Issue 58, 2024

Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(iii)-based dynamic MOFs

Abstract

The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6]·12H2O}n of mixed hexagonal/decagonal (63·103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition to give the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6]·4H2O}n of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}n.

Graphical abstract: Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(iii)-based dynamic MOFs

Supplementary files

Article information

Article type
Communication
Submitted
27 5 2024
Accepted
20 6 2024
First published
21 6 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 7451-7454

Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs

N. El Alouani Dahmouni, M. Orts-Arroyo, A. Sanchis-Perucho, N. Moliner, J. Mayans, M. Pacheco, I. Castro, G. De Munno, N. Marino, R. Ruiz-García and J. Martínez-Lillo, Chem. Commun., 2024, 60, 7451 DOI: 10.1039/D4CC02539C

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