Issue 43, 2022

Design of coordination polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(ii), Zn(ii), Cd(ii) and Co(ii)

Abstract

Five new supramolecular coordination polymers (L-Cu(acac)2, L-Cu(hfac)2, L-ZnCl2, L-CdI2 and L-CoCl2) based on the use of the flexible organic ligand L (1,2-diphenylethane-1,2-diyl diisonicotinate) combined with Cu(acac)2, Cu(hfac)2, ZnCl2, CdI2 or CoCl2 metallaligands, were synthesized and structurally characterized by single-crystal X-ray diffraction. They represent the first reported coordination polymers based on this ligand presenting ester junctions. X-ray diffraction analysis revealed the structure and the dimensionality of these coordination polymers as well as their packing in the crystal that depends on the conformation adopted by the ligand L and the nature of the used metallic salts.

Graphical abstract: Design of coordination polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(ii), Zn(ii), Cd(ii) and Co(ii)

Supplementary files

Article information

Article type
Paper
Submitted
22 7 2022
Accepted
07 10 2022
First published
07 10 2022
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2022,24, 7632-7639

Design of coordination polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II)

S. Zazouli, N. Gruber, V. Bulach, S. Ferlay and A. Jouaiti, CrystEngComm, 2022, 24, 7632 DOI: 10.1039/D2CE01001A

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