Issue 64, 2022

Nitroxyl radical-containing flexible porous coordination polymer for controllable size-aelective aerobic oxidation of alcohols

Abstract

The ability of flexible porous coordination polymers (PCPs) to change their structure in response to various stimuli has not been exploited in the design of tunable-selectivity catalysts. Herein, we make use of this ability and prepare nitroxyl radical-containing flexible PCP that can reversibly switch between large- and contracted-pore configurations in response to solvent change and thus promote the controllable size-selective aerobic oxidation of alcohols.

Graphical abstract: Nitroxyl radical-containing flexible porous coordination polymer for controllable size-aelective aerobic oxidation of alcohols

Associated articles

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Article information

Article type
Communication
Submitted
17 5 2022
Accepted
13 7 2022
First published
25 7 2022

Chem. Commun., 2022,58, 9026-9029

Nitroxyl radical-containing flexible porous coordination polymer for controllable size-aelective aerobic oxidation of alcohols

P. Wang, Z. Xue, O. Ken-ichi and S. Kitagawa, Chem. Commun., 2022, 58, 9026 DOI: 10.1039/D2CC02772K

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