Olivine LiFePO4: the remaining challenges for future energy storage

Jiajun Wang and Xueliang Sun

Energy Environ. Sci., 2015, 8, 1110
DOI: 10.1039/C4EE04016C

Nanostructured flexible Mg-modified LiMnPO4 matrix as high-rate cathode materials for Li-ion batteries

Qi Lu, Gregory S. Hutchings, Yang Zhou, Huolin L. Xin, Haimei Zheng and Feng Jiao

J. Mater. Chem. A, 2014, 2, 6368
DOI: 10.1039/C4TA00654B

Unexpected discovery of low-cost maricite NaFePO4as a high-performance electrode for Na-ion batteries

Jongsoon Kim, Dong-Hwa Seo, Hyungsub Kim, Inchul Park, Jung-Keun Yoo, Sung-Kyun Jung, Young-Uk Park, William A. Goddard III and Kisuk Kang

Energy Environ. Sci., 2015, 8, 540
DOI: 10.1039/C4EE03215B

A novel cationic-ordering fluoro-polyanionic cathode LiV0.5Fe0.5PO4F and its single phase Li+ insertion/extraction behaviour

Zhen-Dong Huang, Yuki Orikasa, Titus Masese, Kentaro Yamamoto, Takuya Mori, Taketoshi Minato and Yoshiharu Uchimoto

RSC Adv., 2013, 3, 22935
DOI: 10.1039/c3ra44094j

Fast synthesis of carbon microspheres via a microwave-assisted reaction for sodium ion batteries

Taiqiang Chen, Likun Pan, Ting Lu, Conglong Fu, Daniel H. C. Chua and Zhuo Sun

J. Mater. Chem. A, 2014, 2, 1263
DOI: 10.1039/C3TA14037G

Na2Fe2F7: a fluoride-based cathode for high power and long life Na-ion batteries

Hyunyoung Park, Yongseok Lee, Min-kyung Cho, Jungmin Kang, Wonseok Ko, Young Hwa Jung, Tae-Yeol Jeon, Jihyun Hong, Hyungsub Kim, Seung-Taek Myung and Jongsoon Kim

Energy Environ. Sci., 2021, 14, 1469
DOI: 10.1039/D0EE02803G

Unexpectedly high electrochemical performances of a monoclinic Na2.4V2(PO4)3/conductive polymer composite for Na-ion batteries

Yongseok Lee, Jung-Keun Yoo, Youngseok Oh, Hyunyoung Park, Wonseok Go, Seung-Taek Myung and Jongsoon Kim

J. Mater. Chem. A, 2018, 6, 17571
DOI: 10.1039/C8TA06238B

Self-assembled graphene and LiFePO4 composites with superior high rate capability for lithium ion batteries

Wen-Bin Luo, Shu-Lei Chou, Yu-Chun Zhai and Hua-Kun Liu

J. Mater. Chem. A, 2014, 2, 4927
DOI: 10.1039/c3ta14471b

How to make lithium iron phosphate better: a review exploring classical modification approaches in-depth and proposing future optimization methods

Zhigao Yang, Yu Dai, Shengping Wang and Jingxian Yu

J. Mater. Chem. A, 2016, 4, 18210
DOI: 10.1039/C6TA05048D

Elucidating lithium-ion diffusion kinetics in cation-disordered rocksalt cathodes

Byungwook Kang, Jonghun Park, Byunghoon Kim, Sung-O Park, Jaekyun Yoo, Seungju Yu, Hyuk-Joon Kim, Jun-Hyuk Song and Kisuk Kang

Energy Environ. Sci., 2025, 18, 2330
DOI: 10.1039/D4EE04580G

Porous 0.2Li2MnO3·0.8LiNi0.5Mn0.5O2nanorods as cathode materials for lithium-ion batteries

Jingang Yang, Fangyi Cheng, Xiaolong Zhang, Haiyan Gao, Zhanliang Tao and Jun Chen

J. Mater. Chem. A, 2014, 2, 1636
DOI: 10.1039/C3TA14228K

Active material and interphase structures governing performance in sodium and potassium ion batteries

Eun Jeong Kim, P. Ramesh Kumar, Zachary T. Gossage, Kei Kubota, Tomooki Hosaka, Ryoichi Tatara and Shinichi Komaba

Chem. Sci., 2022, 13, 6121
DOI: 10.1039/D2SC00946C

MgFePO4F as a feasible cathode material for magnesium batteries

Zhen-Dong Huang, Titus Masese, Yuki Orikasa, Takuya Mori, Taketoshi Minato, Cedric Tassel, Yoji Kobayashi, Hiroshi Kageyama and Yoshiharu Uchimoto

J. Mater. Chem. A, 2014, 2, 11578
DOI: 10.1039/C4TA01779J

Alluaudite LiMnPO4: a new Mn-based positive electrode for Li rechargeable batteries

Jongsoon Kim, Hyungsub Kim, Kyu-Young Park, Young-Uk Park, Seongsu Lee, Hyung-Soon Kwon, Han-Ill Yoo and Kisuk Kang

J. Mater. Chem. A, 2014, 2, 8632
DOI: 10.1039/C4TA00955J

A high-energy conversion-type cathode activated by amorpholization for Li rechargeable batteries

Yongseok Lee, Jungmin Kang, Jinho Ahn, Wonseok Ko, Hyunyoung Park, Seokjin Lee, Sangyeop Lee, Jung-Keun Yoo and Jongsoon Kim

J. Mater. Chem. A, 2022, 10, 20080
DOI: 10.1039/D2TA02167F

A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides

Jinhyuk Lee, Dong-Hwa Seo, Mahalingam Balasubramanian, Nancy Twu, Xin Li and Gerbrand Ceder

Energy Environ. Sci., 2015, 8, 3255
DOI: 10.1039/C5EE02329G

Sandwich-like LiFePO4/graphene hybrid nanosheets: in situ catalytic graphitization and their high-rate performance for lithium ion batteries

Xiangke Guo, Qi Fan, Liang Yu, Jiyuan Liang, Wenxu Ji, Luming Peng, Xuefeng Guo, Weiping Ding and Yanfeng Chen

J. Mater. Chem. A, 2013, 1, 11534
DOI: 10.1039/c3ta12422c

Tailoring a New 4V‐Class Cathode Material for Na‐Ion Batteries

Jongsoon Kim, Inchul Park, Hyungsub Kim, Kyu‐Young Park, Young‐Uk Park and Kisuk Kang

Advanced Energy Materials, 2016, 6
DOI: 10.1002/aenm.201502147

Redesign of Li2MP2O7 (M = Fe or Mn) by Tuning the Li Diffusion in Rechargeable Battery Electrodes

Jongsoon Kim, Byungju Lee, Hyungsub Kim, Hyunah Kim and Kisuk Kang

Chem. Mater., 2016, 28, 6894
DOI: 10.1021/acs.chemmater.6b02198

High-power rhombohedral-Fe2(SO4)3 with outstanding cycle-performance as Fe-based cathode for K-ion batteries

Jungmin Kang, Wonseok Ko, Hyunyoung Park, Yongseok Lee, Jae Hyeon Jo, Ji Ung Choi, Seung-Taek Myung and Jongsoon Kim

Energy Storage Materials, 2020, 33, 276
DOI: 10.1016/j.ensm.2020.08.024

Organic Cathode Materials for Lithium‐Ion Batteries: Past, Present, and Future

Hailong Lyu, Xiao-Guang Sun and Sheng Dai

Adv Energy and Sustain Res, 2021, 2
DOI: 10.1002/aesr.202000044

Studies on graphene enfolded olivine composite electrode material via polyol technique for high rate performance lithium-ion batteries

Rasu Muruganantham, Marimuthu Sivakumar, Rengapillai Subadevi, Sundara Ramaprabhu and Nae-Lih Wu

Electron. Mater. Lett., 2015, 11, 841
DOI: 10.1007/s13391-015-5061-6

Li1+xFePO4 (x = 0 - 0.5) production from Fe3+ sources by glass-ceramic technique with different carbon sources and investigation of structural, thermal and electrochemical performance

E. Altin, S. Altundag, E. Gultek and S. Altin

Journal of Non-Crystalline Solids, 2022, 586, 121546
DOI: 10.1016/j.jnoncrysol.2022.121546

Synthesis, crystal structure and magnetic behavior of a new calcium magnesium and iron orthophosphate Ca2MgFe2(PO4)4

A. Ould Saleck, C. Mercier, C. Follet, O. Mentré, A. Assani, M. Saadi and L. El Ammari

Journal of Solid State Chemistry, 2020, 292, 121715
DOI: 10.1016/j.jssc.2020.121715

An Efficient Scheme for Crystal Structure Prediction Based on Structural Motifs

Zizhong Zhu, Ping Wu, Shunqing Wu, Linhan Xu, Yixu Xu, Xin Zhao, Cai-Zhuang Wang and Kai-Ming Ho

J. Phys. Chem. C, 2017, 121, 11891
DOI: 10.1021/acs.jpcc.7b02486

Li0.75Mn1.50Fe1.75(PO4)3: First alluaudite-type iron phosphate containing only Li+ as alkaline ions

Khiem Trad, Aurore Castets, Alain Wattiaux, Claude Delmas, Mongi Ben Amara and Dany Carlier

Journal of Solid State Chemistry, 2018, 265, 12
DOI: 10.1016/j.jssc.2018.05.014

Ion-Exchangeable Functional Binders and Separator for High Temperature Performance of Li1.1Mn1.86Mg0.04O4Spinel Electrodes in Lithium Ion Batteries

Seung Hee Woo, Hyung-Woo Lim, Sangbin Jeon, Jonathan J. Travis, Steven M. George, Se-Hee Lee, Yong Nam Jo, Jun Ho Song, Yoon Seok Jung, Sung You Hong, Nam-Soon Choi and Kyu Tae Lee

J. Electrochem. Soc., 2013, 160, A2234
DOI: 10.1149/2.092311jes

Na3V(PO4)2: A New Layered-Type Cathode Material with High Water Stability and Power Capability for Na-Ion Batteries

Jongsoon Kim, Gabin Yoon, Hyungsub Kim, Young-Uk Park and Kisuk Kang

Chem. Mater., 2018, 30, 3683
DOI: 10.1021/acs.chemmater.8b00458

Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+

Tamara Đorđević, Ljiljana Karanović, Marko Jagodič and Zvonko Jagličić

Minerals, 2021, 11, 1372
DOI: 10.3390/min11121372

Improving electrochemical performances of LiFePO4/C cathode material via a novel three-layer electrode

Zheng-wei XIAO, Guo-rong HU, Ke DU and Zhong-dong PENG

Transactions of Nonferrous Metals Society of China, 2013, 23, 3324
DOI: 10.1016/S1003-6326(13)62871-X

Li-ion battery materials: present and future

Naoki Nitta, Feixiang Wu, Jung Tae Lee and Gleb Yushin

Materials Today, 2015, 18, 252
DOI: 10.1016/j.mattod.2014.10.040

Electrochemically mediated CO2 reduction for bio-methane production: a review

Anirudh Bhanu Teja Nelabhotla and Carlos Dinamarca

Rev Environ Sci Biotechnol, 2018, 17, 531
DOI: 10.1007/s11157-018-9470-5

Synthesis of alluaudite-type Na2VFe2(PO4)3/C and its electrochemical performance as cathode material for sodium-ion battery

Mingming Wen, Xudong Liu, Yanming Zhao, Shenghong Liu, Huatao Liu, Youzhong Dong, Quan Kuang and Qinghua Fan

J Solid State Electrochem, 2018, 22, 891
DOI: 10.1007/s10008-017-3826-6

Self‐Assembled Alluaudite Na2Fe3−xMnx(PO4)3 Micro/Nanocompounds for Sodium‐Ion Battery Electrodes: A New Insight into Their Electronic and Geometric Structure

Weifeng Huang, Biao Li, Muhammad Farooq Saleem, Xiang Wu, Jianjian Li, Jun Lin, Dingguo Xia, Wangsheng Chu and Ziyu Wu

Chemistry A European J, 2015, 21, 851
DOI: 10.1002/chem.201403062

Highly Stable Fe2+/Ti3+‐Based Fluoride Cathode Enabling Low‐Cost and High‐Performance Na‐Ion Batteries

Jungmin Kang, Jinho Ahn, Hyunyoung Park, Wonseok Ko, Yongseok Lee, Seokjin Lee, Sangyeop Lee, Sung‐Kyun Jung and Jongsoon Kim

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202201816

A New Route Toward Improved Sodium Ion Batteries: A Multifunctional Fluffy Na0.67FePO4/CNT Nanocactus

Weifeng Huang, Jing Zhou, Biao Li, Li An, Peixin Cui, Wei Xia, Li Song, Dingguo Xia, Wangsheng Chu and Ziyu Wu

Small, 2015, 11, 2170
DOI: 10.1002/smll.201402246

Coupled reaction and solvent extraction process to form Li2CO3: Mechanism and product characterization

Zhiyong Zhou, Fan Liang, Wei Qin and Weiyang Fei

AIChE Journal, 2014, 60, 282
DOI: 10.1002/aic.14243

A novel synthesis of LiFePO4/C from Fe2O3 without extra carbon or carbon-containing reductant

