Issue 14, 2019

Achieving high discharge energy density and efficiency with NBT-based ceramics for application in capacitors

Abstract

High-performance capacitors, which have high energy storage density as well as high discharge efficiency, are desired. In this study, we have designed and prepared novel and high quality (1 − x)(0.65Bi0.5Na0.5TiO3–0.35Bi0.1Sr0.85TiO3)–x(K0.5Na0.5NbO3) [(1 − x)(BNT–BST)–xKNN, x = 0, 0.04, 0.06, 0.08, and 0.10] ceramics that demonstrated a remarkable energy storage capability, high efficiency, and ultrafast discharge speed. Particularly, the 0.94(BNT–BST)–0.06KNN ceramic possessed an excellent stored energy storage density (Ws = ∼3.13 J cm−3) and recoverable energy storage density (Wr = ∼2.65 J cm−3), and maintained a relatively high efficiency (η = ∼84.6%) at a relatively low electric field of 180 MV m−1, which is superior to those of the lead-free BNT-based energy-storage materials. Moreover, excellent temperature (20–120 °C) and frequency (1–100 Hz) stabilities of the 0.94(BNT–BST)–0.06KNN ceramic were also achieved. More importantly, the 0.94(BNT–BST)–0.06KNN ceramic exhibited an ultrafast discharge rate (τ0.9 = ∼1.01 μs), a high level of discharge energy density (Wd −1.21 J cm−3), and excellent reliability in energy storage performance by consecutive cycling. Moreover, this study also provides an effective approach to attain large energy-storage capability along with high efficiency in BNT-based ceramics for application in pulsed power capacitors.

Graphical abstract: Achieving high discharge energy density and efficiency with NBT-based ceramics for application in capacitors

Article information

Article type
Paper
Submitted
06 1 2019
Accepted
27 2 2019
First published
01 3 2019

J. Mater. Chem. C, 2019,7, 4072-4078

Achieving high discharge energy density and efficiency with NBT-based ceramics for application in capacitors

Z. Pan, D. Hu, Y. Zhang, J. Liu, B. Shen and J. Zhai, J. Mater. Chem. C, 2019, 7, 4072 DOI: 10.1039/C9TC00087A

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