Recent progress in electrochemical rearrangement reactions

Zhaojiang Shi, Chao-Yan Wen, Li-Xue Yang, Jianan Li and Xiaoxia Sun

Org. Chem. Front., 2025, 12, 2499
DOI: 10.1039/D4QO02437K

Photo-induced difluoroalkylation/cyclization of alkyne ketones: a novel strategy to access difluoroalkyl thiofavones

Shengjie Song, Can Luo, Guan Wang, Jingjing Guo, Zhi Chen and Jianjun Li

Chem. Commun., 2024, 60, 11323
DOI: 10.1039/D4CC03843F

Photoredox-catalyzed three-component carbotrifluoromethylation of alkenes via radical–radical cross-coupling

Lin Tang, Ge Lv, Taijun Wu, Lufang Zhang, Xiaoyu Wang, Fengjuan Jia, Qiuju Zhou and Guodong Zou

Org. Chem. Front., 2024, 11, 4708
DOI: 10.1039/D4QO00799A

Photoinduced difunctionalizations of unactivated olefins enabled by ligand-to-iron charge transfer and functional group migration strategies

Mengqi Luo, Shibo Zhu, Jiawen Yin, Chao Yang, Lin Guo and Wujiong Xia

Org. Chem. Front., 2024, 11, 4748
DOI: 10.1039/D4QO01025F

Organic electrochemical reactions of inorganic compounds

Jiangfei Chen, Juyue Yang, Dayun Huang and Ming Yuan

Org. Biomol. Chem., 2025, 23, 6490
DOI: 10.1039/D5OB00777A

Recent advances in the application of Langlois’ reagent in olefin difunctionalization

Jiabin Shen, Lin Li, Jun Xu, Chao Shen and Pengfei Zhang

Org. Biomol. Chem., 2023, 21, 2046
DOI: 10.1039/D2OB01875F

Electrochemical oxidative CF3 radical-induced lactonization and etherification of terminal and internal alkenes

Riccardo Grigolato, Tommaso Fantoni, Giuseppe Autuori, Matteo Lattanzi, Lucia Ferrazzano, Walter Cabri and Alessandra Tolomelli

RSC Adv., 2025, 15, 15302
DOI: 10.1039/D5RA01852H

Electrochemical synthesis of β-difluoromethylamide compounds by N-benzenesulfonylacrylamide with difluorine reagents

Zhi-Long Lei, Zong-Cang Ding, Shu-Hui Li, Fei-Hu Cui, Hai-Tao Tang and Ying-Ming Pan

Chem. Commun., 2024, 60, 7614
DOI: 10.1039/D4CC02543A

Silver-catalyzed pyrazole migration and cycloaddition reaction of diazo pyrazoleamides with ketimines

Maoqing Shi, Gejun Niu, Tianyuan Zhang, Aimin Xu, Rimei Zheng, Abdulla Yusuf, Taoda Shi, Wenhao Hu and Yu Qian

Chem. Commun., 2023, 59, 10311
DOI: 10.1039/D3CC03253A

Intramolecular trapping of spiro radicals to produce unusual cyclization products from usual migration substrates

Jingming Zhang, Chengkou Liu, Yaqi Qiao, Minghui Wei, Wenjing Guan, Ziren Mao, Hong Qin, Zheng Fang and Kai Guo

Chem. Sci., 2023, 14, 2461
DOI: 10.1039/D2SC05768A

The merger of electro-reduction and hydrogen bonding activation for a radical Smiles rearrangement

Liyuan Lan, Kun Xu and Chengchu Zeng

Chem. Sci., 2024, 15, 13459
DOI: 10.1039/D4SC02821J

Regioselective electrochemical cascade C–H sulfonylation–bromination of indolizines to access difunctionalized indolizines

Wenxuan Jiang, Xiang Liu, Chuanying Zhu, Meiyi Chen, Weidan Li and Hua Cao

Org. Chem. Front., 2024, 11, 2306
DOI: 10.1039/D4QO00035H

Photoinduced Asymmetric Alkene Aminohetarylation with Chiral Sulfoximine Reagents

Zhu Cao, Yuqian Sun, Yasu Chen and Chen Zhu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202408177

Photocatalytic Cyclization Cascades by Radical Relay toward Pyrrolo[1,2-a]indoles: Synthesis, Mechanism, and Application

Chen He, Qi Wang, Xiaoyang Zhou, Lin Yi, Zhiqiang Zhang, Chun Zhang, Haijiao Xie, Qitong Huang, Guanyinsheng Qiu and Min Yang

J. Org. Chem., 2024, 89, 3509
DOI: 10.1021/acs.joc.3c02959

Vicinal Difunctionalization of Unactivated Alkenes Through Radical Addition/Remote (Hetero)Aryl Migration Cascade

