Recent advances in non-precious group metal-based catalysts for water electrolysis and beyond

Hee Jin Kim, Ho Young Kim, Jinwhan Joo, Sang Hoon Joo, June Sung Lim, Jinwoo Lee, Huawei Huang, Minhua Shao, Jue Hu, Jin Young Kim, Byeong Jo Min, Seung Woo Lee, Minsoo Kang, Kwangyeol Lee, Songa Choi, Yeji Park, Yao Wang, Junjun Li, Zhicheng Zhang, Jianmin Ma and Sang-Il Choi

J. Mater. Chem. A, 2022, 10, 50
DOI: 10.1039/D1TA06548C

Regulating the electron density of dual transition metal sulfide heterostructures for highly efficient hydrogen evolution in alkaline electrolytes

Miao Yang, Yimin Jiang, Shu Liu, Mengjie Zhang, Qifei Guo, Wei Shen, Rongxing He, Wei Su and Ming Li

Nanoscale, 2019, 11, 14016
DOI: 10.1039/C9NR03401C

Optimization of iron-doped Ni3S2 nanosheets by disorder engineering for oxygen evolution reaction

Yan Zhu, Haidong Yang, Kai Lan, Kanwal Iqbal, Yang Liu, Ping Ma, Ziming Zhao, Sha Luo, Yutong Luo and Jiantai Ma

Nanoscale, 2019, 11, 2355
DOI: 10.1039/C8NR08469F

High-efficiency overall alkaline seawater splitting: using a nickel–iron sulfide nanosheet array as a bifunctional electrocatalyst

Jie Chen, Longcheng Zhang, Jun Li, Xun He, Yinyuan Zheng, Shengjun Sun, Xiaodong Fang, Dongdong Zheng, Yongsong Luo, Yan Wang, Jing Zhang, Lisi Xie, Zhengwei Cai, Yuntong Sun, Abdulmohsen Ali Alshehri, Qingquan Kong, Chengwu Tang and Xuping Sun

J. Mater. Chem. A, 2023, 11, 1116
DOI: 10.1039/D2TA08568B

Rational design of Cu–Co thiospinel ternary sheet arrays for highly efficient electrocatalytic water splitting

Nan Zang, Zexing Wu, Jie Wang and Wei Jin

J. Mater. Chem. A, 2020, 8, 1799
DOI: 10.1039/C9TA12104H

NiFe-based nanostructures on nickel foam as highly efficiently electrocatalysts for oxygen and hydrogen evolution reactions

Wei Zhang, Daohao Li, Longzhou Zhang, Xilin She and Dongjiang Yang

Journal of Energy Chemistry, 2019, 39, 39
DOI: 10.1016/j.jechem.2019.01.017

Electronic Structure and Crystalline Phase Dual Modulation via Anion–Cation Co-doping for Boosting Oxygen Evolution with Long-Term Stability Under Large Current Density

Jian Chen, Jianpo Chen, Hao Cui and Chengxin Wang

ACS Appl. Mater. Interfaces, 2019, 11, 34819
DOI: 10.1021/acsami.9b08060

Recent Progress on NiFe‐Based Electrocatalysts for the Oxygen Evolution Reaction

Jia Zhao, Ji‐Jie Zhang, Zhao‐Yang Li and Xian‐He Bu

Small, 2020, 16
DOI: 10.1002/smll.202003916

Facile synthesis of flower-like P-doped nickel-iron disulfide microspheres as advanced electrocatalysts for the oxygen evolution reaction

Dongwook Lim, Chaewon Lim, Minji Hwang, Minsoo Kim, Sang Eun Shim and Sung-Hyeon Baeck

Journal of Power Sources, 2021, 490, 229552
DOI: 10.1016/j.jpowsour.2021.229552

Insight into the Boosted Electrocatalytic Oxygen Evolution Performance of Highly Hydrophilic Nickel–Iron Hydroxide

Yi Wei, Cheol-Hwan Shin, Emmanuel Batsa Tetteh, Byong-June Lee and Jong-Sung Yu

ACS Appl. Energy Mater., 2020, 3, 822
DOI: 10.1021/acsaem.9b01952

A novel efficient dual-functional electrocatalyst for overall water splitting based on Ni0.85Se/RGO/CNTs nanocomposite synthesized via different nickel precursors

Hebing Pei, Guigui Liu, Ruibin Guo, Nijuan Liu and Zunli Mo

International Journal of Hydrogen Energy, 2022, 47, 35227
DOI: 10.1016/j.ijhydene.2022.08.130

Hematite-nickel oxide/carbon nanotube composite catalyst for oxygen evolution reaction

Theophile Niyitanga and HaeKyoung Kim

Materials Chemistry and Physics, 2022, 275, 125266
DOI: 10.1016/j.matchemphys.2021.125266

Facile synthesis of self support Fe doped Ni3S2 nanosheet arrays for high performance alkaline oxygen evolution

Qiuyue Chen, Lin Huang, Qingquan Kong, Xuguang An, Xiaoqiang Wu, Weitang Yao and Chenghua Sun

Journal of Electroanalytical Chemistry, 2022, 907, 116047
DOI: 10.1016/j.jelechem.2022.116047

Synthesis and Electronic Modulation of Nanostructured Layered Double Hydroxides for Efficient Electrochemical Oxygen Evolution

Ting Wang, Weiwen Wang, Wenjie Shao, Mingru Bai, Mi Zhou, Shuang Li, Tian Ma, Lang Ma, Chong Cheng and Xikui Liu

ChemSusChem, 2021, 14, 5112
DOI: 10.1002/cssc.202101844

Enhanced Oxygen Evolution in 0.1 % Fe-Doped NiS2 on Carbon Cloth

Shoupik Mullani, Vaibhav Lokhande, Chihoon Kim, Shital Bachankar, Aditi Kumbhar and Taeksoo Ji

Korean. J. Mater. Res., 2025, 35, 51
DOI: 10.3740/MRSK.2025.35.2.51

Interface engineering of N-doped Ni3S2/CoS2 heterostructures as efficient bifunctional catalysts for overall water splitting

Quan Kong, Nanyu Fan, Siyi Chen, Xiaofen Wu, Lihua Liu, Ruifeng Lang, Zeyuan Gao, Hongtao Guan, Chengjun Dong and Gang Chen

Journal of Electroanalytical Chemistry, 2021, 895, 115516
DOI: 10.1016/j.jelechem.2021.115516

FeNi2S4–A Potent Bifunctional Efficient Electrocatalyst for the Overall Electrochemical Water Splitting in Alkaline Electrolyte

Mohamed Barakat Zakaria Hegazy, Judith Zander, Morten Weiss, Christopher Simon, Philipp Gerschel, Sebastian A. Sanden, Mathias Smialkowski, David Tetzlaff, Tobias Kull, Roland Marschall and Ulf‐Peter Apfel

Small, 2024, 20
DOI: 10.1002/smll.202311627

Synergistic Assembly of a CoS@NiFe/Ni Foam Heterostructure Electrocatalyst for Efficient Water Oxidation Catalysis at Large Current Densities

Muheng Wang, Yun Wu, Na Li, Fei Zhao, Qiang Zhao, Jinping Li and Guang Liu

Chemistry An Asian Journal, 2020, 15, 1484
DOI: 10.1002/asia.202000213

Electronic structure regulation and polysulfide bonding of Co-doped (Ni, Fe)1+xS enable highly efficient and stable electrocatalytic overall water splitting

Yuan Huang, Li-Wen Jiang, Hong Liu and Jian-Jun Wang

Chemical Engineering Journal, 2022, 441, 136121
DOI: 10.1016/j.cej.2022.136121

Graphene-Quantum-Dots-induced facile growth of porous molybdenum doped Ni3S2 nanoflakes as efficient bifunctional electrocatalyst for overall water splitting

Jiefei Li, Xueqiong Zhang, Zehao Zhang, Zhenyu Li, Mingming Gao, Hang Wei and Haibin Chu

Electrochimica Acta, 2019, 304, 487
DOI: 10.1016/j.electacta.2019.03.023

Single Atoms and Clusters Based Nanomaterials for Hydrogen Evolution, Oxygen Evolution Reactions, and Full Water Splitting

Siraj Sultan, Jitendra N. Tiwari, Aditya Narayan Singh, Shynggys Zhumagali, Miran Ha, Chang Woo Myung, Pandiarajan Thangavel and Kwang S. Kim

Advanced Energy Materials, 2019, 9
DOI: 10.1002/aenm.201900624

A Review of Transition Metal Boride, Carbide, Pnictide, and Chalcogenide Water Oxidation Electrocatalysts

Kenta Kawashima, Raúl A. Márquez, Lettie A. Smith, Rinish Reddy Vaidyula, Omar A. Carrasco-Jaim, Ziqing Wang, Yoon Jun Son, Chi L. Cao and C. Buddie Mullins

