Deciphering the mechanism of hydrogen peroxide formation in ultrasound-mediated water-in-oil microdroplets

Xiaohu Zhou, Shutong Du, Wenjuan Zhang and Bo Zheng

Chem. Sci., 2025, 16, 6450
DOI: 10.1039/D4SC08098J

Spiers Memorial Lecture: Water at interfaces

Shane W. Devlin, Franky Bernal, Erika J. Riffe, Kevin R. Wilson and Richard J. Saykally

Faraday Discuss., 2024, 249, 9
DOI: 10.1039/D3FD00147D

Why do some metal ions spontaneously form nanoparticles in water microdroplets? Disentangling the contributions of the air–water interface and bulk redox chemistry

Muzzamil Ahmad Eatoo, Nimer Wehbe, Najeh Kharbatia, Xianrong Guo and Himanshu Mishra

Chem. Sci., 2025, 16, 1115
DOI: 10.1039/D4SC03217A

The emerging chemistry of self-electrified water interfaces

Fernando Galembeck, Leandra P. Santos, Thiago A. L. Burgo and Andre Galembeck

Chem. Soc. Rev., 2024, 53, 2578
DOI: 10.1039/D3CS00763D

Concluding remarks for Faraday Discussion on Water at Interfaces

Mischa Bonn

Faraday Discuss., 2024, 249, 521
DOI: 10.1039/D3FD00153A

Ten crucial unknowns in atmospheric chemistry in the cold

Thorsten Bartels-Rausch, Jessie Creamean, Jennie L. Thomas, Megan Willis and Paul Zieger

Faraday Discuss., 2025, 258, 10
DOI: 10.1039/D5FD00056D

Strategies for the synthesis of open vase-like microcapsule ordered arrays with transition metal oxyhydroxide walls and their possible practical applications

Valeri Tolstoy, Anastasia Golubeva, Tatyana Moskvina, Xinge Hu, Manzar Sohail, Xingda An and Le He

Nanoscale, 2025, 17, 23883
DOI: 10.1039/D5NR02646F

The role of analyte concentration in accelerated reaction rates in evaporating droplets

Casey J. Chen and Evan R. Williams

Chem. Sci., 2023, 14, 4704
DOI: 10.1039/D3SC00259D

Spontaneous oxidation of I− in water microdroplets and its atmospheric implications

Dong Xing, Xu Yuan, Chiyu Liang, Tianyun Jin, Shuquan Zhang and Xinxing Zhang

Chem. Commun., 2022, 58, 12447
DOI: 10.1039/D2CC04288F

Busting the myth of spontaneous formation of H2O2 at the air–water interface: contributions of the liquid–solid interface and dissolved oxygen exposed

Muzzamil Ahmad Eatoo and Himanshu Mishra

Chem. Sci., 2024, 15, 3093
DOI: 10.1039/D3SC06534K

Aggregation of molecules is controlled in microdroplets

Pallab Basuri, Jenifer Shantha Kumar, Keerthana Unni, Sujan Manna and Thalappil Pradeep

Chem. Commun., 2022, 58, 12657
DOI: 10.1039/D2CC04587G

Electric fields at hydrophobic water interfaces: spectroscopic evidence, physical origin, and implications on reactivity

Kwing Yeung Chan, Chenjie Zhuang, Vinh Gia Vuong, Naixin Qian, Xin Gao and Wei Min

Chem. Soc. Rev., 2026, 55, 336
DOI: 10.1039/D5CS00778J

In situ photocatalytic formation of carbon quantum dots from corn stover via interfacial hydrogen peroxide generation

Xuejing Kang, Qian Yang, Sean Xiang Tang, Zhe Chen, Samir Budhathoki, Ramhari Paneru, Soyoung Kim, Yan Bai, Qian Li, Zhongbing Chen, Alexander Goroncy, Richard N. Zare and Maohong Fan

