Coherent manipulation of spin qubits based on polyoxometalates: the case of the single ion magnet [GdW30P5O110]14−

José J. Baldoví; Salvador Cardona-Serra; Juan M. Clemente-Juan; Eugenio Coronado; Alejandro Gaita-Ariño; Helena Prima-García

doi:10.1039/C3CC44838J

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Coherent manipulation of spin qubits based on polyoxometalates: the case of the single ion magnet [GdW₃₀P₅O₁₁₀]¹⁴⁻†

José J. Baldoví,^a Salvador Cardona-Serra,^a Juan M. Clemente-Juan,^a Eugenio Coronado,*^a Alejandro Gaita-Ariño^a and Helena Prima-García*^a

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* Corresponding authors

^a Instituto de Ciencia Molecular, University of Valencia, c/Cat. José Beltrán, Paterna, Spain

Abstract

Polyoxometalate single ion magnet [GdW₃₀P₅O₁₁₀]¹⁴⁻ (1) has been studied by generalized Rabi oscillation experiments. It was possible to increase the number of coherent rotations tenfold through matching the Rabi frequency with the frequency of the proton. Achieving high coherence with polyoxometalate chemistry, we show its excellent potential not only for the storage of quantum information but even for the realization of quantum algorithms.

This article is part of the themed collection: Molecular Spintronics

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Article information

DOI: https://doi.org/10.1039/C3CC44838J
Article type: Communication
Submitted: 27 6 2013
Accepted: 31 7 2013
First published: 01 8 2013

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Chem. Commun., 2013,49, 8922-8924

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Coherent manipulation of spin qubits based on polyoxometalates: the case of the single ion magnet [GdW₃₀P₅O₁₁₀]¹⁴⁻

J. J. Baldoví, S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño and H. Prima-García, Chem. Commun., 2013, 49, 8922 DOI: 10.1039/C3CC44838J

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