Photoswitchable catalysis using organometallic complexes

Zoraida Freixa

Catal. Sci. Technol., 2020, 10, 3122
DOI: 10.1039/D0CY00431F

Light switching for product selectivity control in photocatalysis

Bayan G. D. Peelikuburage, Wayde N. Martens and Eric R. Waclawik

Nanoscale, 2024, 16, 10168
DOI: 10.1039/D4NR00885E

Closed-to-open-shell ground state photoswitching of thienyl-based acylhydrazones

Martin Šetek, Valentino L. P. Guerra, Harry Robson, Anna O. Geleverya, Ondřej Maxa, Anna Lamancová, Václav Eigner, Dana Nachtigallová, Ján Tarábek and Petr Kovaříček

J. Mater. Chem. C, 2025, 13, 9520
DOI: 10.1039/D5TC00826C

Visible light-responsive materials: the (photo)chemistry and applications of donor–acceptor Stenhouse adducts in polymer science

Michèle Clerc, Sara Sandlass, Omar Rifaie-Graham, Julie A. Peterson, Nico Bruns, Javier Read de Alaniz and Luciano F. Boesel

Chem. Soc. Rev., 2023, 52, 8245
DOI: 10.1039/D3CS00508A

Sulfoxide hemithioindigo tweezers – visible light addressable capture and release

Thomas Bartelmann, Frederik Gnannt, Max Zitzmann, Peter Mayer and Henry Dube

Chem. Sci., 2021, 12, 3651
DOI: 10.1039/D0SC04981F

Azopyridine-based chiral oxazolines with rare-earth metals for photoswitchable catalysis

Kento Nakamura, Masaru Kondo, Chandu G. Krishnan, Shinobu Takizawa and Hiroaki Sasai

Chem. Commun., 2021, 57, 7414
DOI: 10.1039/D1CC02602J

Triazonine-based bistable photoswitches: synthesis, characterization and photochromic properties

Nawel Goual, Lorenzo Casimiro, Vincent Delattre, Pascal Retailleau, Stéphane Maisonneuve, Nicolas Bogliotti, Rémi Métivier, Juan Xie, Angela Marinetti and Arnaud Voituriez

Chem. Commun., 2021, 57, 10079
DOI: 10.1039/D1CC02746H

Photoswitchable electron-rich phosphines: using light to modulate the electron-donating ability of phosphines

Florenz Buß, Mowpriya Das, Daniel Janssen-Müller, Alexander Sietmann, Ankita Das, Lukas F. B. Wilm, Matthias Freitag, Michael Seidl, Frank Glorius and Fabian Dielmann

Chem. Commun., 2023, 59, 12019
DOI: 10.1039/D3CC04050J

Sunlight-mediated [3 + 2] cycloaddition of azobenzenes with arynes: an approach toward the carbazole skeleton

Wenjie Zhang, Jiahui Bu, Lei Wang, Pinhua Li and Hongji Li

Org. Chem. Front., 2021, 8, 5045
DOI: 10.1039/D1QO00739D

Photocontrol of catalysis in CuAAC reactions by air stable Cu(i) complexes of phenylazopyrazole-incorporated ligands

Debapriya Gupta, Ankit Kumar Gaur, Deepanshu Chauhan, Sandeep Kumar Thakur, Ashish, Sanjay Singh, Gopalan Rajaraman and Sugumar Venkataramani

Inorg. Chem. Front., 2024, 11, 3555
DOI: 10.1039/D4QI00268G

Recent advances utilized in artificial switchable catalysis

Arash Ghorbani-Choghamarani and Zahra Taherinia

RSC Adv., 2022, 12, 23595
DOI: 10.1039/D2RA03842K

Synthesis and properties of photoswitchable diphosphines and gold(i) complexes derived from azobenzenes

Clément Cazorla, Lorenzo Casimiro, Tanzeel Arif, Claire Deo, Nawel Goual, Pascal Retailleau, Rémi Métivier, Juan Xie, Arnaud Voituriez, Angela Marinetti and Nicolas Bogliotti

Dalton Trans., 2021, 50, 7284
DOI: 10.1039/D1DT01080H

Designing P-type bi-stable overcrowded alkene-based chiroptical photoswitches

Jinyu Sheng, Wojciech Danowski, Stefano Crespi, Ainoa Guinart, Xiaobing Chen, Cosima Stähler and Ben L. Feringa

Chem. Sci., 2023, 14, 4328
DOI: 10.1039/D2SC05903G

Enlightening dynamic functions in molecular systems by intrinsically chiral light-driven molecular motors

Jinyu Sheng, Daisy R. S. Pooler and Ben L. Feringa

Chem. Soc. Rev., 2023, 52, 5875
DOI: 10.1039/D3CS00247K

Alkyne hydrazones for Raman scattering spectroscopy

Daniil Sosnin and Ivan Aprahamian

Chem. Commun., 2025, 61, 10119
DOI: 10.1039/D5CC02471D

Exploring molecular motors

Jos C. M. Kistemaker, Anouk S. Lubbe and Ben L. Feringa

Mater. Chem. Front., 2021, 5, 2900
DOI: 10.1039/D0QM01091J

A photoresponsive palladium complex of an azopyridyl-triazole ligand: light-controlled solubility drives catalytic activity in the Suzuki coupling reaction

Attila Kunfi, István Jablonkai, Tamás Gazdag, Péter J. Mayer, Péter Pál Kalapos, Krisztina Németh, Tamás Holczbauer and Gábor London

RSC Adv., 2021, 11, 23419
DOI: 10.1039/D1RA03838A

Stereoselective synthesis and properties of glycoazobenzene macrocycles through intramolecular glycosylation

Chaoqi Lin, Jinbiao Jiao, Stéphane Maisonneuve, Julien Mallétroit and Juan Xie

Chem. Commun., 2020, 56, 3261
DOI: 10.1039/C9CC09853D

Reversible photochromic properties of 4,5,6-triaryl-4H-pyran derivatives in a solid state

Yufeng Xie, Zhiqiang Wang, Dan Wang, Yunbing Zhou, Yunxiang Lei, Wenxia Gao, Miaochang Liu, Xiaobo Huang and Huayue Wu

Mater. Chem. Front., 2021, 5, 3413
DOI: 10.1039/D1QM00152C

Temporal control in tritylation reactions through light-driven variation in chloride ion binding catalysis – a proof of concept

Surbhi Grewal, Saonli Roy, Himanshu Kumar, Mayank Saraswat, Naimat K. Bari, Sharmistha Sinha and Sugumar Venkataramani

Catal. Sci. Technol., 2020, 10, 7027
DOI: 10.1039/D0CY01090A

Accounts of applied molecular rotors and rotary motors: recent advances

Anup Singhania, Sudeshna Kalita, Prerna Chettri and Subrata Ghosh

Nanoscale Adv., 2023, 5, 3177
DOI: 10.1039/D3NA00010A

Installation of cationic phosphorus on dimethyldihydropyrene photoswitches: expanding the atomic repertoire towards far-red photoswitching in water

Manik Lal Maity, Sayan Chandra, Samyadeb Mahato and Subhajit Bandyopadhyay

Chem. Sci., 2025, 16, 21991
DOI: 10.1039/D5SC06168G

Interplay between anti–anti and syn–anti conformations of thiourea modulating ON–OFF catalysis

Renitta Benny and Soumen De

Dalton Trans., 2023, 52, 16767
DOI: 10.1039/D3DT02398B

A multi-stimuli responsive ruthenium complex for catalytic water oxidation

Masanari Hirahara, Hiroki Goto, Masayuki Yagi and Yasushi Umemura

Chem. Commun., 2020, 56, 12825
DOI: 10.1039/D0CC04940A

New horizons for catalysis disclosed by supramolecular chemistry

Giorgio Olivo, Giorgio Capocasa, Daniele Del Giudice, Osvaldo Lanzalunga and Stefano Di Stefano

Chem. Soc. Rev., 2021, 50, 7681
DOI: 10.1039/D1CS00175B

The influence of surface proximity on photoswitching activity of stilbene-functionalized N-heterocyclic carbene monolayers

Shahar Dery, Israel Alshanski, Evgeniy Mervinetsky, Daniel Feferman, Shlomo Yitzchaik, Mattan Hurevich and Elad Gross

Chem. Commun., 2021, 57, 6233
DOI: 10.1039/D1CC02491D

Excited-state antiaromaticity relief in photoactive amine–boranes promotes transfer hydrogenation to electron-poor olefins

Enrique M. Arpa

Phys. Chem. Chem. Phys., 2025, 27, 18121
DOI: 10.1039/D5CP02226F

Data-driven discovery of molecular photoswitches with multioutput Gaussian processes

Ryan-Rhys Griffiths, Jake L. Greenfield, Aditya R. Thawani, Arian R. Jamasb, Henry B. Moss, Anthony Bourached, Penelope Jones, William McCorkindale, Alexander A. Aldrick, Matthew J. Fuchter and Alpha A. Lee

Chem. Sci., 2022, 13, 13541
DOI: 10.1039/D2SC04306H

Two-photon induced isomerization through a cyaninic molecular antenna in azo compounds

Emmanuel Villatoro, Leonardo Muñoz-Rugeles, Jesús Durán-Hernández, Bernardo Salcido-Santacruz, Nuria Esturau-Escofet, Jose G. López-Cortés, M. Carmen Ortega-Alfaro and Jorge Peón

Chem. Commun., 2021, 57, 3123
DOI: 10.1039/D0CC08346A

“The red cage”: implementation of pH-responsiveness within a macrobicyclic pyridinium-based molecular host

Pablo Cortón, Hongye Wang, Iago Neira, Arturo Blanco-Gómez, Elena Pazos, Carlos Peinador, Hao Li and Marcos D. García

Org. Chem. Front., 2022, 9, 81
DOI: 10.1039/D1QO01331A

Metal complexes bearing photochromic ligands: photocontrol of functions and processes

Olivier Galangau, Lucie Norel and Stéphane Rigaut

Dalton Trans., 2021, 50, 17879
DOI: 10.1039/D1DT03397B

Benzofuranone-based spiropyrans: synthesis, temperature-dependent photochromic properties, and DFT calculations

Xincheng Zhou, Zhichao Chang, Yongchun Hu, Jianming Zhong, Jiaying Liao, Chunying Rong and Wang Zhou

Org. Chem. Front., 2025, 12, 1619
DOI: 10.1039/D4QO02123A

Spatiotemporal control for integrated catalysis

Shijie Deng, Brandon J. Jolly, James R. Wilkes, Yu Mu, Jeffery A. Byers, Loi H. Do, Alexander J. M. Miller, Dunwei Wang, Chong Liu and Paula L. Diaconescu

Nat Rev Methods Primers, 2023, 3
DOI: 10.1038/s43586-023-00207-0

Visible‐light‐switchable Chalcone‐Flavylium Photochromic Systems in Aqueous Media

Manik Lal Maity, Samyadeb Mahato and Subhajit Bandyopadhyay

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202311551

Stereodivergent Anion Binding Catalysis with Molecular Motors

Ruth Dorel and Ben L. Feringa

Angew Chem Int Ed, 2020, 59, 785
DOI: 10.1002/anie.201913054

Visible‐Light‐Triggered Photoswitching of Diphosphene Complexes

Clemens Taube, Jannis Fidelius, Kai Schwedtmann, Christopher Ziegler, Florian Kreuter, Leigh Loots, Leonard J. Barbour, Ralf Tonner‐Zech, Robert Wolf and Jan J. Weigand

