Issue 5, 2016
From the journal:

Organic Chemistry Frontiers

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates†

Kohei Harada,‡a   Marina Nogami,‡a   Keiichi Hirano,*a   Daisuke Kurauchi,a   Hisano Kato,a   Kazunori Miyamoto,a   Tatsuo Saitoa  and  Masanobu Uchiyama*ab  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: k1hirano@mol.f.u-tokyo.ac.jp, uchiyama@mol.f.u-tokyo.ac.jp
Fax: +81 3 5841 0733
Tel: +81 3 5841 0277

b Advanced Elements Chemistry Research Team, RIKEN, RIKEN Center for Sustainable Resource Science, and Elements Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama, Japan
E-mail: uchi_yama@riken.jp
Fax: +81 48 467 2869
Tel: +81 48 467 2879

Abstract

A facile and divergent synthetic process for converting tertiary allylic alcohols to multiply substituted allylic boronates is reported. This methodology is especially effective for tertiary alcohol substrates, providing the corresponding allylic boronates in moderate to good yields.

Graphical abstract: Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

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Article information

DOI
https://doi.org/10.1039/C6QO00009F
Article type
Research Article
Submitted
09 1 2016
Accepted
23 2 2016
First published
01 3 2016

Org. Chem. Front., 2016,3, 565-569

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Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

K. Harada, M. Nogami, K. Hirano, D. Kurauchi, H. Kato, K. Miyamoto, T. Saito and M. Uchiyama, Org. Chem. Front., 2016, 3, 565 DOI: 10.1039/C6QO00009F

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