Issue 5, 2019

Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

Abstract

A supramolecular polymer, 3T-DPP, that undergoes photoinduced proton-coupled electron transfer was constructed by means of amidinium-carboxylate salt bridges that serve to link terthiophene electron donors and diketopyrrolopyrrole electron acceptors with a 1 : 1 binding constant of 1.13 × 105 M−1 in N-methyl pyrrolidone.

Graphical abstract: Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

Supplementary files

Article information

Article type
Research Article
Submitted
25 12 2018
Accepted
22 1 2019
First published
24 1 2019

Org. Chem. Front., 2019,6, 584-590

Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

X. Ren, X. Wang, Y. Sun, X. Chi, D. Mangel, H. Wang and J. L. Sessler, Org. Chem. Front., 2019, 6, 584 DOI: 10.1039/C8QO01408F

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