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202306706

Optically Controlled Recovery and Recycling of Homogeneous Organocatalysts Enabled by Photoswitches

Qianfeng Qiu, Zhenhuan Sun, Danielle Joubran, Xiang Li, Joshua Wan, Klaus Schmidt‐Rohr and Grace G. D. Han

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202300723

Heterocyclic Hemithioindigos: Highly Advantageous Properties as Molecular Photoswitches**

Verena Josef, Frank Hampel and Henry Dube

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202210855

Enantiodivergent epoxidation of alkenes with a photoswitchable phosphate manganese-salen complex

Xiaofei Chen, Pieter J. Gilissen, Paul Tinnemans, Nicolas Vanthuyne, Floris P. J. T. Rutjes, Ben L. Feringa, Johannes A. A. W. Elemans and Roeland J. M. Nolte

Nat. Synth, 2022, 1, 873
DOI: 10.1038/s44160-022-00157-7

The Power of Action Plots: Unveiling Reaction Selectivity of Light‐Stabilized Dynamic Covalent Chemistry

Steven C. Gauci, Filip E. Du Prez, Joshua O. Holloway, Hannes A. Houck and Christopher Barner‐Kowollik

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310274

Photoswitching, Colloidal Stability, and Reversible Self-Assembly of Gold Nanoparticles Covered with Thiolated Donor–Acceptor Stenhouse Adducts

Grzegorz Sobczak, Iwona Misztalewska-Turkowicz and Volodymyr Sashuk

J. Phys. Chem. C, 2021, 125, 5306
DOI: 10.1021/acs.jpcc.0c10595

Photoisomerizable azobenzene dyes incorporated into polymers and dendrimers. Influence of the molecular aggregation on the nonlinear optical properties

Fabián Cuétara-Guadarrama, Mireille Vonlanthen, Kendra Sorroza-Martínez, Israel González-Méndez and Ernesto Rivera

Dyes and Pigments, 2021, 194, 109551
DOI: 10.1016/j.dyepig.2021.109551

Three-State Switching of an Anthracene Extended Bis-thiaxanthylidene with a Highly Stable Diradical State

Marco B. S. Wonink, Brian P. Corbet, Artem A. Kulago, Gregory B. Boursalian, Bas de Bruin, Edwin Otten, Wesley R. Browne and Ben L. Feringa

J. Am. Chem. Soc., 2021, 143, 18020
DOI: 10.1021/jacs.1c05938

Thermal and Photochemical Switching of Chiral Sugar Azoalkenes: A Mechanistic Interrogation

Ana María Sánchez‐León, Pedro Cintas, Mark E. Light and Juan Carlos Palacios

Eur J Org Chem, 2020, 2020, 2827
DOI: 10.1002/ejoc.202000029

Hemiphosphoindigos as a platform for chiroptical or water soluble photoswitching

Fabien Kohl, Theresa Vogl, Frank Hampel and Henry Dube

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-56942-3

Photoisomerization‐Driven Photoluminescence Modulation in CdSeS Gradient Quantum Dot/Liquid Crystal Nanocomposites

Pragnya Satapathy, V. Navyashree, Pralay K. Santra and S. Krishna Prasad

ChemPhotoChem, 2020, 4, 413
DOI: 10.1002/cptc.201900293

Facile One‐Step Oxidation of N‐Boc‐Protected Diarylhydrazines to Diaryldiazenes with (Diacetoxyiodo)benzene under Mild Conditions

Jakub Orvoš, Filip Pančík and Róbert Fischer

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300049

Azobenzene-based Chiral Photoswitchable Catalysts

Masaru Kondo, Kento Nakamura, Hiroaki Sasai and Shinobu Takizawa

J. Synth. Org. Chem. Jpn., 2023, 81, 817
DOI: 10.5059/yukigoseikyokaishi.81.817

Configurational Selection in Azobenzene‐Based Supramolecular Systems Through Dual‐Stimuli Processes

Paolo Tecilla and Davide Bonifazi

ChemistryOpen, 2020, 9, 538
DOI: 10.1002/open.202000045

Photo- and ionochromic N-acylated 2-(aminomethylene)benzo[b]thiophene-3(2H)-ones containing a terpyridine receptor

Vladimir P. Rybalkin, Sofiya Y. Zmeeva, Lidiya L. Popova, Anton V. Lisovin, Mikhail E. Kletskii, Oleg N. Burov, Irina V. Dubonosova, Oleg P. Demidov, Olga Y. Karlutova, Evgenii N. Shepelenko, Vitaly A. Podshibyakin, Alexander D. Dubonosov and Vladimir A. Bren

Journal of Photochemistry and Photobiology A: Chemistry, 2025, 459, 116066
DOI: 10.1016/j.jphotochem.2024.116066

Azo-dimethylaminopyridine-functionalized Ni(II)-porphyrin as a photoswitchable nucleophilic catalyst

Jannis Ludwig, Julian Helberg, Hendrik Zipse and Rainer Herges

Beilstein J. Org. Chem., 2020, 16, 2119
DOI: 10.3762/bjoc.16.179

Complex Multistate Photophysics of a Rhodanine Photoswitch

Anam Fatima, Pratip Chakraborty, Xinyue Xu, Garth A. Jones, Isabelle Chambrier, Giorgia Logan, Andrew N. Cammidge, Trevor Smith, Christopher R. Hall and Stephen R. Meech

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202506137

Photoswitchable Catalytic Divergent Synthesis by a Viologen‐Functionalized Lanthanide‐Organic Tetrahedral Cage

Ke‐Han Tang, Yu‐Xi Tian, Fan Yin, Wei‐Hui Zhuang, Shao‐Jun Hu, Li‐Peng Zhou, Jian Yang and Qing‐Fu Sun

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202510095

Kooperative Effekte in schaltbarer Katalyse: Verbesserung der Doppel‐Click‐Reaktionsausbeuten von symmetrischen Rotaxanen

Amit Ghosh, Indrajit Paul and Michael Schmittel

Angewandte Chemie, 2021, 133, 20722
DOI: 10.1002/ange.202108269

Ampeln für die Katalyse: Stimulus‐reaktive molekulare und erweiterte katalytische Systeme

Grace C. Thaggard, Johanna Haimerl, Roland A. Fischer, Kyoung Chul Park and Natalia B. Shustova

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202302859

ReaxFF-based nonadiabatic dynamics method for azobenzene derivatives

Helena Osthues and Nikos L. Doltsinis

The Journal of Chemical Physics, 2022, 157
DOI: 10.1063/5.0129699

Pfadunabhängiges mit sichtbarem Licht adressierbares orthogonales Photoschalten für Anwendungen in multi‐photochromomen Polymeren und molekularen Computern

Laura Köttner and Henry Dube

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202409214

The mechanisms and topologies of Ru-based water oxidation catalysts: A comprehensive review

Quoc Hai Nguyen, Qui Thanh Hoai Ta and Ngo Tran

Ceramics International, 2023, 49, 4030
DOI: 10.1016/j.ceramint.2022.11.228

Light‐Induced and Thermal Isomerization of Azobenzenes on Immobilized Gold Nanoparticle Aggregates

Attila Kunfi, Ágnes Ábrahám, Gergő Gyulai, Éva Kiss and Gábor London

ChemPlusChem, 2022, 87
DOI: 10.1002/cplu.202200153

Azobenzene‐Oxindole Photochromic Dyads

Marco Ovalle, Daniel Doellerer and Ben L. Feringa

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202501872

Photoresponsive Dynamic Supramolecular Assembly and Regulation of Stiff-Stilbenes

Qianhong Cao, Yongmei Xiao and Guoxing Liu

Chinese Journal of Organic Chemistry, 2024, 44, 2124
DOI: 10.6023/cjoc202312026

Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin

Jacob Jan van der Wal, Jorn D. Steen, Ann‐Kathrin Rückert, Roman Yu. Peshkov, Michiel F. Hilbers, P. Tim Prins, Wybren Jan Buma, Andreas Orthaber and Stefano Crespi

Angew Chem Int Ed, 2025
DOI: 10.1002/anie.202519686

Remote-Controlled Exchange Rates by Photoswitchable Internal Catalysis of Dynamic Covalent Bonds

David N. Barsoum, Viraj C. Kirinda, Boyeong Kang and Julia A. Kalow

J. Am. Chem. Soc., 2022, 144, 10168
DOI: 10.1021/jacs.2c04658

Dual-Stimulus-Driven Dynamically Controllable [3]Rotaxane with Tunable Organic Room-Temperature Phosphorescence

Guoxing Liu, Changming Tian, Xinhui Fan, Yuli Dang, Jieqiong Qin, Lijie Liu, Zhanqi Cao and Song Jiang

Org. Lett., 2023, 25, 8761
DOI: 10.1021/acs.orglett.3c03804

1,2-Diaroyl Benzofurans: Synthesis and Photochromic Properties

Jianming Zhong, Shuangshuang Li, Zhaoxin Wang and Wang Zhou

Synlett, 2025, 36, 464
DOI: 10.1055/s-0043-1775039

Azobenzene‐Oxindole Photochromic Dyads

Marco Ovalle, Daniel Doellerer and Ben L. Feringa

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202501872

Complex Multistate Photophysics of a Rhodanine Photoswitch

Anam Fatima, Pratip Chakraborty, Xinyue Xu, Garth A. Jones, Isabelle Chambrier, Giorgia Logan, Andrew N. Cammidge, Trevor Smith, Christopher R. Hall and Stephen R. Meech

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202506137

Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis

Kun-Yu Wang, Jiaqi Zhang, Yu-Chuan Hsu, Hengyu Lin, Zongsu Han, Jiandong Pang, Zhentao Yang, Rong-Ran Liang, Wei Shi and Hong-Cai Zhou

Chem. Rev., 2023, 123, 5347
DOI: 10.1021/acs.chemrev.2c00879

Photoswitchable Catalytic Divergent Synthesis by a Viologen‐Functionalized Lanthanide‐Organic Tetrahedral Cage

Ke‐Han Tang, Yu‐Xi Tian, Fan Yin, Wei‐Hui Zhuang, Shao‐Jun Hu, Li‐Peng Zhou, Jian Yang and Qing‐Fu Sun

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202510095

A photoswitchable catalyst for the enantiodivergent epoxidation of alkenes

Nat. Synth, 2022, 1, 837
DOI: 10.1038/s44160-022-00160-y

Photoswitchable Chiral Organocatalysts: Photocontrol of Enantioselective Reactions

Masaru Kondo, Kento Nakamura, Chandu G. Krishnan, Hiroaki Sasai and Shinobu Takizawa

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202300040

Semi-automated screening of azobezenes for solar energy storage using extended tight binding methods

Karoline Schjelde, Oscar B. Obel, Andreas Erbs Hillers-Bendtsen and Kurt V. Mikkelsen

Sci Rep, 2025, 15
DOI: 10.1038/s41598-025-99925-6

Chemically Driven Rotatory Molecular Machines

Anirban Mondal, Ryojun Toyoda, Romain Costil and Ben L. Feringa

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202206631

From Organic Fragments to Photoswitchable Catalysts: The OFF–ON Structural Repository for Transferable Kernel-Based Potentials

Frédéric Célerse, Matthew D. Wodrich, Sergi Vela, Simone Gallarati, Raimon Fabregat, Veronika Juraskova and Clémence Corminboeuf

J. Chem. Inf. Model., 2024, 64, 1201
DOI: 10.1021/acs.jcim.3c01953

Molecularly Controlled Catalysis – Targeting Synergies Between Local and Non‐local Environments

Basujit Chatterjee, Wei‐Chieh Chang and Christophe Werlé

ChemCatChem, 2021, 13, 1659
DOI: 10.1002/cctc.202001431

From Triplet to Twist: The Photochemical E/Z‐Isomerization Pathway of the Near‐Infrared Photoswitch peri‐Anthracenethioindigo

Martina Hartinger, Maximilian Herm, Christoph Schüßlbauer, Laura Köttner, Dirk Guldi, Henry Dube and Carolin Müller

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202510626

Tautomerism and switching in 7-hydroxy-8-(azophenyl)quinoline and similar compounds

Lidia Zaharieva, Vera Deneva, Fadhil S Kamounah, Nikolay Vassilev, Ivan Angelov, Michael Pittelkow and Liudmil Antonov

Beilstein J. Org. Chem., 2025, 21, 1404
DOI: 10.3762/bjoc.21.105

Traffic Lights for Catalysis: Stimuli‐Responsive Molecular and Extended Catalytic Systems

Grace C. Thaggard, Johanna Haimerl, Roland A. Fischer, Kyoung Chul Park and Natalia B. Shustova

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202302859

Smart Photochromic Materials Triggered with Visible Light

Anna‐Lena Leistner and Zbigniew L. Pianowski

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202101271

Advances in the Structural Strategies of the Self-Assembly of Photoresponsive Supramolecular Systems

Vivian J. Santamaria-Garcia, Domingo R. Flores-Hernandez, Flavio F. Contreras-Torres, Rodrigo Cué-Sampedro and José Antonio Sánchez-Fernández

IJMS, 2022, 23, 7998
DOI: 10.3390/ijms23147998

Metal–Photoswitch Friendship: From Photochromic Complexes to Functional Materials

Grace C. Thaggard, Johanna Haimerl, Kyoung Chul Park, Jaewoong Lim, Roland A. Fischer, Buddhima K. P. Maldeni Kankanamalage, Brandon J. Yarbrough, Gina R. Wilson and Natalia B. Shustova

J. Am. Chem. Soc., 2022, 144, 23249
DOI: 10.1021/jacs.2c09879

Electronic Influences on the Dynamic Range of Photoswitchable Dithienylethene–Thiourea Organocatalysts

Debashis Majee, Gabriele Ramanauskaite and Stanislav Presolski

J. Org. Chem., 2023, 88, 4372
DOI: 10.1021/acs.joc.2c02987

Pentacoordinate silicon compounds based on 2,2′-dihydroxyazobenzene ligand

Anastasiya S. Soldatenko, Irina V. Sterkhova and Nataliya F. Lazareva

Journal of Organometallic Chemistry, 2019, 903, 120997
DOI: 10.1016/j.jorganchem.2019.120997

Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin

Jacob Jan van der Wal, Jorn D. Steen, Ann‐Kathrin Rückert, Roman Yu. Peshkov, Michiel F. Hilbers, P. Tim Prins, Wybren Jan Buma, Andreas Orthaber and Stefano Crespi

Angewandte Chemie, 2025
DOI: 10.1002/ange.202519686

Fluorescent Photochromic α‐Cyanodiarylethene Molecular Switches: An Emerging and Promising Class of Functional Diarylethene

Siyang Lin, Karla G. Gutierrez‐Cuevas, Xinfang Zhang, Jinbao Guo and Quan Li

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202007957

Path‐Independent All‐Visible Orthogonal Photoswitching for Applications in Multi‐Photochromic Polymers and Molecular Computing

Laura Köttner and Henry Dube

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202409214

The Effect of Aldehyde and Carboxylic Acid Substitution on the Isomerization of Hemithioindigo Photoswitches

Matías I. Quindt, Taegeun Jo, Amol Kumar, Jorn D. Steen, Luca D'Amario, Sascha Ott and Stefano Crespi

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501108

(Supra)Molecular Switches Controlled by Artificial Signaling Cascades

Jayashree Venkatesh, Akanksha Sharma, Soumen De, Susnata Pramanik and Michael Schmittel

Synlett, 2025, 36, 1868
DOI: 10.1055/s-0043-1775490

Synthesis and Characterization of Photoswitchable Dithienylethene‐Based Chiral Bisoxazoline Compounds with Bidirectional Visible‐Light Control

Hao‐Zhao Wei, Yin Wei and Min Shi

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202300633

Multi-Ferrocene-Based Ligands: From Design to Applications

Axel Straube, Liridona Useini and Evamarie Hey-Hawkins

Chem. Rev., 2025, 125, 3007
DOI: 10.1021/acs.chemrev.4c00295

Phosphoramidite-based photoresponsive ligands displaying multifold transfer of chirality in dynamic enantioselective metal catalysis

Stefano F. Pizzolato, Peter Štacko, Jos C. M. Kistemaker, Thomas van Leeuwen and Ben L. Feringa

Nat Catal, 2020, 3, 488
DOI: 10.1038/s41929-020-0452-y

A photochemical method to evidence directional molecular motions

Benjamin Lukas Regen-Pregizer, Ani Ozcelik, Peter Mayer, Frank Hampel and Henry Dube

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-40190-4

Synthesis and Evaluation of the Photochemical Properties of Heterocyclic Hemiindigos

Aurélie Gernet, Louise‐Marie Balivet, Ahmed El Rhaz, Lucas Pagès, Guillaume Laurent, François Maurel and Ludovic Jean

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202500803

Photoswitching Lewis Acid Catalysis with Highly Fatigue Resistant Photochromic Boronates

Lennart Stoess, Jeremy A. Davis and Lutz Greb

J. Am. Chem. Soc., 2026
DOI: 10.1021/jacs.5c22962

Synthesis and Characterization of a [1,2,6]Diazaphosphonine Oxide: An Example of a Photoswitchable Phosphorus-Containing Cyclic Azobenzene

Nawel Goual, Stéphane Maisonneuve, Pascal Retailleau, Juan Xie, Angela Marinetti and Arnaud Voituriez

J. Org. Chem., 2024, 89, 5098
DOI: 10.1021/acs.joc.3c02450

Substrate Photoswitching for Rate Enhancement of a Organocatalytic Cyclization Reaction

Matej Žabka and Ruth M. Gschwind

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200048

Azobenzene-Integrated NHC Ligands: A Versatile Platform for Visible-Light-Switchable Metal Catalysis

Martin Rölz, Burkhard Butschke and Bernhard Breit

J. Am. Chem. Soc., 2024, 146, 13210
DOI: 10.1021/jacs.4c01138

Harnessing the photochromic behavior of metal-complexes from non-photochromic ligands: A brief review of current insights and future perspectives

Pranesh Chowdhury and Nandagopal Bar

Polyhedron, 2026, 289, 118004
DOI: 10.1016/j.poly.2026.118004

Photoswitchable Chiral Phase Transfer Catalyst

Masaru Kondo, Kento Nakamura, Chandu G. Krishnan, Shinobu Takizawa, Tsukasa Abe and Hiroaki Sasai

ACS Catal., 2021, 11, 1863
DOI: 10.1021/acscatal.1c00057

Funktionsgewinn recycelbarer Photoschalter: Gleichzeitige reversible Substitution und Erzeugung von Photochromie

Max Zitzmann, Matthias Fröhling and Henry Dube

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202318767

Diaryl-hemiindigos as visible light, pH, and heat responsive four-state switches and application in photochromic transparent polymers

Maximilian Sacherer, Frank Hampel and Henry Dube

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-39944-x

Die Stärke von Action Plots: Untersuchung der Reaktionsselektivität lichtstabilisierter dynamischer kovalenter Chemie

Steven C. Gauci, Filip E. Du Prez, Joshua O. Holloway, Hannes A. Houck and Christopher Barner‐Kowollik

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310274

Searching the Chemical Space of Bicyclic Dienes for Molecular Solar Thermal Energy Storage Candidates

Andreas Erbs Hillers‐Bendtsen, Jacob Lynge Elholm, Oscar Berlin Obel, Helen Hölzel, Kasper Moth‐Poulsen and Kurt V. Mikkelsen

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202309543

Photoswitchable Macroscopic Solid Surfaces Based On Azobenzene‐Functionalized Polydopamine/Gold Nanoparticle Composite Materials: Formation, Isomerization and Ligand Exchange

Attila Kunfi, Rita Bernadett Vlocskó, Zsófia Keresztes, Miklós Mohai, Imre Bertóti, Ágnes Ábrahám, Éva Kiss and Gábor London

ChemPlusChem, 2020, 85, 797
DOI: 10.1002/cplu.201900674

How Robust Is the Reversible Steric Shielding Strategy for Photoswitchable Organocatalysts?

Simone Gallarati, Raimon Fabregat, Veronika Juraskova, Theo Jaffrelot Inizan and Clemence Corminboeuf

J. Org. Chem., 2022, 87, 8849
DOI: 10.1021/acs.joc.1c02991

Optically Controlled Recovery and Recycling of Homogeneous Organocatalysts Enabled by Photoswitches

Qianfeng Qiu, Zhenhuan Sun, Danielle Joubran, Xiang Li, Joshua Wan, Klaus Schmidt‐Rohr and Grace G. D. Han

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202300723

Dithienylethene-Based Photoswitchable Phosphines for the Palladium-Catalyzed Stille Coupling Reaction

Anastasiia Sherstiuk, Agustí Lledós, Peter Lönnecke, Jordi Hernando, Rosa María Sebastián and Evamarie Hey-Hawkins

Inorg. Chem., 2024, 63, 7652
DOI: 10.1021/acs.inorgchem.3c04423

Vom Triplett zum Twist: Mechanismus der photochemischen E/Z‐Isomerisierung des Nahinfrarot‐Photoschalters peri‐Anthracenthioindigo

Martina Hartinger, Maximilian Herm, Christoph Schüßlbauer, Laura Köttner, Dirk M. Guldi, Henry Dube and Carolin Müller

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202510626

Rhodanine-Based Chromophores: Fast Access to Capable Photoswitches and Application in Light-Induced Apoptosis

Laura Köttner, Friederike Wolff, Peter Mayer, Esther Zanin and Henry Dube

J. Am. Chem. Soc., 2024, 146, 1894
DOI: 10.1021/jacs.3c07710

Switching Dual Catalysis without Molecular Switch: Using A Multicomponent Information System for Reversible Reconfiguration of Catalytic Machinery

Abir Goswami, Thomas Paululat and Michael Schmittel

J. Am. Chem. Soc., 2019, 141, 15656
DOI: 10.1021/jacs.9b07737

Stereodivergent Anion Binding Catalysis with Molecular Motors

Ruth Dorel and Ben L. Feringa

Angewandte Chemie, 2020, 132, 795
DOI: 10.1002/ange.201913054

All-Red-Light Photoswitching of Indirubin Controlled by Supramolecular Interactions

Stefan Thumser, Laura Köttner, Nadine Hoffmann, Peter Mayer and Henry Dube

J. Am. Chem. Soc., 2021, 143, 18251
DOI: 10.1021/jacs.1c08206

Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch

Rajesh Deka, Jorn D. Steen, Michiel F. Hilbers, Wim G. Roeterdink, Alessandro Iagatti, Ruisheng Xiong, Wybren Jan Buma, Mariangela Di Donato, Andreas Orthaber and Stefano Crespi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202419943

Dynamical Effects of Solvation on Norbornadiene/Quadricyclane Systems

Andreas Erbs Hillers-Bendtsen, Yogesh Todarwal, Patrick Norman and Kurt V. Mikkelsen

J. Phys. Chem. A, 2024, 128, 2602
DOI: 10.1021/acs.jpca.4c00045

Hemithioindigo-Based Trioxobicyclononadiene: 3D Multiswitching of Electronic and Geometric Properties

Fabien Kohl, Aaron Gerwien, Frank Hampel, Peter Mayer and Henry Dube

J. Am. Chem. Soc., 2022, 144, 2847
DOI: 10.1021/jacs.1c12364

Azobenzene-based photoswitchable catalysts: State of the art and perspectives

Rui Liu, Xiaojin Zhang, Fan Xia and Yu Dai

Journal of Catalysis, 2022, 409, 33
DOI: 10.1016/j.jcat.2022.03.015

Mechanochemical Regulation of Oxidative Addition to a Palladium(0) Bisphosphine Complex

Liqi Wang, Yichen Yu, Anton O. Razgoniaev, Patricia N. Johnson, Chenxu Wang, Yancong Tian, Roman Boulatov, Stephen L. Craig and Ross A. Widenhoefer

J. Am. Chem. Soc., 2020, 142, 17714
DOI: 10.1021/jacs.0c08506

Light-Induced Increase in Bond Strength─from Chalcogen Bond to Three-Electron σ Bond upon Excitation

Zoe Nonie Scheller, Saber Mehrparvar and Gebhard Haberhauer

J. Am. Chem. Soc., 2025, 147, 6249
DOI: 10.1021/jacs.4c18435

Visible‐light‐switchable Chalcone‐Flavylium Photochromic Systems in Aqueous Media

Manik Lal Maity, Samyadeb Mahato and Subhajit Bandyopadhyay

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202311551

Cooperative Effects in Switchable Catalysis: Enhancing Double‐Click Reaction Yield of Symmetrical Rotaxanes

Amit Ghosh, Indrajit Paul and Michael Schmittel

Angew Chem Int Ed, 2021, 60, 20558
DOI: 10.1002/anie.202108269

Enantiodivergent Sulfoxidation Catalyzed by a Photoswitchable Iron Salen Phosphate Complex

Pieter J. Gilissen, Xiaofei Chen, Joep De Graaf, Paul Tinnemans, Ben L. Feringa, Johannes A. A. W. Elemans and Roeland J. M. Nolte

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203539

In Situ Switching of Site-Selectivity with Light in the Acetylation of Sugars with Azopeptide Catalysts

Dominik Niedek, Frederik R. Erb, Christopher Topp, Alexander Seitz, Raffael C. Wende, André K. Eckhardt, Jonas Kind, Dominik Herold, Christina M. Thiele and Peter R. Schreiner

J. Org. Chem., 2020, 85, 1835
DOI: 10.1021/acs.joc.9b01913

Toward Molecular Cybernetics – the Art of Communicating Chemical Systems

Michael Schmittel and Prodip Howlader

The Chemical Record, 2021, 21, 523
DOI: 10.1002/tcr.202000126

Cis-trans isomerism-driven thermal and phase transitions in oleic and elaidic acids and their derived polymers

Minghao Wang, Haomin Yu, Jiawei Jiang, Wencong Xu, Guofeng Xu and Si Wu

Polymer, 2025, 317, 127954
DOI: 10.1016/j.polymer.2024.127954

Orthogonal Photoswitching in Nematic Liquid Crystals

Hoàn Quân Trân and Bart Jan Ravoo

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501851

Heterocyclic Hemithioindigos: Highly Advantageous Properties as Molecular Photoswitches**

Verena Josef, Frank Hampel and Henry Dube

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202210855

Light-Controlled Functions with Metal–Organic Capsules: From Guest Release to Catalysis, Separation, and Molecular Transport

Amit Ghosh and Jonathan R. Nitschke

Acc. Chem. Res., 2026, 59, 372
DOI: 10.1021/acs.accounts.5c00790

Photoresponsive Small Molecule Enzyme Mimics

Soumen Adak, Manik Lal Maity and Subhajit Bandyopadhyay

ACS Omega, 2022, 7, 35361
DOI: 10.1021/acsomega.2c05210

Dithienylethene-Based Photoswitchable Catalysts: State of the Art and Future Perspectives

Debashis Majee and Stanislav Presolski

ACS Catal., 2021, 11, 2244
DOI: 10.1021/acscatal.0c05232

Gain of Function Recyclable Photoswitches: Reversible Simultaneous Substitution and Photochromism Generation

Max Zitzmann, Matthias Fröhling and Henry Dube

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202318767

Towards artificial molecular factories from framework-embedded molecular machines

Simon Krause and Ben L. Feringa

Nat Rev Chem, 2020, 4, 550
DOI: 10.1038/s41570-020-0209-9

Fundamentals and utilization of solid/ liquid phase boundary interactions on functional surfaces

László Mérai, Ágota Deák, Imre Dékány and László Janovák

Advances in Colloid and Interface Science, 2022, 303, 102657
DOI: 10.1016/j.cis.2022.102657

The Growing Field of Photoswitchable Macrocycles: A Promising Way to Tune Various Properties with Light