Sébastien Meyer and Aurélie Claraz

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400504

Electrochemical Synthesis of Aryl Chlorides Using HCl as the Chlorine Source

Tao Shen, Yuanbo Xu, Chengjun Jiang, Yifeng Lai, Linlin Wu, Shenghui Liu, Liangquan Zhang, Chao Qian and Shaodong Zhou

ACS Sustainable Chem. Eng., 2024, 12, 3289
DOI: 10.1021/acssuschemeng.3c07843

Asymmetric Functionalization Harnessing Radical‐Mediated Functional‐Group Migration

Fushan Chen, Zhu Cao and Chen Zhu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202424667

Electrochemically‐Driven 1,4‐Aryl Migration via Radical Fluoromethylation of N‐Allylbenzamides: a Straightforward Access to Functionalized β‐Arylethylamines

Etienne Derat, Géraldine Masson and Aurélie Claraz

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202406017

Electrosynthesis of β‐Acyloxy‐γ‐Selenyl Amines via Migratory Oxyselenation of N‐Acyl Allylamines

Kejun Lin, Jianyong Lan and Tingshun Zhu

Adv Synth Catal, 2022, 364, 3466
DOI: 10.1002/adsc.202200597

Recent Advances in the Electrochemical Functionalization of Imidazoheterocycles

Sifeng Li

Adv Synth Catal, 2024, 366, 4908
DOI: 10.1002/adsc.202401064

Photocatalytic Asymmetric Acyl Radical Truce–Smiles Rearrangement for the Synthesis of Enantioenriched α‐Aryl Amides

Wei‐Yang Ma, Matteo Leone, Etienne Derat, Pascal Retailleau, Chada Raji Reddy, Luc Neuville and Géraldine Masson

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202408154

Merging Fluorine Incorporation and Functional Group Migration

Zhigang Ma, Xinxin Wu and Chen Zhu

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202200221

Photoinduced Asymmetric Alkene Aminohetarylation with Chiral Sulfoximine Reagents

Zhu Cao, Yuqian Sun, Yasu Chen and Chen Zhu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202408177

Asymmetric Functionalization Harnessing Radical‐Mediated Functional‐Group Migration

Fushan Chen, Zhu Cao and Chen Zhu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202424667

Electrochemically Promoted Three-Component Reaction to N-Sulfonyl Amidines

Zhang Zhang, Xiu-Jin Meng, Fei-Hu Cui, Hai-Tao Tang, Ying-Chun Wang, Guo-Bao Huang and Ying-Ming Pan

Org. Lett., 2024, 26, 193
DOI: 10.1021/acs.orglett.3c03820

Advances in radical Smiles rearrangement

Nianhua Luo, Jiayi Jiang, Muhammad Suleman, Zhaowen Liu, Shuping Huang, Wei Xiao, Jie Wu and Jiapian Huang

Chinese Chemical Letters, 2025, 111556
DOI: 10.1016/j.cclet.2025.111556

Photocatalytic Asymmetric Acyl Radical Truce–Smiles Rearrangement for the Synthesis of Enantioenriched α‐Aryl Amides

Wei‐Yang Ma, Matteo Leone, Etienne Derat, Pascal Retailleau, Chada Raji Reddy, Luc Neuville and Géraldine Masson

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202408154

Visible-Light-Induced Decarbonylative Truce–Smiles Rearrangement of N-Sulfonylbenzamides

Zheng Liu, Lin Tian, Jiayu Mo and Huawen Huang

Org. Lett., 2025, 27, 7501
DOI: 10.1021/acs.orglett.5c01435

Electrochemical Difunctionalization of Alkenes

Jing-Hao Qin, Ning Nan and Jin-Heng Li

Synthesis, 2023, 55, 2843
DOI: 10.1055/a-2036-2074

Fe (III)-Photocatalyzed Decarboxylative Fluoroalkylation of Unactivated Alkenes via Distal Migration

Yuhua Zhong, Xiaoyu Li, Hu Cai and Wentao Xu

J. Org. Chem., 2025, 90, 12247
DOI: 10.1021/acs.joc.5c01683

Electrochemically‐Driven 1,4‐Aryl Migration via Radical Fluoromethylation of N‐Allylbenzamides: a Straightforward Access to Functionalized β‐Arylethylamines

Etienne Derat, Géraldine Masson and Aurélie Claraz

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202406017

Transition Metal and Base‐Free Electro‐Oxidative Regioselective Trifluoromethylation of Imidazo[1,2‐a]pyridines

Atreyee Halder, Sayan Ghosh and Suman De Sarkar

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202300294