Issue 41, 2021

Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

Abstract

Under the guidance of the ESI-MS result for [TeO6@Ag36(C[triple bond, length as m-dash]CtBu)18(tfa)12] (1, tfa = trifluoroacetate), a new 36-nucleus silver-alkynyl cluster substituted by four pentafluorobenzoates, named as [TeO6@Ag36(C[triple bond, length as m-dash]CtBu)18(tfa)8(F5PhCO2)4] (2), has been fabricated. After shell ligand substitution, cluster 2 emits green yellow light in the solid state and shows a remarkable change in the near-infrared luminescence emission compared to cluster 1.

Graphical abstract: Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

Supplementary files

Article information

Article type
Communication
Submitted
10 8 2021
Accepted
15 9 2021
First published
16 9 2021

CrystEngComm, 2021,23, 7202-7205

Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

L. Hou, H. Li, D. Yu, X. Cheng, Z. Yao, K. Liu and X. Yan, CrystEngComm, 2021, 23, 7202 DOI: 10.1039/D1CE01061A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements