Issue 2, 2010

Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

Abstract

Silver(I) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96–99% ee; one substrate with 91% ee) without subsequent racemization.

Graphical abstract: Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

Supplementary files

Article information

Article type
Communication
Submitted
20 7 2009
Accepted
04 9 2009
First published
16 9 2009

Chem. Commun., 2010,46, 213-215

Silver(I)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

V. K. Lo, C. Zhou, M. Wong and C. Che, Chem. Commun., 2010, 46, 213 DOI: 10.1039/B914516H

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