Issue 30, 2020

Recent advances in sulfonylation reactions using potassium/sodium metabisulfite

Abstract

Recently, sulfonylation reactions using potassium/sodium metabisulfite as the sulfur dioxide surrogate have been developed rapidly. In most cases, the transformations go through radical processes with the insertion of sulfur dioxide under mild conditions. Additionally, transition metal catalysis is applied in the reactions for the synthesis of sulfonyl-containing compounds. Among the approaches, photoinduced conversions under visible light or ultraviolet irradiation are also involved. In this updated report, the insertion of sulfur dioxide from potassium metabisulfite or sodium metabisulfite is summarized.

Graphical abstract: Recent advances in sulfonylation reactions using potassium/sodium metabisulfite

Article information

Article type
Feature Article
Submitted
07 3 2020
Accepted
24 3 2020
First published
24 3 2020

Chem. Commun., 2020,56, 4145-4155

Recent advances in sulfonylation reactions using potassium/sodium metabisulfite

S. Ye, M. Yang and J. Wu, Chem. Commun., 2020, 56, 4145 DOI: 10.1039/D0CC01775B

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