Issue 46, 2018

A linear trinuclear ferrous single molecule magnet

Abstract

A linear trinuclear ferrous complex [FeII3(pymp)4(MeOH)2][BPh4]2·2MeOH (1) (Hpymp = 2-[(pyridine-2-ylimine)-methyl]phenol) was isolated and characterized both structurally and magnetically. A magnetic study revealed the ferromagnetic coupling (J = +3.54 cm−1) within the [FeII3] units and uniaxial magnetic anisotropy (D = −1.21 cm−1) of the molecule. Slow relaxation of the magnetization at below 5 K and an effective energy barrier of 26.0(2) cm−1 under a 1200 Oe applied dc field were evidenced. Moreover, clear magnetic hysteresis loops were observed at below 2.5 K, which further corroborated the single-molecule magnet behavior of 1.

Graphical abstract: A linear trinuclear ferrous single molecule magnet

Supplementary files

Article information

Article type
Paper
Submitted
21 8 2018
Accepted
22 10 2018
First published
23 10 2018

Dalton Trans., 2018,47, 16704-16708

A linear trinuclear ferrous single molecule magnet

S. Liu, Y. Deng, C. Li, X. Chang and Y. Zhang, Dalton Trans., 2018, 47, 16704 DOI: 10.1039/C8DT03410A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements