Issue 26, 2019

Nanoparticulate and microporous solid acid catalysts bearing aliphatic sulfonic acids for biomass conversion

Abstract

This work introduces new nanocatalytic systems based on microporous organic network (MON) chemistry for fructose conversion to 5-hydroxymethylfurfural (HMF). The efficiency of the catalytic systems could be improved through the size-controlled synthesis of MON materials. Through a predesigned building block approach and a post-synthetic modification, aliphatic sulfonic acid groups were incorporated into nano-sized MON materials to form N-MON-AS. The N-MON-AS showed selective conversion of fructose to HMF in up to 91% yield at 100 °C and good recyclability.

Graphical abstract: Nanoparticulate and microporous solid acid catalysts bearing aliphatic sulfonic acids for biomass conversion

Supplementary files

Article information

Article type
Communication
Submitted
17 1 2019
Accepted
15 2 2019
First published
15 2 2019

Chem. Commun., 2019,55, 3697-3700

Nanoparticulate and microporous solid acid catalysts bearing aliphatic sulfonic acids for biomass conversion

K. Cho, S. M. Lee, H. J. Kim, Y. Ko and S. U. Son, Chem. Commun., 2019, 55, 3697 DOI: 10.1039/C9CC00436J

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