Issue 35, 2021

Halogen bonding effect on electrochemical anion oxidation in ionic liquids

Abstract

Three Ionic liquids (ILs) based on an imidazolium core have been compared and used as solvents for the oxidation of various anions. Electrochemical experiments as well as NMR titrations and X-ray diffraction analyses unambiguously confirm the crucial role of non-covalent halogen bonding on the oxidation potentials and consequently the electrochemical window of the respective ILs.

Graphical abstract: Halogen bonding effect on electrochemical anion oxidation in ionic liquids

Supplementary files

Article information

Article type
Communication
Submitted
27 5 2021
Accepted
13 8 2021
First published
14 8 2021

Org. Biomol. Chem., 2021,19, 7587-7593

Halogen bonding effect on electrochemical anion oxidation in ionic liquids

M. S. Alvarez, C. Houzé, S. Groni, B. Schöllhorn and C. Fave, Org. Biomol. Chem., 2021, 19, 7587 DOI: 10.1039/D1OB01031J

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