Issue 14, 2021

Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

Abstract

A LCST-type [2]pseudorotaxane based on perbromoethylated pillar[5]arene/imidazolium iodide ionic liquid ion-pair recognition is constructed in both solution and the solid state. The thermo-responsive behavior can be adjusted by altering the molar ratio of the host and guest as well as the concentrations of these two components in solution.

Graphical abstract: Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

Supplementary files

Article information

Article type
Research Article
Submitted
23 3 2021
Accepted
04 5 2021
First published
10 5 2021

Org. Chem. Front., 2021,8, 3675-3680

Pillar[5]arene-based ion-pair recognition for constructing a [2]pseudorotaxane with supramolecular interaction induced LCST behavior

M. Li, B. Hua and F. Huang, Org. Chem. Front., 2021, 8, 3675 DOI: 10.1039/D1QO00457C

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