Issue 63, 2019

Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

Abstract

N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.

Graphical abstract: Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

Supplementary files

Article information

Article type
Communication
Submitted
02 7 2019
Accepted
15 7 2019
First published
17 7 2019

Chem. Commun., 2019,55, 9291-9294

Author version available

Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

M. Kashihara, R. Zhong, K. Semba, S. Sakaki and Y. Nakao, Chem. Commun., 2019, 55, 9291 DOI: 10.1039/C9CC05055H

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