Issue 3, 2016

A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

Abstract

A metal-free, photo-induced C–C bond formation methodology was developed to construct tetrahydrofluorenones and their related structures. This mild and efficient method proceeds either through electrocyclization or radical cyclization from β-Cl or β-Br aryl vinyl ketone. We believe that this method is particularly useful for the synthesis of related tetrahydrofluorenone containing natural products.

Graphical abstract: A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

Supplementary files

Article information

Article type
Research Article
Submitted
21 11 2015
Accepted
13 1 2016
First published
14 1 2016

Org. Chem. Front., 2016,3, 354-358

Author version available

A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

S. Cai, Z. Xiao, J. Ou, Y. Shi and S. Gao, Org. Chem. Front., 2016, 3, 354 DOI: 10.1039/C5QO00392J

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