Green Chem., 2026, 28, 6758
DOI: 10.1039/D5GC04545B

Disentangling reaction rate acceleration in microdroplets

Manuel F. Ruiz-López and Marilia T. C. Martins-Costa

Phys. Chem. Chem. Phys., 2022, 24, 29700
DOI: 10.1039/D2CP04998H

Tuning oxidative modification by a strong electric field using nanoESI of highly conductive solutions near the minimum flow rate

Zhongbao Han, Nozomu Omata, Takeshi Matsuda, Shoki Hishida, Shuuhei Takiguchi, Ryoki Komori, Riku Suzuki and Lee Chuin Chen

Chem. Sci., 2023, 14, 4506
DOI: 10.1039/D2SC07113D

Identifying the acidic or basic behavior of surface water: a QM/MM-MD study

Md Al Mamunur Rashid, Mofizur Rahman, Thamina Acter and Nizam Uddin

Phys. Chem. Chem. Phys., 2023, 25, 31194
DOI: 10.1039/D3CP02080K

Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study

Jhih-Hong Huang, Fuyi Zhang, Yan-Pin Shi, Jia-Rong Cai, Yu-Hsuan Chuang, Wei-Ping Hu, Yin-Yu Lee and Chia C. Wang

J. Phys. Chem. Lett., 2023, 14, 3765
DOI: 10.1021/acs.jpclett.3c00560

Calibrating the Oxidative Capacity of Microdroplets

Tirthick Majumder, Dmitry B. Eremin, Berk Delibas, Archishman Sarkar, ValeryV. Fokin and Jahan M. Dawlaty

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202414746

Catalyst-free production of hydrogen peroxide enabled by plasma-microdroplet-generated water radical cations

Xiaoping Zhang, Xiaoyun Wang, Liqun Cheng, Lijuan Liu, Jianchuan Liu, Jianhua Ding, Roman Balabin, Xinglei Zhang, Konstantin Chingin and Huanwen Chen

Chinese Chemical Letters, 2026, 112774
DOI: 10.1016/j.cclet.2026.112774

Nitrogen‐Doped Engineering in Covalent Organic Frameworks for Photocatalytic Synthesis of Hydrogen Peroxide†

Wenbo Dong, Zhiying Qin, Xiangyang Liu and Longyu Li

Chin. J. Chem., 2025, 43, 1504
DOI: 10.1002/cjoc.70009

Spontaneous Reduction-Induced Degradation of Viologen Compounds in Water Microdroplets and Its Inhibition by Host–Guest Complexation

Chu Gong, Danyang Li, Xilai Li, Dongmei Zhang, Dong Xing, Lingling Zhao, Xu Yuan and Xinxing Zhang

J. Am. Chem. Soc., 2022, 144, 3510
DOI: 10.1021/jacs.1c12028

Through-Space Electrochemiluminescence Reveals Bubble Forces at Remote Phase Boundaries

Brady R. Layman and Jeffrey E. Dick

J. Am. Chem. Soc., 2024, 146, 707
DOI: 10.1021/jacs.3c10505

Bicarbonate-Mediated Generation of H2O2, 1O2, and OH* at the Hydrophobic Gas–Water Interface and Its Underlying Mechanism

Chenying Wang, Sangyeon Lee and Vidhya Chakrapani

Langmuir, 2026, 42, 4518
DOI: 10.1021/acs.langmuir.5c05232

Probing solvation electrostatics at the air–water interface

Marilia T. C. Martins-Costa and Manuel F. Ruiz-López

Theor Chem Acc, 2023, 142
DOI: 10.1007/s00214-023-02969-y

Sprayed Water Microdroplets Are Able to Generate Hydrogen Peroxide Spontaneously

Masoud A. Mehrgardi, Mohammad Mofidfar and Richard N. Zare

J. Am. Chem. Soc., 2022, 144, 7606
DOI: 10.1021/jacs.2c02890

Spontaneous Formation of Hydrogen Peroxide in Water Microdroplets

Joseph P. Heindel, Hongxia Hao, R. Allen LaCour and Teresa Head-Gordon

J. Phys. Chem. Lett., 2022, 13, 10035
DOI: 10.1021/acs.jpclett.2c01721

Humidity drives spontaneous OH oxidation of organic particles

Maria Angelaki, D. James Donaldson, Sébastien Perrier, Matthieu Riva and Christian George

