Issue 11, 2019

Facile synthesis of diverse rotaxanes via successive supramolecular transformations

Abstract

Facile synthesis of diverse rotaxanes was successfully realized through a simple and efficient supramolecular transformation strategy. Starting from an organometallic [3]rotaxane with a platinum-acetylide moiety as the bridge moiety and transformation site, employing a simple phosphine ligand exchange and sequential reductive elimination reactions resulted in the successful preparation of various rotaxanes with diverse structures and properties.

Graphical abstract: Facile synthesis of diverse rotaxanes via successive supramolecular transformations

Supplementary files

Article information

Article type
Research Article
Submitted
01 7 2019
Accepted
05 9 2019
First published
06 9 2019

Mater. Chem. Front., 2019,3, 2397-2402

Facile synthesis of diverse rotaxanes via successive supramolecular transformations

Y. Hu, W. Wang, R. Yao, X. Wang, Y. Wang, B. Sun, L. Chen, Y. Zhang, X. Zhao, L. Xu, H. Tan, Y. Yu, X. Li and H. Yang, Mater. Chem. Front., 2019, 3, 2397 DOI: 10.1039/C9QM00430K

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