Issue 99, 2016

Core expansion of bis-calix[4]arene-supported clusters

Abstract

Calix[4]arenes are excellent ligand supports for the synthesis of polymetallic clusters of transition and lanthanide metal ions, as well as 3d–4f ion mixtures. Bis-calix[4]arene, a recent addition to the calixarene family, forms structurally related cages that mirror the metal ion binding preferences of calix[4]arene. Here we show that stoichiometric control causes remarkable expansion in the cores of two known bis-calix[4]arene-supported clusters, with concomitant changes to the magnetic properties observed.

Graphical abstract: Core expansion of bis-calix[4]arene-supported clusters

Supplementary files

Article information

Article type
Communication
Submitted
06 10 2016
Accepted
08 11 2016
First published
09 11 2016

Chem. Commun., 2016,52, 14246-14249

Core expansion of bis-calix[4]arene-supported clusters

M. Coletta, R. McLellan, A. Waddington, S. Sanz, K. J. Gagnon, S. J. Teat, E. K. Brechin and S. J. Dalgarno, Chem. Commun., 2016, 52, 14246 DOI: 10.1039/C6CC08059F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements