Stable and easily available sulfide surrogates allow a stereoselective activation of alcohols

Jérémy Merad, Ján Matyašovský, Tobias Stopka, Bogdan R. Brutiu, Alexandre Pinto, Martina Drescher and Nuno Maulide

Chem. Sci., 2021, 12, 7770
DOI: 10.1039/D1SC01602D

Nickel-catalyzed cross-electrophile coupling of aryl thiols with aryl bromides via C–S bond activation

Hao Xu, Cai-Yu He, Bo-Jie Huo, Jia-Wen Jing, Chengping Miao, Weidong Rao, Xue-Qiang Chu, Xiaocong Zhou and Zhi-Liang Shen

Org. Chem. Front., 2023, 10, 5171
DOI: 10.1039/D3QO01236K

Transition-metal mediated carbon–sulfur bond activation and transformations: an update

Jiang Lou, Quannan Wang, Ping Wu, Hongmei Wang, Yong-Gui Zhou and Zhengkun Yu

Chem. Soc. Rev., 2020, 49, 4307
DOI: 10.1039/C9CS00837C

Ni-catalyzed C–S bond construction and cleavage

Su Huang, Ming Wang and Xuefeng Jiang

Chem. Soc. Rev., 2022, 51, 8351
DOI: 10.1039/D2CS00553K

A review on the syntheses of Dronabinol and Epidiolex as classical cannabinoids with various biological activities including those against SARS-COV2

Neda Tadayon and Ali Ramazani

J IRAN CHEM SOC, 2021, 18, 2517
DOI: 10.1007/s13738-021-02212-0

Copper-Catalyzed Reductive Alkylation of β-Acyl Allylic Thioethers with Alkyl Bromides to Access α-Branched Enones with Flexible Alkyl Chains

Qin-Qin Dang, Xu Tian, Hui Li, Xue-Ni Liu and Zhen-Kang Wen

Org. Lett., 2025, 27, 4355
DOI: 10.1021/acs.orglett.5c01098

Oxidative cleavage and ammoxidation of organosulfur compounds via synergistic Co-Nx sites and Co nanoparticles catalysis

Huihui Luo, Shuainan Tian, Hongliang Liang, He Wang, Shuang Gao and Wen Dai

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-38614-2

Nickel-Catalyzed Direct Cross-Coupling of Aryl Thioether with Aryl Bromide

Na-Na Ma, Xuan-Bo Hu, Yuan-Shuai Wu, Ya-Wen Zheng, Mengtao Ma, Xue-Qiang Chu, Hao Xu, Haiqing Luo and Zhi-Liang Shen

Org. Lett., 2023, 25, 1771
DOI: 10.1021/acs.orglett.3c00518

Two-Step Formation of Substituted Pyridines from Iodoenones

Carl Malenfant, Maxime Denis and Sylvain Canesi

J. Org. Chem., 2025, 90, 580
DOI: 10.1021/acs.joc.4c02502

S-methylation of organosulfur substrates: A comprehensive overview

Saad Moulay

Phosphorus, Sulfur, and Silicon and the Related Elements, 2021, 196, 702
DOI: 10.1080/10426507.2021.1925672

Nickel-Catalyzed Desulfurative Cross-Coupling of Aryl Iodides with Heteroaromatic Thioethers via C–S Bond Cleavage

Pingliang Zhu, Yu Zhao, Shaowen Ling, Baolong Xu, Hui Liu, Xinjin Li and Feng-Gang Sun

J. Org. Chem., 2024, 89, 12001
DOI: 10.1021/acs.joc.4c00678

Tandem Ene/[4 + 2] Cycloaddition Reaction for the Synthesis of 9-Benzylphenanthrenes from Arynes and α-(Bromomethyl)styrenes

Yun Sa, Xin Lv, Jia-Yu Yao, Xu-Yang Lu, Ai-Bin Wu, Wen-Ming Shu and Wei-Chu Yu

J. Org. Chem., 2023, 88, 8034
DOI: 10.1021/acs.joc.3c00051

Ni-catalyzed C–S bond cleavage of aryl 2-pyridyl thioethers coupling with alkyl and aryl thiols

Cheng-Yi Wang, Rui Tian and Yong-Ming Zhu

Tetrahedron, 2021, 99, 132453
DOI: 10.1016/j.tet.2021.132453

Well‐Defined NHC−Ni Complexes as Catalysts: Preparation, Structures and Mechanistic Studies in Cross‐Coupling Reactions

Kouki Matsubara

The Chemical Record, 2021, 21, 3925
DOI: 10.1002/tcr.202100204

Palladium-Catalyzed Arylthiolation of Alkynes Enabled by Surmounting Competitive Dimerization of Alkynes

Daisuke Uno, Keisuke Nogi and Hideki Yorimitsu

Org. Lett., 2019, 21, 8295
DOI: 10.1021/acs.orglett.9b03056

Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis

Andrew L. Clevenger, Ryan M. Stolley, Justis Aderibigbe and Janis Louie

Chem. Rev., 2020, 120, 6124
DOI: 10.1021/acs.chemrev.9b00682

Oxidative C–S bond cleavage of organosulfur compounds with singlet oxygen generated from trans-5-hydroperoxy-3,5-dimethyl-1,2-dioxolan-3-yl ethaneperoxate

Zohreh Najminejad and Davood Azarifar

Monatsh Chem, 2025, 156, 481
DOI: 10.1007/s00706-025-03308-6

Nickel-catalyzed cyanation of C—S bond using CO2 and NH3

Qin Shi, Yang Li, Yudong Li, Yanan Dong, Shaoli Liu, Zhen Li, Lin He, Liwei Sun and Yuehui Li

Journal of Catalysis, 2025, 442, 115870
DOI: 10.1016/j.jcat.2024.115870

Reduction of CO2 with NaBH4/I2 for the Conversion of Thiophenols to Aryl Methyl Sulfides

Bo Zhang, Zhengning Fan, Zhiqiang Guo and Chanjuan Xi

J. Org. Chem., 2019, 84, 8661
DOI: 10.1021/acs.joc.9b01180

Synthetic Strategies for (−)‐Cannabidiol and Its Structural Analogs

Byunghyuck Jung, Jungkyu K. Lee, Jungnam Kim, Eunhye K. Kang, Sang Yeong Han, Hee‐Yoon Lee and Insung S. Choi

Chemistry An Asian Journal, 2019, 14, 3749
DOI: 10.1002/asia.201901179

Transition-metal-free methylthiolation of aryl fluorides with S-methylisothiourea sulfate in PEG-400

Xiangmei Wu and Dayun Huang

Tetrahedron, 2025, 184, 134785
DOI: 10.1016/j.tet.2025.134785

Nickel‐katalysierte inter‐ und intramolekulare Arylthioether‐Metathese durch reversible Arylierung

Tristan Delcaillau, Alessandro Bismuto, Zhong Lian and Bill Morandi

Angewandte Chemie, 2020, 132, 2126
DOI: 10.1002/ange.201910436

Organophosphorus-Catalyzed “Dual-Substrate Deoxygenation” Strategy for C–S Bond Formation from Sulfonyl Chlorides and Alcohols/Acids

Gang Sun, Jing Li, Xin Liu, Yiting Liu, Xiaoan Wen, Hongbin Sun and Qing-Long Xu

J. Org. Chem., 2023, 88, 8628
DOI: 10.1021/acs.joc.3c00532

Synthesis of ethane from CO 2 by a methyl transferase–inspired molecular catalyst

Suman Patra, Souvik Dinda, Soumili Ghosh, Triparna Roy and Abhishek Dey

Proc. Natl. Acad. Sci. U.S.A., 2025, 122
DOI: 10.1073/pnas.2417764122

Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers

Tristan Delcaillau, Philip Boehm and Bill Morandi

J. Am. Chem. Soc., 2021, 143, 3723
DOI: 10.1021/jacs.1c00529

Nickel-Catalyzed Alkylation or Reduction of Allylic Alcohols with Alkyl Grignard Reagents

Bo Yang and Zhong-Xia Wang

J. Org. Chem., 2020, 85, 4772
DOI: 10.1021/acs.joc.0c00008

Multifaceted Hidden Catalysis Revealed by Mechanistic Analysis of FeBr3‐Catalysed Arene Borylation

Luke Britton, Andrew D. Bage, Sarah L. McOnie and Stephen P. Thomas

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202423929

Desulfurative Functionalization of β-Acyl Allylic Sulfides with N–H Free Indoles Highly Regioselective at C3 and N1 Positions: Rapid Access to α-Branched Enones

Qin-Qin Dang, Xue-Ni Liu, Hui Li and Zhen-Kang Wen

J. Org. Chem., 2024, 89, 5200
DOI: 10.1021/acs.joc.4c00205

Dehalogenative Deuteration of Unactivated Alkyl Halides Using D2O as the Deuterium Source

Aiyou Xia, Xin Xie, Xiaoping Hu, Wei Xu and Yuanhong Liu

J. Org. Chem., 2019, 84, 13841
DOI: 10.1021/acs.joc.9b02026

Two Catalytic Protocols for the Synthesis of N‐Aryl Sulfoximines From Aryl Thianthrenium Salts

Liting Wang, Pan Gong and Lei Shi

Adv Synth Catal, 2026, 368
DOI: 10.1002/adsc.70350

Remote C–H Activation Strategy Enables Total Syntheses of Nortriterpenoids (±)-Walsucochin B and (±)-Walsucochinoids M and N

Xinyue Chen, Danyang Zhang, Dan Xu, Huan Zhou and Gong Xu

Org. Lett., 2020, 22, 6993
DOI: 10.1021/acs.orglett.0c02548

Nickel-Catalyzed Cyanation of Aryl Thioethers

Tristan Delcaillau, Adrian Woenckhaus-Alvarez and Bill Morandi

Org. Lett., 2021, 23, 7018
DOI: 10.1021/acs.orglett.1c02285

Generation of Organozinc Reagents from Arylsulfonium Salts Using a Nickel Catalyst and Zinc Dust

Kodai Yamada, Tomoyuki Yanagi and Hideki Yorimitsu

Org. Lett., 2020, 22, 9712
DOI: 10.1021/acs.orglett.0c03782

t-BuOK-promoted methylthiolation of aryl fluorides with dimethyldisulfide under transition-metal-free and mild conditions

Dayun Huang and Xiangmei Wu

Journal of Fluorine Chemistry, 2021, 245, 109778
DOI: 10.1016/j.jfluchem.2021.109778

Synthesis of Furfural Sulfides and 4‐Alkylthiopyridines via Heterocyclization of α‐Acyl Ketene Dithioacetals

Xiaoxuan Zhang, Jian Chang, Chong Chen, Qianqian Zhai, Shengnan Li and Xiaoning Song

Adv Synth Catal, 2023, 365, 3622
DOI: 10.1002/adsc.202300574

Nickel‐Catalyzed Inter‐ and Intramolecular Aryl Thioether Metathesis by Reversible Arylation

Tristan Delcaillau, Alessandro Bismuto, Zhong Lian and Bill Morandi

Angew Chem Int Ed, 2020, 59, 2110
DOI: 10.1002/anie.201910436

Nickel‐Catalyzed Thiolation of Aryl Nitriles

Tristan Delcaillau and Bill Morandi

Chemistry A European J, 2021, 27, 11823
DOI: 10.1002/chem.202101273

Multifaceted Hidden Catalysis Revealed by Mechanistic Analysis of FeBr3‐Catalysed Arene Borylation

Luke Britton, Andrew D. Bage, Sarah L. McOnie and Stephen P. Thomas

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202423929