Chem. Rev., 2023, 123, 12795
DOI: 10.1021/acs.chemrev.3c00005

Sulfur Mismatch Substitution in Layered Double Hydroxides as Efficient Oxygen Electrocatalysts for Flexible Zinc–Air Batteries

Xiaotong Han, Nannan Li, Jae Sung Baik, Peixun Xiong, Yingbo Kang, Qingyun Dou, Qing Liu, Jin Yong Lee, Chul Sung Kim and Ho Seok Park

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202212233

Co-anion exchange prepared 2D structure Ni(Co,Fe)PS for efficient overall water electrolysis

Yongjae Jeung, Hyogyun Roh and Kijung Yong

Applied Surface Science, 2022, 576, 151720
DOI: 10.1016/j.apsusc.2021.151720

Tailoring NiFeS microstructure through electrodeposition for high-performance anion exchange membrane water electrolysis

Marina Medina, Anelisse Brunca da Silva, Lu Xia, Wulyu Jiang, Andreas Glüsen, Caue Ribeiro and Lucia Helena Mascaro

Journal of Power Sources, 2025, 657, 238128
DOI: 10.1016/j.jpowsour.2025.238128

Facile synthesis of NiSe2 particles with highly efficient electrocatalytic oxygen evolution reaction

Jingchao Zhang, Bei Jiang, Jingru Zhang, Ruguang Li, Nana Zhang, Ruixin Liu, Jiakai Li, Daojun Zhang and Renchun Zhang

Materials Letters, 2019, 235, 53
DOI: 10.1016/j.matlet.2018.09.163

Oxygen-Evolution Catalysts Based on Iron-Mediated Nickel Metal–Organic Frameworks

Zixia Wan, Dandan Yang, Judan Chen, Jianniao Tian, Tayirjan Taylor Isimjan and Xiulin Yang

ACS Appl. Nano Mater., 2019, 2, 6334
DOI: 10.1021/acsanm.9b01330

A review on NiFe-based electrocatalysts for efficient alkaline oxygen evolution reaction

Jamesh Mohammed-Ibrahim

Journal of Power Sources, 2020, 448, 227375
DOI: 10.1016/j.jpowsour.2019.227375

Co, N co-doping controlled preparation of FeS/FeS2 heterojunction for efficient overall water splitting

Meijing Cao, Jing Tian, Yang Zhou, WenLong Liu, Jin Dang, Weibing Li, Jiarun Li and Lei Wang

International Journal of Hydrogen Energy, 2024, 84, 900
DOI: 10.1016/j.ijhydene.2024.06.110

Monitoring oxygen-vacancy ratio in NiFe-based electrocatalysts during oxygen evolution reaction in alkaline electrolyte

Hyunki Kim, Junhyeong Kim and Sang Hyun Ahn

Journal of Industrial and Engineering Chemistry, 2019, 72, 273
DOI: 10.1016/j.jiec.2018.12.028

Enhancing the oxygen evolution reaction performance of NiFeOOH electrocatalyst for Zn-air battery by N-doping

Jiawang Li, Jidong Song, Bo-Ying Huang, Guofeng Liang, Wanli Liang, Guoju Huang, Yan Qi Jin, Hao Zhang, Fangyan Xie, Jian Chen, Nan Wang, Yanshuo Jin, Xi-Bo Li and Hui Meng

Journal of Catalysis, 2020, 389, 375
DOI: 10.1016/j.jcat.2020.06.022

A Review on Advanced FeNi-Based Catalysts for Water Splitting Reaction

Dongze Li, Hui Liu and Ligang Feng

Energy Fuels, 2020, 34, 13491
DOI: 10.1021/acs.energyfuels.0c03084

Structural design of cobalt phosphate on nickel foam for electrocatalytic oxygen evolution

Chunfeng Zhu, Zhongyuan Yu, Tong Lin, Jintang Li and Xuetao Luo

Nanotechnology, 2021, 32, 305702
DOI: 10.1088/1361-6528/abf454

Fe Doped Ni3S2 Nanosheet Arrays for Efficient and Stable Electrocatalytic Overall Urea Splitting

Chang Liu, Fang Li, Shan Xue, Haili Lin, Yue Sun, Jing Cao and Shifu Chen

ACS Appl. Energy Mater., 2022, 5, 1183
DOI: 10.1021/acsaem.1c03536

Insight into the role of sulfur in increasing intrinsic activity of Ni–Fe for efficient water splitting electrocatalysis

Wei Xu, Shuan Zhao, Jun-Peng Zhang, Xu Yang, Yu-Xia Tang, Yi-Wen Han and Yu Shen

International Journal of Hydrogen Energy, 2023, 48, 18315
DOI: 10.1016/j.ijhydene.2023.01.341

Surface reconstruction of Fe(III)/NiS nanotubes for generating high-performance oxygen-evolution catalyst

Mengxiao Zhong, Weimo Li, Junjie Chen, Siyu Ren, Ruikai Qi, Ce Wang and Xiaofeng Lu

Separation and Purification Technology, 2023, 310, 123164
DOI: 10.1016/j.seppur.2023.123164

Designing 3d dual transition metal electrocatalysts for oxygen evolution reaction in alkaline electrolyte: Beyond oxides

Kexin Wang, Xinyue Wang, Zhongjian Li, Bin Yang, Min Ling, Xiang Gao, Jianguo Lu, Qiurong Shi, Lecheng Lei, Gang Wu and Yang Hou

Nano Energy, 2020, 77, 105162
DOI: 10.1016/j.nanoen.2020.105162

Controllable growth of Fe-doped NiS2 on NiFe-carbon nanofibers for boosting oxygen evolution reaction

Mengxiao Zhong, Na Song, Cuimei Li, Ce Wang, Wei Chen and Xiaofeng Lu

Journal of Colloid and Interface Science, 2022, 614, 556
DOI: 10.1016/j.jcis.2022.01.134

Research progress on surface reconstruction of transition metal sulfides (TMS, M=Fe, Co, Ni) as precatalysts for oxygen evolution reaction

Shiqi Zhang, Ying Cheng, Peng Wang, Xuefei Lei, Junhua You, Rui Guo and Hangzhou Zhang

International Journal of Hydrogen Energy, 2024, 51, 545
DOI: 10.1016/j.ijhydene.2023.10.122

In-situ growth of hierarchically porous FeNi2S4/Ti3C2Tx nanosheets arrays on Ni-Fe foam for overall water splitting

Zhimin He, Zhengjie Tan, Yu Pu, Qiyu Li, Wei Hong, Rong Li and Xinglong Gou

Journal of Solid State Chemistry, 2023, 327, 124264
DOI: 10.1016/j.jssc.2023.124264

Facile synthesis and electrochemical performances of three dimensional Ni3S2 as bifunctional electrode for overall water splitting

Kexin Cui, Jincheng Fan, Songyang Li, Shidong Li, Moukaila Fatiya Khadidja, Jianghong Wu, Mingyu Wang, Jianxin Lai, Hong-Guang Jin, Wenbin Luo and Zisheng Chao

Materials Science and Engineering: B, 2021, 263, 114875
DOI: 10.1016/j.mseb.2020.114875

Recent developments in metal phosphide and sulfide electrocatalysts for oxygen evolution reaction

Lishan Peng, Syed Shoaib Ahmad Shah and Zidong Wei

Chinese Journal of Catalysis, 2018, 39, 1575
DOI: 10.1016/S1872-2067(18)63130-4

Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting

Yanna Guo, Teahoon Park, Jin Woo Yi, Joel Henzie, Jeonghun Kim, Zhongli Wang, Bo Jiang, Yoshio Bando, Yoshiyuki Sugahara, Jing Tang and Yusuke Yamauchi

Advanced Materials, 2019, 31
DOI: 10.1002/adma.201807134

Preparation of Molybdenum doped Nickel Sulfides Supported on Nickel Foam via Two-step Electrodeposition for Oxygen Evolution Reaction

Yi-Wen Dong, Bao-Yu Guo, Qin-Wei Chen and Bin Dong

International Journal of Electrochemical Science, 2020, 15, 5529
DOI: 10.20964/2020.06.88

Designing an FeIII-Doped Nickel Sulfide/Carbon Nanotube Hybrid Catalyst for Alkaline Electrolyte Membrane Water Electrolyzers and Zn–Air Battery Performances

Pandian Ganesan, Aleksandar Staykov, Hiroaki Shu, Mitsugu Uejima and Naotoshi Nakashima

ACS Appl. Energy Mater., 2020, 3, 10961
DOI: 10.1021/acsaem.0c01931

NiFe/(Ni,Fe)3S2 Core/Shell Nanowire Arrays as Outstanding Catalysts for Electrolytic Water Splitting at High Current Densities

Cheng‐Ting Hsieh, Xui‐Fang Chuah, Chun‐Lung Huang, Hao‐Wei Lin, Yu‐An Chen and Shih‐Yuan Lu

Small Methods, 2019, 3
DOI: 10.1002/smtd.201900234

One-step preparation of Fe-doped Ni3S2/rGO@NF electrode and its superior OER performances

