Issue 59, 2024

A three-component hydrogen bonded framework

Abstract

A porous three-component hydrogen bonded framework, 1⋅biphen⋅TP, was prepared from a tetra-amidinium component (14+) and two different dianions, benzene-1,4-dicarboxylate (terephthalate, TP2−) and biphenyl-4,4′-dicarboxylate (biphen2−). Interestingly, when the framework was prepared in ethanol/water, 1⋅biphen⋅TP forms even when an excess of either dicarboxylate is present. However, when only water is used as solvent, only two-component frameworks are formed.

Graphical abstract: A three-component hydrogen bonded framework

Supplementary files

Article information

Article type
Communication
Submitted
10 5 2024
Accepted
25 6 2024
First published
04 7 2024

Chem. Commun., 2024,60, 7582-7585

A three-component hydrogen bonded framework

P. Muang-Non, M. K. S. Perry-Britton, L. K. Macreadie and N. G. White, Chem. Commun., 2024, 60, 7582 DOI: 10.1039/D4CC02265C

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