Issue 25, 2022

Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

Abstract

Metal–organic frameworks (MOFs) containing open metal sites are advantageous for wide applications. Here, carboxylate linkers are replaced with triazolate coordination in pre-formed Zn-MOF-74 via solvent-assisted linker exchange (SALE) to prepare the novel NU-250, within the known hexagonal channel-based MAF-X25 series that has not previously been synthesized de novo.

Graphical abstract: Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

Supplementary files

Article information

Article type
Communication
Submitted
15 2 2022
Accepted
25 2 2022
First published
07 3 2022

Chem. Commun., 2022,58, 4028-4031

Author version available

Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

K. M. Fahy, M. R. Mian, M. C. Wasson, F. A. Son, T. Islamoglu and O. K. Farha, Chem. Commun., 2022, 58, 4028 DOI: 10.1039/D2CC00925K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements