Issue 14, 2024

Gold nanostructures/quantum dots for the enhanced efficiency of organic solar cells

Abstract

Incorporating gold nanoparticles (AuNPs) into organic solar cell (OSC) structures provides an effective means to manipulate light–matter interactions. AuNPs have been used as plasmonic-enhancement and light-trapping materials in OSCs and exhibit diverse single and mixed morphologies. Substantial near-field enhancement from metal periodic structures has consistently demonstrated high enhancement in solar cell efficiency. Additionally, coupling with atomic gold clusters in the form of gold quantum dots holds promise for light harvesting through fluorescence phenomena. The configured devices optimize light utilization in OSCs by considering factors such as the morphology, position, and hybridization of localized surface plasmon resonance, propagating surface plasmon resonance, and fluorescence phenomena. This optimization enhances light absorption, scattering, and efficient trapping facilitated by gold nanostructures/quantum dots. The configured setup exhibits multiple effects, concurrently improving plasmonic and fluorescence responses under solar irradiation, thereby enhancing energy conversion performance. Integrating plasmonic nanostructures with OSCs can address fundamental issues, providing opportunities to enhance the light-absorption intensity and charge transfer efficiency at intra and intermolecular levels. This comprehensive review demonstrates that the greatest improvement in solar cell efficiency exceeded 30% compared with the reference cells.

Graphical abstract: Gold nanostructures/quantum dots for the enhanced efficiency of organic solar cells

Article information

Article type
Review Article
Submitted
06 1 2024
Accepted
18 5 2024
First published
22 5 2024
This article is Open Access
Creative Commons BY-NC license

Nanoscale Adv., 2024,6, 3494-3512

Gold nanostructures/quantum dots for the enhanced efficiency of organic solar cells

A. Phengdaam, S. Phetsang, S. Jonai, K. Shinbo, K. Kato and A. Baba, Nanoscale Adv., 2024, 6, 3494 DOI: 10.1039/D4NA00016A

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