Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

Jianhui Chen; Tuo Xi; Xiang Ren; Biao Cheng; Jun Guo; Zhan Lu

doi:10.1039/C4QO00295D

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Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes†

Jianhui Chen,^a Tuo Xi,^a Xiang Ren,^a Biao Cheng,^a Jun Guo^a and Zhan Lu*^a

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* Corresponding authors

^a Department of Chemistry, Zhejiang University, 148 Tianmushan Road Hangzhou, Zhejiang, China
E-mail: luzhan@zju.edu.cn

Abstract

Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1,1-disubstituted aryl alkenes. These novel IPO ligands will likely be of high value for asymmetric transformations with first-row transition metals.

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DOI: https://doi.org/10.1039/C4QO00295D
Article type: Research Article
Submitted: 10 11 2014
Accepted: 18 11 2014
First published: 19 11 2014

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Org. Chem. Front., 2014,1, 1306-1309

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Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

J. Chen, T. Xi, X. Ren, B. Cheng, J. Guo and Z. Lu, Org. Chem. Front., 2014, 1, 1306 DOI: 10.1039/C4QO00295D

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Organic Chemistry Frontiers

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes†

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