Sci. Adv., 2025, 11
DOI: 10.1126/sciadv.adx4507

Quantum dynamics study of photodissociation in phenol–water clusters

Barry P. Mant, Thierry Tran, Sandra Gómez, Léon L. E. Cigrang and Graham A. Worth

The Journal of Chemical Physics, 2026, 164
DOI: 10.1063/5.0314493

The Structure of Carbon Dioxide at the Air‐Water Interface and its Chemical Implications

Marilia T. C. Martins‐Costa and Manuel F. Ruiz‐López

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400825

Silica's role in plant abiotic stress tolerance: A redox buffer hypothesis

Nerya Zexer, Shula Blum, Itay Stav, Oshry Markovich and Rivka Elbaum

Plant Physiology and Biochemistry, 2025, 229, 110474
DOI: 10.1016/j.plaphy.2025.110474

The Role of Interfaces and Charge for Chemical Reactivity in Microdroplets

R. Allen LaCour, Joseph P. Heindel, Ruoqi Zhao and Teresa Head-Gordon

J. Am. Chem. Soc., 2025, 147, 6299
DOI: 10.1021/jacs.4c15493

An Alternative Explanation for Ions Put Forth as Evidence for Abundant Hydroxyl Radicals Formed Due to the Intrinsic Electric Field at the Surface of Water Droplets

Casey J. Chen and Evan R. Williams

Anal. Chem., 2025, 97, 17687
DOI: 10.1021/acs.analchem.5c02973

Dielectric barrier discharge plasma combined with peroxydisulfate for efficient regeneration of waste granular activated carbon: Enhancing micropore recovery

Dong Yoon Oh, Kien Tiek Wong, Seok Byum Jang, Jun Sup Lim, Junghyun Lim, Choe Earn Choong, Yeomin Yoon, Eun Ha Choi and Min Jang

Chemical Engineering Journal, 2025, 519, 165363
DOI: 10.1016/j.cej.2025.165363

The Effect of Electric Fields on Oxidization Processes at the Air‐Water Interface

Marilia T. C. Martins‐Costa and Manuel F. Ruiz‐López

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202418593

A review of H2O2 electrosynthesis by 2-electron ORR and 2-electron WOR: From catalysts to electrochemical cells

Erzhuo Zhao, Wendan Xue, Shuhan Qin, Yang Guo, Xin Xin, Huijiao Wang, Yinqiao Zhang and Sijin Zuo

Coordination Chemistry Reviews, 2025, 545, 217042
DOI: 10.1016/j.ccr.2025.217042

Water Reactivity in Electrified Interfaces: The Simultaneous Production of Electricity, Hydrogen, and Hydrogen Peroxide at Room Temperature

Leandra P. Santos, Diana Lermen, Rafael Galiza Yoshimura, Bruno Leuzinger da Silva, André Galembeck, Thiago A. L. Burgo and Fernando Galembeck

Langmuir, 2023, 39, 5840
DOI: 10.1021/acs.langmuir.3c00186

Generation and transfer of long lifetime reactive oxygen species (ROSs) from electrochemical regulation

Tong Zhang, Yuehua Liu, Yuhui Wang, Zhi Wang, Junhao Liu and Xuzhong Gong

Chemical Engineering Journal, 2023, 464, 142443
DOI: 10.1016/j.cej.2023.142443

Unveiling the Role of Seawater Microdroplets in Accelerating Steel Corrosion

Yang Shen, Yuhao Hu, Jinyan Du, Junchang Guo, Zhenxu Shi, Jianing Song, Tao Zhong, Haoze Yuan, Zhengrong Lin, Dehui Wang and Xu Deng

J. Am. Chem. Soc., 2026, 148, 12717
DOI: 10.1021/jacs.5c20003

Activated hydrogen-promoted self-generation of H2O2 and reduction of Fe(III) mediated by Pd-based catalysts: A green Fenton-like process

Yijun Chen, Meina Cheng, Hailiang Yang, Sanjian Ma, Long Jin, Zixia Lin and Xin Liu

Sustainable Materials and Technologies, 2024, 41, e01098
DOI: 10.1016/j.susmat.2024.e01098

Mitigating soil nitrification and greenhouse gas emissions in non-paddy cropping systems by micro-molar hydrogen peroxide

Kaiqing Fan, Udara Piyathilake, Yunji Wang, Jun Wei Lim, Chuxia Lin, Junhao Qin and Rongliang Qiu

Science of The Total Environment, 2024, 953, 176102
DOI: 10.1016/j.scitotenv.2024.176102

A Critical Reappraisal of the Evidence for Spontaneous Generation of Hydroxyl Radicals in Aqueous Nanodroplets

Aidan G. Purcell and Ryan R. Julian

J. Am. Chem. Soc., 2026
DOI: 10.1021/jacs.5c21778

Spontaneous dark formation of OH radicals at the interface of aqueous atmospheric droplets

Kangwei Li, Yunlong Guo, Sergey A. Nizkorodov, Yinon Rudich, Maria Angelaki, Xinke Wang, Taicheng An, Sebastien Perrier and Christian George

Proc. Natl. Acad. Sci. U.S.A., 2023, 120
DOI: 10.1073/pnas.2220228120

Deciphering the Kinetics of Spontaneous Generation of H2O2 in Individual Water Microdroplets

Kai Zhou, Hua Su, Jia Gao, Haoran Li, Shasha Liu, Xuannuo Yi, Zhibing Zhang and Wei Wang

J. Am. Chem. Soc., 2024, 146, 2445
DOI: 10.1021/jacs.3c09864

Liquid Addition Techniques to Enhance Methane Biotrickling Filters at Dairy Barn Concentrations

Anna M. Pryor, Peter A. Gostomski and Carlo R. Carere

Clean Technol., 2025, 8, 3
DOI: 10.3390/cleantechnol8010003

Highly Sensitive Surface-Enhanced Raman Scattering Detection of Hydroxyl Radicals in Water Microdroplets Using Phthalhydrazide/Ag Nanoparticles Nanosensor

Shengmao Chao, Chiara Valsecchi, Ji Sun, Hong Shao, Xinxia Li, Changyu Tang and Meikun Fan

Environ. Sci. Technol., 2024, 58, 16497
DOI: 10.1021/acs.est.4c03081

Radical surface chemistry: Augmentation of reactivity by radicals at aqueous interfaces

Kurt W. Kolasinski

Surface Science Reports, 2025, 80, 100668
DOI: 10.1016/j.surfrep.2025.100668

Electrostatics, Hydration, and Chemical Equilibria at Charged Monolayers on Water

Kenneth D. Judd, Sean W. Parsons, Tirthick Majumder and Jahan M. Dawlaty

Chem. Rev., 2025, 125, 2440
DOI: 10.1021/acs.chemrev.4c00676

Capture of Hydroxyl Radicals by Hydronium Cations in Water Microdroplets

Dong Xing, Yifan Meng, Xu Yuan, Shuihui Jin, Xiaowei Song, Richard N. Zare and Xinxing Zhang

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202207587

Revisiting the Effect of the Air–Water Interface of Ultrasonically Atomized Water Microdroplets on H2O2 Formation

Duy Nguyen and Son C. Nguyen

J. Phys. Chem. B, 2022, 126, 3180
DOI: 10.1021/acs.jpcb.2c01310

Chemical Kinetics in Microdroplets

Kevin R. Wilson and Alexander M. Prophet

Annual Review of Physical Chemistry, 2024, 75, 185
DOI: 10.1146/annurev-physchem-052623-120718

Fragmentation engineering on the edge of hydroxy-functional COFs for the enhanced photocatalytic production of H2O2 and direct photo-oxidation of benzene to phenol in aqueous systems

Shijian Zhou, Yuexin Shi, Guangyuan Chen, Weiguo Kong, Hao Hu, Haoran Xie, Changlai Li, Jinping Qin, Zewu Zhang, Luming Peng, Xiaokang Ke and Yan Kong

Chemical Engineering Journal, 2023, 477, 146946
DOI: 10.1016/j.cej.2023.146946

Calibrating the Oxidative Capacity of Microdroplets

Tirthick Majumder, Dmitry B. Eremin, Berk Delibas, Archishman Sarkar, ValeryV. Fokin and Jahan M. Dawlaty

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202414746

Unexpected Generation of Singlet Oxygen at the Air–Water Interface of Aqueous Microdroplets

Feifei Li, Jitao Lv, Anen He, Jin Xu, Lixia Zhao, Xianwei Wang, Li Mao, Shasha Li, Hailin Wang, Yawei Wang and Guibin Jiang

J. Am. Chem. Soc., 2025, 147, 30574
DOI: 10.1021/jacs.5c02431

Dissolved Oxygen Redox as the Source of Hydrogen Peroxide and Hydroxyl Radical in Sonicated Emulsive Water Microdroplets

Abdelilah Asserghine, Aravind Baby, Jeanne N’Diaye, Adolfo I. B. Romo, Supriya Das, Chloe A. Litts, Prashant K. Jain and Joaquín Rodríguez-López

J. Am. Chem. Soc., 2025, 147, 11851
DOI: 10.1021/jacs.4c16759

Spontaneous Production of H2O2 at the Liquid–Ice Interface: A Potential Source of Atmospheric Oxidants

Junwei Song, Laura Werner, Yoan Carreira Mendes Da Silva, Alexander Theis, D. James Donaldson and Christian George

Environ. Sci. Technol., 2024, 58, 22691
DOI: 10.1021/acs.est.4c07546

Reevaluating Anomalous Electric Fields at the Air–Water Interface: A Surface-Specific Spectroscopic Survey

Joseph C. Shirley, Zi Xuan Ng, Kuo-Yang Chiang, Yuki Nagata, Yair Litman, Arsh S. Hazrah and Mischa Bonn

J. Am. Chem. Soc., 2025, 147, 46163
DOI: 10.1021/jacs.5c14541

A Source of the Mysterious m/z 36 Ions Identified: Implications for the Stability of Water and Unusual Chemistry in Microdroplets

Casey J. Chen and Evan R. Williams

ACS Cent. Sci., 2025, 11, 622
DOI: 10.1021/acscentsci.5c00306

Charged Water Microdroplets Enable Dissociation of Surrounding Dioxygen

Jian Zhou, Qing Wang, Gongkui Cheng, Wei Shen, Richard N. Zare and Xiaoyan Sun

J. Am. Chem. Soc., 2025, 147, 10916
DOI: 10.1021/jacs.4c12740

Unexpected Spontaneous Photochemical Formation of Hydrogen Peroxide in Water Microdroplets on Silicate Mineral Surfaces

Haoran Yu, Longgang Chu, Zhaoyue Sun, Ruobing Wang, Xinghao Wang, Juan Gao, Davide Vione, Bing Wu, Hongqiang Ren, Joseph S. Francisco and Cheng Gu

Angewandte Chemie, 2026
DOI: 10.1002/ange.9633132

Predicting droplet detachment force: Young-Dupré Model Fails, Young-Laplace Model Prevails

Muhammad Subkhi Sadullah, Yinfeng Xu, Sankara Arunachalam and Himanshu Mishra

Commun Phys, 2024, 7
DOI: 10.1038/s42005-024-01582-0

Microdroplet Chemistry with Unactivated Droplets

Huan Chen, Xiaoxu Li, Bowen Li, Yeye Chen, Haoran Ouyang, Youcun Li and Xinxing Zhang

