Issue 50, 2018

Low-overpotential CO2 reduction by a phosphine-substituted Ru(ii) polypyridyl complex

Abstract

A Ru polypyridyl complex containing a phosphine donor promoted electrocatalytic CO2 reduction at a low overpotential. Mechanistic investigations revealed that the introduction of a phosphine donor at the trans position to the labile ligand is the key to reduce the overpotential for CO2 reduction.

Graphical abstract: Low-overpotential CO2 reduction by a phosphine-substituted Ru(ii) polypyridyl complex

Supplementary files

Article information

Article type
Communication
Submitted
17 3 2018
Accepted
23 5 2018
First published
23 5 2018

Chem. Commun., 2018,54, 6915-6918

Author version available

Low-overpotential CO2 reduction by a phosphine-substituted Ru(II) polypyridyl complex

S. K. Lee, M. Kondo, G. Nakamura, M. Okamura and S. Masaoka, Chem. Commun., 2018, 54, 6915 DOI: 10.1039/C8CC02150C

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