Issue 7, 2014

Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

Abstract

A novel type of open-chain chiral chelating olefin bearing a simple monophosphite unit with a binaphthyl backbone was designed and synthesized, which could serve as an elegant chiral bidentate ligand in the rhodium-catalyzed asymmetric 1,2-additions of organoboron reagents to α-diketones and N-sulfonyl aldimines.

Graphical abstract: Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

Supplementary files

Article information

Article type
Research Article
Submitted
08 5 2014
Accepted
04 6 2014
First published
05 6 2014

Org. Chem. Front., 2014,1, 738-741

Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

Y. Yu and M. Xu, Org. Chem. Front., 2014, 1, 738 DOI: 10.1039/C4QO00135D

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