Issue 78, 2022

Unravelling the synthesis of a rare-earth cluster-based metal–organic framework with spn topology

Abstract

Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality material. Y-CU-45 shows high crystallinity and surface area, shining light on the potential for rare-earth cluster-based MOFs with open metal sites.

Graphical abstract: Unravelling the synthesis of a rare-earth cluster-based metal–organic framework with spn topology

Supplementary files

Article information

Article type
Communication
Submitted
27 6 2022
Accepted
25 8 2022
First published
26 8 2022

Chem. Commun., 2022,58, 10925-10928

Unravelling the synthesis of a rare-earth cluster-based metal–organic framework with spn topology

H. A. Bicalho, F. Saraci, J. D. J. Velazquez-Garcia, H. M. Titi and A. J. Howarth, Chem. Commun., 2022, 58, 10925 DOI: 10.1039/D2CC03575H

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