Issue 34, 2021

Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

Abstract

Two isomeric zeolite-like metal–organic frameworks with the formula of [(CH3)2NH2][Cd(TPO)]·xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3− nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N2.

Graphical abstract: Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

Supplementary files

Article information

Article type
Communication
Submitted
07 4 2021
Accepted
12 5 2021
First published
13 5 2021

CrystEngComm, 2021,23, 5753-5757

Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

S. Peng, Y. Qi, X. Li, C. Sun, L. Li, X. Li, S. Zheng and Q. Zhang, CrystEngComm, 2021, 23, 5753 DOI: 10.1039/D1CE00464F

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