Issue 6, 2010

Gold(i)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

Abstract

1,6-Enynes can be transformed into vinylidenecyclopentanes via gold-promoted 5-exo dig cyclisation followed by 1,5-hydride or -alkoxide shift.

Graphical abstract: Gold(i)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

Supplementary files

Article information

Article type
Communication
Submitted
16 9 2009
Accepted
17 12 2009
First published
07 1 2010

Chem. Commun., 2010,46, 865-867

Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

Y. Harrak, A. Simonneau, M. Malacria, V. Gandon and L. Fensterbank, Chem. Commun., 2010, 46, 865 DOI: 10.1039/B919240A

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