Issue 46, 2009

Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

Abstract

A highly regioselective iron-catalyzed addition of branched primary, secondary or tertiary alkyl Grignard reagents to activated vinyl cyclopropanes is described, which likely proceeds by a direct addition mechanism as opposed to single electron transfer or an iron-allyl based process.

Graphical abstract: Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

Supplementary files

Article information

Article type
Communication
Submitted
10 9 2009
Accepted
05 10 2009
First published
29 10 2009

Chem. Commun., 2009, 7116-7118

Iron-catalyzed addition of Grignard reagents to activated vinyl cyclopropanes

B. D. Sherry and A. Fürstner, Chem. Commun., 2009, 7116 DOI: 10.1039/B918818E

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