Issue 5, 2023

Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4′-bipyridine)2(NCS)2]n

Abstract

Switching coordination networks (CNs) featuring stepped sorption isotherms that are accompanied by phase changes offer promise for gas storage and separation applications. However, their responsiveness to different adsorbates remains largely understudied. Herein, we report the variable switching behaviour of a previously known square lattice (sql) topology CN, [Ni(4,4′-bipyridine)2(NCS)2] (sql-1-Ni-NCS), with respect to nine gaseous adsorbates.

Graphical abstract: Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4′-bipyridine)2(NCS)2]n

Supplementary files

Article information

Article type
Communication
Submitted
01 12 2022
Accepted
08 12 2022
First published
08 12 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 559-562

Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni(4,4′-bipyridine)2(NCS)2]n

S. Wang, S. Darwish and M. J. Zaworotko, Chem. Commun., 2023, 59, 559 DOI: 10.1039/D2CC06549E

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