A photoluminescent indium–organic framework with discrete cages and one-dimensional channels for gas adsorption

Jinjie Qian; Qipeng Li; Linfeng Liang; Yan Yang; Zhen Cao; Panpan Yu; Shaoming Huang; Maochun Hong

doi:10.1039/C5CC10359B

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A photoluminescent indium–organic framework with discrete cages and one-dimensional channels for gas adsorption†

Jinjie Qian,*^ab Qipeng Li,^bc Linfeng Liang,^b Yan Yang,^b Zhen Cao,^b Panpan Yu,^a Shaoming Huang*^a and Maochun Hong^b

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* Corresponding authors

^a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
E-mail: jinjieqian@wzu.edu.cn, smhuang@wzu.edu.cn
Tel: +86-577-88373064

^b State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China

^c School of Chemistry and Life Science, Zhaotong University, Zhaotong, Yunnan 657000, P. R. China

Abstract

We have successfully obtained, for the first time, a new heterometallic indium–organic framework (InOF-14) with a functional and luminescent Eu(III) component. Based on the mutually competitive [In(CO₂)₄] and [Eu₂(CO₂)₄(H₂O)₄] units, this microporous structure possesses discrete nano-cages and one-dimensional channels for gas adsorption, and simultaneously exhibits excellent luminescence properties.

This article is part of the themed collection: 2016 Emerging Investigators

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DOI: https://doi.org/10.1039/C5CC10359B
Article type: Communication
Submitted: 17 12 2015
Accepted: 06 1 2016
First published: 06 1 2016

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Chem. Commun., 2016,52, 9032-9035

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A photoluminescent indium–organic framework with discrete cages and one-dimensional channels for gas adsorption

J. Qian, Q. Li, L. Liang, Y. Yang, Z. Cao, P. Yu, S. Huang and M. Hong, Chem. Commun., 2016, 52, 9032 DOI: 10.1039/C5CC10359B

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Chemical Communications

A photoluminescent indium–organic framework with discrete cages and one-dimensional channels for gas adsorption†

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A photoluminescent indium–organic framework with discrete cages and one-dimensional channels for gas adsorption

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