Issue 16, 2007

Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility

Abstract

The development of alkali-metal amidinate reagents, in particular formamidinates, has proceeded hand-in-hand with fundamental advances in transition-metal bonding, e.g. metal–metal bonding, and the progressive departure from cyclopentadienyl support ligands in early transition-metal catalysis. This highly personalised account highlights the coordinative versatility of one alkali-metal amidinate subclass; the bis(aryl)formamidinates. These compounds have proven invaluable during transition-metal studies but were considered unworthy of investigation in their own right prior to our work.

Graphical abstract: Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility

Article information

Article type
Feature Article
Submitted
26 9 2006
Accepted
22 11 2006
First published
05 1 2007

Chem. Commun., 2007, 1579-1590

Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility

P. C. Junk and M. L. Cole, Chem. Commun., 2007, 1579 DOI: 10.1039/B613984A

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