Issue 67, 2022

Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

Abstract

The cubic SBU Ni8X6L6 (X = OH/H2O, L = ligand) is of great interest due to its stability and potential applications when integrated in MOFs. Here, we investigate by detailed DRIFTS measurements and exchange reactions whether it is found to be neutral in MOFs, as previously assumed in the literature, or whether it can show anionic character, as observed in complexes.

Graphical abstract: Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

Supplementary files

Article information

Article type
Communication
Submitted
30 5 2022
Accepted
26 7 2022
First published
26 7 2022

Chem. Commun., 2022,58, 9349-9352

Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

R. Freund, A. Kalytta-Mewes, M. Kraft and D. Volkmer, Chem. Commun., 2022, 58, 9349 DOI: 10.1039/D2CC03016K

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