Issue 50, 2018

Ambiphilic geometrically constrained phosphenium cation

Abstract

In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.

Graphical abstract: Ambiphilic geometrically constrained phosphenium cation

Supplementary files

Article information

Article type
Communication
Submitted
26 3 2018
Accepted
28 5 2018
First published
28 5 2018

Chem. Commun., 2018,54, 6931-6934

Ambiphilic geometrically constrained phosphenium cation

S. Volodarsky and R. Dobrovetsky, Chem. Commun., 2018, 54, 6931 DOI: 10.1039/C8CC02423E

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