, Harrison D. Root, Benjamin W. Stein, Joe D. Thompson and Jennifer N. Wacker

Chem. Sci., 2024, 15, 12754
DOI: 10.1039/D4SC01767F

Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations

Zachary Dubrawski, Iker Del Rosal, Erwann Jeanneau, Laurent Maron, Chloé Thieuleux and Clément Camp

Chem. Sci., 2025, 16, 14564
DOI: 10.1039/D5SC03465E

Hydrogenation Reactions with Heterobimetallic Complexes

Preshit C. Abhyankar and Christine M. Thomas

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202416100

Effect of Ti-doping on the dimer transition in Lithium Ruthenate

Sheetal Jain, Zhengbang Zhou, Ezekiel Horsley, Christopher J. S. Heath, Mohsen Shakouri, Qunfeng Xiao, Ning Chen, Weifeng Chen, Graham King and Young-June Kim

Phys. Rev. Materials, 2025, 9
DOI: 10.1103/9hvr-3yz5

C(sp2)─H Bond Activation with a Heterometallic Nickel–Aluminium Complex

Joseph A. Zurakowski, Benedek Stadler, Marcus W. Drover and Mark R. Crimmin

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202512684

Hydrogenation Reactions with Heterobimetallic Complexes

Preshit C. Abhyankar and Christine M. Thomas

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202416100

Synthesis of Perdeuterated Pentane and THF Under Mild Conditions by Silica‐Supported Ta/M (M = Co, Ir) Heterobimetallic Catalysts

Andrey V. Pichugov, Abdelhak Lachguar, Vincent Maurel, Serge Gambarelli, Jean‐Marie Mouesca, Laurent Veyre, Chloé Thieuleux and Clément Camp

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.202522721

Synthesis of Quinoline-Based Pt–Sb Complexes with L- or Z-Type Interaction: Ligand-Controlled Redox via Anion Transfer

Christopher K. Webber, Fanji Kong, Jugal Kumawat, Jyothish Joy, Erica K. Richardson, Paolo Siano, Diane A. Dickie, Daniel H. Ess and T. Brent Gunnoe

Organometallics, 2024, 43, 1789
DOI: 10.1021/acs.organomet.4c00221

Highly Selective and Efficient Perdeuteration of n‐Pentane via H/D Exchange Catalyzed by a Silica‐Supported Hafnium‐Iridium Bimetallic Complex

Andrey V. Pichugov, Léon Escomel, Sébastien Lassalle, Julien Petit, Ribal Jabbour, David Gajan, Laurent Veyre, Emiliano Fonda, Anne Lesage, Chloé Thieuleux and Clément Camp

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202400992

Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates

Thomas X. Gentner, Gerd M. Ballmann, Sumanta Banerjee, Alan R. Kennedy, Stuart D. Robertson and Robert E. Mulvey

Organometallics, 2024, 43, 1393
DOI: 10.1021/acs.organomet.4c00190

Snapshots of Cooperative Trimetallic Alkene Hydrogenation

Till L. Kalkuhl, Israel Fernández and Terrance J. Hadlington

J. Am. Chem. Soc., 2025, 147, 46373
DOI: 10.1021/jacs.5c15492

Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Christopher Z. Ye, Iker Del Rosal, Sheridon N. Kelly, Erik T. Ouellette, Laurent Maron, Clément Camp and John Arnold

Inorg. Chem., 2024, 63, 21167
DOI: 10.1021/acs.inorgchem.4c03449

Synthesis of Perdeuterated Pentane and THF Under Mild Conditions by Silica‐Supported Ta/M (M = Co, Ir) Heterobimetallic Catalysts

Andrey V. Pichugov, Abdelhak Lachguar, Vincent Maurel, Serge Gambarelli, Jean‐Marie Mouesca, Laurent Veyre, Chloé Thieuleux and Clément Camp

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.202522721

Isolobal Cationic Iridium Dihydride and Dizinc Complexes: A Dual Role for the ZnR Ligand Enhances H2 Activation

Amber M. Walsh, Lia Sotorrios, Rebecca G. Cameron, Anne-Frédérique Pécharman, Barbara Procacci, John P. Lowe, Stuart A. Macgregor, Mary F. Mahon, Neil T. Hunt and Michael K. Whittlesey

Inorg. Chem., 2024, 63, 22944
DOI: 10.1021/acs.inorgchem.4c04058

Bimetallic H2 Addition and Intramolecular Caryl–H Activation Mediated by an Iron–Zinc Hydride

Rui Sun, Yang Jiang, Hao-Ran Chen, Xuebin Jiang, Yu-Chen Cao, Shengfa Ye, Rong-Zhen Liao, Chen-Ho Tung and Wenguang Wang

Inorg. Chem., 2024, 63, 6082
DOI: 10.1021/acs.inorgchem.4c00454

1,4-Dialumination of benzene by sodium and potassium aluminyls

Andrea O’Reilly, Andrew M.S. Booth, Claire L. McMullin, J. Robin Fulton and Martyn P. Coles

Polyhedron, 2024, 264, 117226
DOI: 10.1016/j.poly.2024.117226

Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals

Till Neumann, Iker Del Rosal, Laurent Maron, Erwann Jeanneau, Vincent Maurel, Serge Gambarelli, Jean-Marie Mouesca, Chloé Thieuleux and Clément Camp

Inorg. Chem., 2025, 64, 21353
DOI: 10.1021/acs.inorgchem.5c02380

π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO2 to Ketenyl Transformation

Abdelhak Lachguar, Iker Del Rosal, Laurent Maron, Erwann Jeanneau, Laurent Veyre, Chloé Thieuleux and Clément Camp

J. Am. Chem. Soc., 2024, 146, 18306
DOI: 10.1021/jacs.4c02172

Mechanistic Studies of Alkyl Chloride Acetoxylation by Pt–Sb Complexes

Christopher K. Webber, Jugal Kumawat, Fanji Kong, Diane A. Dickie, Daniel H. Ess and T. Brent Gunnoe

Organometallics, 2025, 44, 617
DOI: 10.1021/acs.organomet.4c00399

Alkane Elimination Preparation of Heterobimetallic MoAl Tetranuclear and Binuclear Complexes Promoting THF Ring Opening

Léon Escomel, Erwann Jeanneau, Chloé Thieuleux and Clément Camp

Inorganics, 2024, 12, 72
DOI: 10.3390/inorganics12030072

Highly Selective and Efficient Perdeuteration of n‐Pentane via H/D Exchange Catalyzed by a Silica‐Supported Hafnium‐Iridium Bimetallic Complex

Andrey V. Pichugov, Léon Escomel, Sébastien Lassalle, Julien Petit, Ribal Jabbour, David Gajan, Laurent Veyre, Emiliano Fonda, Anne Lesage, Chloé Thieuleux and Clément Camp

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202400992

C(sp2)─H Bond Activation with a Heterometallic Nickel–Aluminium Complex

Joseph A. Zurakowski, Benedek Stadler, Marcus W. Drover and Mark R. Crimmin

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202512684