Issue 45, 2015

Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

Abstract

A new iron-catalyzed reaction for the coupling of perfluoroalkyl iodides (RFI) with aromatic substrates is described. The perfluoroalkylated arene products are obtained in good to excellent yields in the presence of a [(bpy)Fe(II)] catalyst (10%) electrochemically regenerated or generated from [(bpy)Fe(III)] at room temperature. The development, scope, and preliminary mechanistic studies of these transformations are reported.

Graphical abstract: Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

  • This article is part of the themed collection: Fluorine

Supplementary files

Article information

Article type
Paper
Submitted
05 8 2015
Accepted
30 9 2015
First published
30 9 2015

Dalton Trans., 2015,44, 19674-19681

Author version available

Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

M. Khrizanforov, S. Strekalova, V. Khrizanforova, V. Grinenko, K. Kholin, M. Kadirov, T. Burganov, A. Gubaidullin, T. Gryaznova, O. Sinyashin, L. Xu, D. A. Vicic and Y. Budnikova, Dalton Trans., 2015, 44, 19674 DOI: 10.1039/C5DT03009A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements