Issue 18, 2012

Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

Abstract

Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.

Graphical abstract: Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

Supplementary files

Article information

Article type
Communication
Submitted
24 1 2012
Accepted
28 2 2012
First published
12 3 2012

Dalton Trans., 2012,41, 5458-5460

Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

A. F. Gross, E. Sherman and J. J. Vajo, Dalton Trans., 2012, 41, 5458 DOI: 10.1039/C2DT30174A

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