Danmin Shao, Pengwei Li, Ruizhi Zhang, Chunhua Zhao, Deqiang Wang and Chongjun Zhao

International Journal of Hydrogen Energy, 2019, 44, 2664
DOI: 10.1016/j.ijhydene.2018.11.054

Enhancing Oxygen Evolution Electrocatalysis via the Intimate Hydroxide–Oxide Interface

Dandan Zhao, Yecan Pi, Qi Shao, Yonggang Feng, Ying Zhang and Xiaoqing Huang

ACS Nano, 2018, 12, 6245
DOI: 10.1021/acsnano.8b03141

Fe‐Doped Ni3S2 Nanowires with Surface‐Restricted Oxidation Toward High‐Current‐Density Overall Water Splitting

Xiangyu Wang, Wuzhengzhi Zhang, Junliang Zhang and Zhengcui Wu

ChemElectroChem, 2019, 6, 4550
DOI: 10.1002/celc.201901201

Tunable nanocotton-like amorphous ternary Ni-Co-B: A highly efficient catalyst for enhanced oxygen evolution reaction

Shuai Wang, Ping He, Zhengwei Xie, Lingpu Jia, Mingqian He, Xingquan Zhang, Faqin Dong, Huanhuan Liu, Ying Zhang and Caixia Li

Electrochimica Acta, 2019, 296, 644
DOI: 10.1016/j.electacta.2018.11.099

Advanced opportunities and insights on the influence of nitrogen incorporation on the physico-/electro-chemical properties of robust electrocatalysts for electrocatalytic energy conversion

Sundaram Chandrasekaran, Chenle Zhang, Yiqing Shu, Huide Wang, Sanming Chen, Thomas Nesakumar Jebakumar Immanuel Edison, Yongping Liu, Namachivayam Karthik, R.D.K. Misra, Libo Deng, Peng Yin, Yanqi Ge, Omar A. Al-Hartomy, Ahmed Al-Ghamdi, Swelm Wageh, Peixin Zhang, Chris Bowen and Zhang Han

Coordination Chemistry Reviews, 2021, 449, 214209
DOI: 10.1016/j.ccr.2021.214209

N and Mo Dual Modulating Electronic Structure of NiS Nanosheet Arrays for Boosted Full Water Electrolysis

Yuxue Zhou, Yuxing Lu, Tengfei Li, Chenjie Bian, Min Zhou and Xiangdong Meng

ACS Appl. Nano Mater., 2025, 8, 15347
DOI: 10.1021/acsanm.5c02861

Self‐Derivation and Surface Reconstruction of Fe‐Doped Ni3S2 Electrode Realizing High‐Efficient and Stable Overall Water and Urea Electrolysis

Derun Li, Wenjing Wan, Zhaowu Wang, Hengyi Wu, Shixin Wu, Tao Jiang, Guangxu Cai, Changzhong Jiang and Feng Ren

Advanced Energy Materials, 2022, 12
DOI: 10.1002/aenm.202201913

Mixed metal sulfides (FeNiS2) nanosheets decorated reduced graphene oxide for efficient electrode materials for supercapacitors

Milon Miah, Poulami Hota, Tapas Kumar Mondal, Rui Chen and Shyamal K. Saha

Journal of Alloys and Compounds, 2023, 933, 167648
DOI: 10.1016/j.jallcom.2022.167648

Electrodeposition of NiS/Ni2P nanoparticles embedded in amorphous Ni(OH)2 nanosheets as an efficient and durable dual-functional electrocatalyst for overall water splitting

Qingli Xu, Wenluan Gao, Miao Wang, Gang Yuan, Xiaona Ren, Rong Zhao, Sida Zhao and Qingfa Wang

International Journal of Hydrogen Energy, 2020, 45, 2546
DOI: 10.1016/j.ijhydene.2019.11.217

Reduced graphene oxide composite Ni3S2 microspheres grown directly on nickel foam as an efficient electrocatalyst for OER

Zhenxin Zhao, Jianming Liao, Ruijie Shi, Xuan Zhao, Zikang Wang, Jiajun Li, Qing Li, Daxiang Yang, Ming Nie and Yuping Liu

International Journal of Hydrogen Energy, 2023, 48, 27441
DOI: 10.1016/j.ijhydene.2023.03.276

Ru doping NiCoP hetero-nanowires with modulated electronic structure for efficient overall water splitting

Jianmei Cen, Pei Kang Shen and Yanfei Zeng

Journal of Colloid and Interface Science, 2022, 610, 213
DOI: 10.1016/j.jcis.2021.12.028