Issue 38, 2020

Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide

Abstract

Borohydride (BH4)-containing coordination polymers converted CO2 into HCO2 or [BH3(OCHO)], whose reaction routes were affected by the electronegativity of metal ions and the coordination mode of BH4. The reactions were investigated using thermal gravimetric analysis under CO2 gas flow, infrared spectroscopy, and NMR experiments.

Graphical abstract: Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide

Supplementary files

Article information

Article type
Communication
Submitted
06 3 2020
Accepted
06 4 2020
First published
06 4 2020

Chem. Commun., 2020,56, 5111-5114

Author version available

Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide

K. Kadota, E. Sivaniah and S. Horike, Chem. Commun., 2020, 56, 5111 DOI: 10.1039/D0CC01753A

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