Reaction of potassium phosphide KP(iPr)Ter with chalcogens, heteroallenes and an acyl chloride

Lilian Sophie Szych, Karsten Paul Lüdtke, Yannic Pilopp, Jonas Bresien, Alexander Villinger and Axel Schulz

Dalton Trans., 2021, 50, 16568
DOI: 10.1039/D1DT03400F

π-Delocalization in phosphaphthalimide and its ambident reactivity (O/P) toward main-group electrophiles

Qi Shen, Jiashi Xu and Xiaodan Chen

Dalton Trans., 2022, 51, 10240
DOI: 10.1039/D2DT01163H

Insight into fragmentation of a phosphirane to form phosphinidene complexes: an illustration with the 1-phenylselenylphosphirane W(CO)5 complex

Lingzhi Qiu, Qiaoyu Zhang, Donghui Wei, Rongqiang Tian and Zheng Duan

Dalton Trans., 2022, 51, 3046
DOI: 10.1039/D1DT04208D

Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene

Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady and Jose M. Goicoechea

Chem. Sci., 2020, 11, 862
DOI: 10.1039/C9SC05969E

The phosphinoboration of acyl chlorides

Maia C. Murphy, Alina Trofimova, James H. W. LaFortune, Christopher M. Vogels, Stephen J. Geier, Justin F. Binder, Charles L. B. Macdonald, Douglas W. Stephan and Stephen A. Westcott

Dalton Trans., 2020, 49, 5092
DOI: 10.1039/D0DT00579G

Phosphanylphosphaalkenes as precursors for metallaphosphaalkene complexes

Aleksandra Ziółkowska, Tomasz Kruczyński, Dietrich Gudat and Łukasz Ponikiewski

Dalton Trans., 2024, 53, 19107
DOI: 10.1039/D4DT03012E

Copper-catalyzed phosphorothiolation/seleno(telluro) phosphorylation of vinylsulfonium salts with P(iii)-nucleophiles via the insertion of elemental sulfur/selenium/tellurium

Biquan Xiong, Siya Zheng, Weifeng Xu, Yu Liu, Longzhi Zhu, Ke-Wen Tang, Zelin Sun and Wai-Yeung Wong

Org. Chem. Front., 2025, 12, 936
DOI: 10.1039/D4QO02154A

Reactive FLP–alkyne addition products: a route to anionic and zwitterionic phosphines

Hyehwang Kim and Douglas W. Stephan

Dalton Trans., 2023, 52, 5023
DOI: 10.1039/D3DT00607G

Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions

Suma Basappa, Ramesh Bhawar, D. H. Nagaraju and Shubhankar Kumar Bose

Dalton Trans., 2022, 51, 3778
DOI: 10.1039/D1DT03994F

Reactivity of the phosphaethynolate anion with stabilized carbocations: mechanistic studies and synthetic applications

Thi Hong Van Nguyen, Saloua Chelli, Sonia Mallet-Ladeira, Martin Breugst and Sami Lakhdar

Chem. Sci., 2024, 15, 14406
DOI: 10.1039/D4SC03518F

A case study on the conversion of Li/Cl phosphinidenoid into phosphinidene complexes

Philip Junker, Zheng-Wang Qu, Tim Kalisch, Gregor Schnakenburg, Arturo Espinosa Ferao and Rainer Streubel

Dalton Trans., 2021, 50, 739
DOI: 10.1039/D0DT03884A

Phospha-Peterson reactions with esters and thioesters: isolation of phosphaalkenes bearing C-heteroatom substituents

Aaron A. Mitchell, Paul A. Heine, Joseph Chang, Adam De Paolis, Brian O. Patrick and Derek P. Gates

Dalton Trans., 2025, 54, 14277
DOI: 10.1039/D5DT01781E

Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins

Tiansi Xin, Michael B. Geeson, Hui Zhu, Zheng-Wang Qu, Stefan Grimme and Christopher C. Cummins

Chem. Sci., 2022, 13, 12696
DOI: 10.1039/D2SC05011K

Phosphine‐Stabilized Pnictinidenes

Dominik Raiser, Klaus Eichele, Hartmut Schubert and Lars Wesemann

Chemistry A European J, 2021, 27, 14073
DOI: 10.1002/chem.202102320

Organophosphorus Synthesis beyond P-Cl Bond: The Development of Shelf-stable Reagents for [RP] Transfer

Vadim D. Romanenko

COC, 2024, 28, 1483
DOI: 10.2174/0113852728323258240613061150

Cobalt‐Mediated [3+1] Fragmentation of White Phosphorus: Access to Acylcyanophosphanides

Sebastian Hauer, Thomas M. Horsley Downie, Gábor Balázs, Kai Schwedtmann, Jan J. Weigand and Robert Wolf

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202317170

3,5-Diphenyl-2-phosphafuran: Synthesis, Structure, and Thermally Reversible [4 + 2] Cycloaddition Chemistry

Martin-Louis Y. Riu and Christopher C. Cummins

J. Org. Chem., 2020, 85, 14810
DOI: 10.1021/acs.joc.0c02025

Metallaphosphirenes with σ‐Aromaticity: Capture of Phosphorus Atom by Metalla‐Aromatics

Xin Yang, Xiaoyan Zhang, Yapeng Cai, Haiping Xia and Hong Zhang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202512214

Metallaphosphirenes with σ‐Aromaticity: Capture of Phosphorus Atom by Metalla‐Aromatics

Xin Yang, Xiaoyan Zhang, Yapeng Cai, Haiping Xia and Hong Zhang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202512214

Cobalt‐Mediated [3+1] Fragmentation of White Phosphorus: Access to Acylcyanophosphanides

Sebastian Hauer, Thomas M. Horsley Downie, Gábor Balázs, Kai Schwedtmann, Jan J. Weigand and Robert Wolf

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202317170

Synthesis of Phosphet-2-one Derivatives via Phosphinidene Transfer to Cyclopropenones

Tiansi Xin and Christopher C. Cummins

J. Am. Chem. Soc., 2023, 145, 25989
DOI: 10.1021/jacs.3c11263

Non‐conventional Behavior of a 2,1‐Benzazaphosphole: Heterodiene or Hidden Phosphinidene?

Vít Kremláček, Erik Kertész, Zoltán Benkő, Milan Erben, Robert Jirásko, Aleš Růžička, Roman Jambor and Libor Dostál

Chemistry A European J, 2021, 27, 13149
DOI: 10.1002/chem.202101686

A Terminal Chlorophosphinidene Complex

Josh Abbenseth and Sven Schneider

Zeitschrift anorg allge chemie, 2020, 646, 565
DOI: 10.1002/zaac.202000010

Isolation of an elusive phosphatetrahedrane

Martin-Louis Y. Riu, Rebecca L. Jones, Wesley J. Transue, Peter Müller and Christopher C. Cummins

Sci. Adv., 2020, 6
DOI: 10.1126/sciadv.aaz3168

Identification of Reactive Intermediates Relevant to Dimethylgermylene Group Transfer Reactions of an Anthracene-Based Precursor

Michael B. Geeson, Wesley J. Transue and Christopher C. Cummins

Organometallics, 2019, 38, 3229
DOI: 10.1021/acs.organomet.9b00410

Diphospha‐Ureas from the Phosphaketene Ph3GePCO

Kevin M. Szkop, Andrew R. Jupp, Hlib Razumkov, Maotong Xu and Douglas W. Stephan

Chemistry A European J, 2019, 25, 10084
DOI: 10.1002/chem.201902789

An Azophosphine Synthetic Equivalent of Mesitylphosphaazide and Its 1,3-Dipolar Cycloaddition Reactions

Martin-Louis Y. Riu, Wesley J. Transue, Jan M. Rall and Christopher C. Cummins

J. Am. Chem. Soc., 2021, 143, 7635
DOI: 10.1021/jacs.1c03333

Indium-Catalyzed Reductive Coupling Enabled Efficient Synthesis of Acylphosphine Oxides and Diphosphines

Dongdong Xu, Ming Yu Jin, Yu Chen, Dingnuo Han, Lizhi Tao and Xiangyou Xing

ACS Catal., 2024, 14, 3241
DOI: 10.1021/acscatal.3c05947

Formation, Reactivity and Decomposition of Aryl Phospha‐Enolates

Stephanie J. Urwin and Jose M. Goicoechea

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203081

The story of acyl phosphines: Synthesis, reactivity, and catalytic applications

Pawan Kumar, Urvashi Sharma and Guddekoppa S. Ananthnag

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6672

Acylation Reactions of Dibenzo‐7‐phosphanorbornadiene: DFT Mechanistic Insights

Zheng‐Wang Qu, Hui Zhu and Stefan Grimme

ChemistryOpen, 2019, 8, 807
DOI: 10.1002/open.201900176

Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes

Michael B. Geeson, Wesley J. Transue and Christopher C. Cummins

J. Am. Chem. Soc., 2019, 141, 13336
DOI: 10.1021/jacs.9b07069