Issue 33, 2018

Rectangle and [2]catenane from cluster modular construction

Abstract

Reaction of [Et4N][Tp*WS3] (1) with [Cu(MeCN)4]PF6, CsCl, isonicotinic acid and CuCN, and treatment of [Et4N][Tp*WS3(CuCl)3] (2)/[Et4N][{Tp*WS3Cu3Cl}2(μ-Cl)24-Cl)] (3) with AgOTf and bpp (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate; bpp = 1,3-di(4-pyridyl)propane) give rise to [Et4N]2[{Tp*WS3Cu3(CN)0.5}2(μ-Cl)24-Cl)]2(PF6)2 (4) and [(Tp*WS3Cu3)23-Cl)2(bpp)3]2(OTf)4 (5), respectively. Compounds 4 and 5 feature cluster-based rectangle and [2]catenane architecture, and both exhibit enhanced third-order nonlinear optical responses relative to those of 1.

Graphical abstract: Rectangle and [2]catenane from cluster modular construction

Supplementary files

Article information

Article type
Communication
Submitted
11 3 2018
Accepted
29 3 2018
First published
03 4 2018

Chem. Commun., 2018,54, 4168-4171

Rectangle and [2]catenane from cluster modular construction

X. Qiu, R. Yao, W. Zhou, M. Liu, Q. Liu, Y. Song, D. J. Young, W. Zhang and J. Lang, Chem. Commun., 2018, 54, 4168 DOI: 10.1039/C8CC01950A

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