Issue 3, 2015

Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

Abstract

We report two porous Zr phosphonate frameworks. The kinetic product, ZrH2L-A, shows low order and is less porous. An HF-modulated structure, CALF-31, is more ordered and has higher porosity. While not single crystalline, CALF-31 is highly robust and the CO2 heats of adsorption give insights into ordering in phosphonate MOFs.

Graphical abstract: Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

Supplementary files

Article information

Article type
Research Article
Submitted
24 11 2014
Accepted
22 1 2015
First published
03 2 2015

Inorg. Chem. Front., 2015,2, 273-277

Author version available

Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

R. K. Mah, B. S. Gelfand, J. M. Taylor and G. K. H. Shimizu, Inorg. Chem. Front., 2015, 2, 273 DOI: 10.1039/C4QI00209A

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