Zheng-wei Xiao and Guo-rong Hu

J. Cent. South Univ., 2014, 21, 2143
DOI: 10.1007/s11771-014-2164-4

Alluaudite Battery Cathodes

Debasmita Dwibedi, Prabeer Barpanda and Atsuo Yamada

Small Methods, 2020, 4
DOI: 10.1002/smtd.202000051

Na/Co dual-doped olivine LiMn0.6Fe0.4PO4 cathode with superior reaction kinetics for Li-ion batteries

Pengxu Wang, Erdong Zhang, Yaoguo Fang, Yihong Chen, Haifeng Yu, Ya Zhang, Qian Cheng and Hao Jiang

J Solid State Electrochem, 2024, 28, 4303
DOI: 10.1007/s10008-024-06043-w

Self-consistent assessment of Li+ ion cathodes: Theory vs. experiments

Hongjie Xu, Weidong Xiao, Zhuo Wang, Junhua Hu and Guosheng Shao

Journal of Energy Chemistry, 2021, 59, 229
DOI: 10.1016/j.jechem.2020.11.008

Synthesis, crystals structures and theoretical studies of novel alkali copper indium orthophosphates ACuIn(PO4)2 (A = Na, K and Rb)

Abdessalem Badri, Sami Slimi, Ines Mokni, Necmi Dege, Rosa Maria Solé, Magdalena Aguiló, Francesc Díaz, Xavier Mateos and Mongi Ben Amara

Journal of Solid State Chemistry, 2023, 318, 123757
DOI: 10.1016/j.jssc.2022.123757

Highly Stable Iron- and Manganese-Based Cathodes for Long-Lasting Sodium Rechargeable Batteries

Hyungsub Kim, Gabin Yoon, Inchul Park, Jihyun Hong, Kyu-Young Park, Jongsoon Kim, Kug-Seung Lee, Nark-Eon Sung, Seongsu Lee and Kisuk Kang

Chem. Mater., 2016, 28, 7241
DOI: 10.1021/acs.chemmater.6b01766

Off‐Stoichiometry in Alluaudite‐Type Sodium Iron Sulfate Na2+2xFe2−x(SO4)3 as an Advanced Sodium Battery Cathode Material

Gosuke Oyama, Shin‐ichi Nishimura, Yuya Suzuki, Masashi Okubo and Atsuo Yamada

ChemElectroChem, 2015, 2, 1019
DOI: 10.1002/celc.201500036

Anionic Activity in Fast-Charging Batteries: Recent Advances, Prospects, and Challenges

Shumao Xu, Baixin Peng, Xin Pang and Fuqiang Huang

ACS Materials Lett., 2022, 4, 2195
DOI: 10.1021/acsmaterialslett.2c00810

Development of Novel Cathode with Large Lithium Storage Mechanism Based on Pyrophosphate‐Based Conversion Reaction for Rechargeable Lithium Batteries

Yongseok Lee, Jae Hyeon Jo, Hyunyoung Park, Wonseok Ko, Jungmin Kang, Seung‐Taek Myung, Yang‐Kook Sun and Jongsoon Kim

Small Methods, 2020, 4
DOI: 10.1002/smtd.201900847

Intrinsic Nanodomains in Triplite LiFeSO4F and Its Implication in Lithium‐Ion Diffusion

Dong‐Hwa Seo, Kyu‐Young Park, Haegyeom Kim, Sung‐Kyun Jung, Min‐Sik Park and Kisuk Kang

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201701408

In Situ Tracking Kinetic Pathways of Li+/Na+ Substitution during Ion-Exchange Synthesis of LixNa1.5–xVOPO4F0.5

Young-Uk Park, Jianming Bai, Liping Wang, Gabin Yoon, Wei Zhang, Hyungsub Kim, Seongsu Lee, Sung-Wook Kim, J. Patrick Looney, Kisuk Kang and Feng Wang

J. Am. Chem. Soc., 2017, 139, 12504
DOI: 10.1021/jacs.7b05302

Structural and magnetic insights of the novel phosphate Ca2NiFe2(PO4)4

Sirine El Arni, Loubna Chayal, Fouad Alloun, Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, Mimoun El Marssi, Abdelilah Lahmar and Lahcen El Ammari

Solid State Sciences, 2024, 155, 107652
DOI: 10.1016/j.solidstatesciences.2024.107652

Effect of LiFePO₄ Cathode Thickness on Lithium Battery Performance

Ariska Rinda Adityarini, Eka Yoga Ramadhan, Endah Retno Dyartanti and Agus Purwanto

MSF, 2015, 827, 146
DOI: 10.4028/www.scientific.net/MSF.827.146

Synthesis, crystal structure determination of a novel phosphate Ag1.64Zn1.64Fe1.36(PO4)3 with an alluaudite-like structure

Jamal Khmiyas, Abderrazzak Assani, Mohamed Saadi and Lahcen El Ammari

Acta Crystallogr E Cryst Commun, 2020, 76, 1491
DOI: 10.1107/S2056989020011408

Electrochemical Energy Storage Devices─Batteries, Supercapacitors, and Battery–Supercapacitor Hybrid Devices

Lei Liu, Xiyao Zhang, Yanghe Liu and Xiong Gong

ACS Appl. Electron. Mater., 2025, 7, 2233
DOI: 10.1021/acsaelm.5c00069

Metal tetrabromophthalocyanines mediate the structure and electrochemical performance of lithium iron phosphate as cathode materials for lithium-ion batteries

Ruiqiong Wang, Ronglan Zhang, Bei Xu, Fei Yang, Jianshe Zhao, Shichao Zhang and Junlong Wang

Journal of Electroanalytical Chemistry, 2015, 755, 47
DOI: 10.1016/j.jelechem.2015.07.019

Unusual Activation of Cation Disordering by Li/Fe Rearrangement in Triplite LiFeSO4F

Minkyu Kim, Minkyung Kim, Heetaek Park, Hong Li and Byoungwoo Kang

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201800298

Unveiling yavapaiite-type K Fe(SO4)2 as a new Fe-based cathode with outstanding electrochemical performance for potassium-ion batteries

Wonseok Ko, Hyunyoung Park, Jae Hyeon Jo, Yongseok Lee, Jungmin Kang, Young Hwa Jung, Tae-Yeol Jeon, Seung-Taek Myung and Jongsoon Kim

Nano Energy, 2019, 66, 104184
DOI: 10.1016/j.nanoen.2019.104184

Uncovering the predictive pathways of lithium and sodium interchange in layered oxides

Yu Han, Weihang Xie, Grant T. Hill, Paul Smeets, Xiaobing Hu, Gangbin Yan, Siqi Zou, Jiadong Liu, Ronghui Wu, Fengyuan Shi, Hua Zhou, Pieremanuele Canepa and Chong Liu

Nat. Mater., 2024, 23, 951
DOI: 10.1038/s41563-024-01862-8

The Conversion Chemistry for High-Energy Cathodes of Rechargeable Sodium Batteries

Yongseok Lee, Jung-Keun Yoo, Jae Hyeon Jo, Hyunyoung Park, Chang-Heum Jo, Wonseok Ko, Hitoshi Yashiro, Seung-Taek Myung and Jongsoon Kim

ACS Nano, 2019, 13, 11707
DOI: 10.1021/acsnano.9b05635

Synthesis, Crystal Structure, and Electrochemical Properties of Alluaudite Na1.702Fe3(PO4)3 as a Sodium-Ion Battery Cathode

Dan Liu and G. Tayhas R. Palmore

ACS Sustainable Chem. Eng., 2017, 5, 5766
DOI: 10.1021/acssuschemeng.7b00371

Lithium versus Mono/Polyvalent Ion Intercalation: Hybrid Metal Ion Systems for Energy Storage

Radostina Stoyanova, Violeta Koleva and Antonia Stoyanova

The Chemical Record, 2019, 19, 474
DOI: 10.1002/tcr.201800081

Unlocking New Redox Activity in Alluaudite Cathodes through Compositional Design

Vincent C. Wu, Raynald Giovine, Emily E. Foley, Jordan Finzel, Mahalingam Balasubramanian, Elias Sebti, Eve M. Mozur, Andrew H. Kwon and Raphaële J. Clément

Chem. Mater., 2022, 34, 4088
DOI: 10.1021/acs.chemmater.2c00324

Surface-Modified Spinel LiNi0.5Mn1.5O4 for Li-Ion Batteries

Jongsoon Kim, Hyungsub Kim and Kisuk Kang

J. Korean Ceram. Soc, 2018, 55, 21
DOI: 10.4191/kcers.2018.55.1.08

Cathode materials for rechargeable lithium batteries: Recent progress and future prospects

Moumita Kotal, Sonu Jakhar, Sandipan Roy and Harish K. Sharma

Journal of Energy Storage, 2022, 47, 103534
DOI: 10.1016/j.est.2021.103534