Issue 10, 2014
From the journal:

Organic Chemistry Frontiers

Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts†‡

Gaoyuan Maa  and  Mukund P. Sibi*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58108, USA
E-mail: mukund.sibi@ndsu.edu

Abstract

We have investigated the asymmetric allylic amination of Morita–Baylis–Hillman (MBH) carbonates with nitrogen nucleophiles in the presence of newly designed chiral DMAP catalysts. A series of α-methylene β-amino esters were obtained with good yield and selectivities.

Graphical abstract: Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

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Article information

DOI
https://doi.org/10.1039/C4QO00210E
Article type
Research Article
Submitted
26 7 2014
Accepted
09 9 2014
First published
10 9 2014

Org. Chem. Front., 2014,1, 1152-1156

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Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

G. Ma and M. P. Sibi, Org. Chem. Front., 2014, 1, 1152 DOI: 10.1039/C4QO00210E

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