Corentin Ludwig and Juan Xie

ChemPhotoChem, 2023, 7
DOI: 10.1002/cptc.202300126

Supramolecular Relay-Control of Organocatalysis with a Hemithioindigo-Based Molecular Motor

Kerstin Grill and Henry Dube

J. Am. Chem. Soc., 2020, 142, 19300
DOI: 10.1021/jacs.0c09519

Visible‐Light‐Initiated Palladium‐Catalyzed Cross‐coupling by PPh3 Uncaging from an Azobenzene Ruthenium–Arene Complex

Lou Rocard, Jérôme Hannedouche and Nicolas Bogliotti

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202200519

Hydrogen-Bonded Self-assembly of Supramolecular Donor–Acceptor Complexes of (E)-Bis(18-crown-6)azobenzene with Bis(ammoniopropyl) Derivatives of Bipyridine and Dipyridylethylene in Acetonitrile

Valery V. Volchkov, Mikhail N. Khimich, Mikhail Ya. Melnikov, Anton E. Egorov, Roman O. Starostin, Alexandra Ya. Freidzon, Svetlana N. Dmitrieva and Sergey P. Gromov

J Solution Chem, 2023, 52, 805
DOI: 10.1007/s10953-023-01271-6

Photoswitchable phosphines in catalysis

Fabrizio Medici, Nawel Goual, Vincent Delattre, Arnaud Voituriez and Angela Marinetti

ChemCatChem, 2020, 12, 5573
DOI: 10.1002/cctc.202000620

Molecular Switches and Motors Powered by Orthogonal Stimuli

Myeongsu Jeong, Jiyoon Park and Sunbum Kwon

Eur J Org Chem, 2020, 2020, 7254
DOI: 10.1002/ejoc.202001179

Light‐Responsive Aldehyde‐Reduction Catalysis Through Catalyst Encapsulation

Amit Ghosh, John D. Thoburn and Jonathan R. Nitschke

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202419575

Photoswitchable Catalysis Mediated by Nanoparticles

Grzegorz Sobczak and Volodymyr Sashuk

ChemCatChem, 2021, 13, 506
DOI: 10.1002/cctc.202001598

Chemically Driven Rotatory Molecular Machines

Anirban Mondal, Ryojun Toyoda, Romain Costil and Ben L. Feringa

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202206631

Photoswitchable Catalysis by a Self-Assembled Molecular Cage

Ray G. DiNardi, Samina Rasheed, Simona S. Capomolla, Man Him Chak, Isis A. Middleton, Lauren K. Macreadie, Jake P. Violi, William A. Donald, Paul J. Lusby and Jonathon E. Beves

J. Am. Chem. Soc., 2024, 146, 21196
DOI: 10.1021/jacs.4c04846

Light‐Responsive Aldehyde‐Reduction Catalysis Through Catalyst Encapsulation

Amit Ghosh, John D. Thoburn and Jonathan R. Nitschke

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202419575

Multiple Azoarenes Based Systems – Photoswitching, Supramolecular Chemistry and Application Prospects

Pravesh Kumar, Debapriya Gupta, Surbhi Grewal, Anjali Srivastava, Ankit Kumar Gaur and Sugumar Venkataramani

The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202200074

Visible‐Light‐Triggered Photoswitching of Diphosphene Complexes

Clemens Taube, Jannis Fidelius, Kai Schwedtmann, Christopher Ziegler, Florian Kreuter, Leigh Loots, Leonard J. Barbour, Ralf Tonner‐Zech, Robert Wolf and Jan J. Weigand

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202306706

Pursuing the Complete OFF State in Photoswitchable Catalysis

Mykola Kravets, Matteo Flaibani, Magdalena Szewczyk, Paola Posocco and Volodymyr Sashuk

ACS Catal., 2023, 13, 15967
DOI: 10.1021/acscatal.3c04435

Tailoring Polymerization Controllability and Dispersity Through a Photoswitchable Catalyst Strategy

Zhuan Chen, Yue Sun, Xin Wang, Weidong Zhang and Zhengbiao Zhang

Macromol. Rapid Commun., 2023, 44
DOI: 10.1002/marc.202300198

Design of Azobenzene beyond Simple On–Off Behavior

Saber Mehrparvar, Zoe Nonie Scheller, Christoph Wölper and Gebhard Haberhauer

J. Am. Chem. Soc., 2021, 143, 19856
DOI: 10.1021/jacs.1c09090

Sandwich like poly(ionic liquid)s functionalized microspheres: Efficient interfacial catalysts for preparation of biodiesel

Anguo Ying, Mingshu Li, Xiaotong Lu, Shengnan Li, Limin Wang, Zhongqiu Liu and Yujing Liu

Chemical Engineering Journal, 2023, 473, 145361
DOI: 10.1016/j.cej.2023.145361

Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch

Rajesh Deka, Jorn D. Steen, Michiel F. Hilbers, Wim G. Roeterdink, Alessandro Iagatti, Ruisheng Xiong, Wybren Jan Buma, Mariangela Di Donato, Andreas Orthaber and Stefano Crespi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202419943

Photoresponsive Azobenzene-Functionalized Shell Cross-Linked Micelles for Selective Asymmetric Transfer Hydrogenation

Fangbei Liu, Peiyuan Qu and Marcus Weck

Org. Lett., 2022, 24, 4099
DOI: 10.1021/acs.orglett.2c00925

Searching the Chemical Space of Bicyclic Dienes for Molecular Solar Thermal Energy Storage Candidates

Andreas Erbs Hillers‐Bendtsen, Jacob Lynge Elholm, Oscar Berlin Obel, Helen Hölzel, Kasper Moth‐Poulsen and Kurt V. Mikkelsen

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202309543