J. Am. Chem. Soc., 2025, 147, 11399
DOI: 10.1021/jacs.5c01072

A Fluorogenic Reaction for Monitoring Cross-Coupling with Turn-On Ratio Greater than a Hundred Thousand

Rachel V. Czerwinski, Benjamin A. Brewster, Sunil P. Upadhyay, Andrew C. Cavell, Veronica K. Krasecki, Mackinsey A. Smith, Jeffrey Bartz and Randall H. Goldsmith

Chemical & Biomedical Imaging, 2026, 4, 199
DOI: 10.1021/cbmi.5c00103

Water-Microdroplet-Driven Interface-Charged Chemistries

Xiuquan Jia, Jianhan Wu and Feng Wang

JACS Au, 2024, 4, 4141
DOI: 10.1021/jacsau.4c00804

Understanding and Preventing the Spontaneous Gelation of Thiol-Norbornene Hydrogels

Ayan Dutta and William M. Gramlich

Biomacromolecules, 2025, 26, 4146
DOI: 10.1021/acs.biomac.5c00142

Ozone-coupled photocatalytic H2O2 synthesis via Mn/Ce bimetallic metal organic framework: synergistic catalysis and sacrificial agent-free efficiency

Guanqing Song, Chi Song, Gansheng Shi, Xiao Wang, Guanhong Lu, Lu Chen, Jing Sun and Xiaofeng Xie

Journal of Colloid and Interface Science, 2026, 702, 138801
DOI: 10.1016/j.jcis.2025.138801

Enabling Hypoxic Electroanalysis Using Dense Gases in a Fish Tank

Amber K. Wang, Patrick J. Herchenbach and Jeffrey E. Dick

ACS Electrochem., 2025, 1, 2878
DOI: 10.1021/acselectrochem.5c00339

Dual role of gas–water microbubbles as interfacial reactors and optically active scatterers for photochemical synthesis of hydrogen peroxide

Mohammad Reza Rezayat, Seyedeh Malahat Shadman, Masoud A. Mehrgardi and Richard N. Zare

Chemical Engineering Journal Advances, 2026, 26, 101198
DOI: 10.1016/j.ceja.2026.101198

Magneto‐hydrodynamic mixing: A new technique for preparing carbomer hydrogels

Maarten Houlleberghs, Loes Verheyden, Filip Voorspoels, C. Vinod Chandran, Karel Duerinckx, Sambhu Radhakrishnan, Johan A. Martens and Eric Breynaert

AIChE Journal, 2023, 69
DOI: 10.1002/aic.17911

Recent Achievements and Current Challenges Concerning Solvation Electrostatics at the Air–Water Interface

Marilia T. C. Martins‐Costa and Manuel F. Ruiz‐López

ChemPhysChem, 2026, 27
DOI: 10.1002/cphc.202500748

Electronic Excitation and High‐Energy Reactions Originate From Anionic Microdroplets Formed by Electrospray or Pneumatic Nebulization

Casey J. Chen, Veena S. Avadhani and Evan R. Williams

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202424662

Microdroplet-Assisted Sulfate Formation Incorporating Versatile Oxygen Sources

Xiang Sun, Wenbo You, Yu Wei, Hao Yan, Liwu Zhang and Huiming Bao

J. Am. Chem. Soc., 2026, 148, 16650
DOI: 10.1021/jacs.5c17911

Unexpected Spontaneous Generation of Superoxide Radicals: Water‐Solid Collision as an Atypical Source

Jin Xu, Chengzhuo Yu, Fengjie Chen, Feifei Li, Wanchao Yu, Silong Wang, Li Xiong, Fanglan Geng, Jitao Lv, Xianwei Wang, Lixia Zhao, Yawei Wang and Guibin Jiang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202511594

Direct electrochemical evidence suggests that aqueous microdroplets spontaneously produce hydrogen peroxide

Lynn E. Krushinski and Jeffrey E. Dick

Proc. Natl. Acad. Sci. U.S.A., 2024, 121
DOI: 10.1073/pnas.2321064121

Deconstructing the origins of interfacial catalysis: Why electric fields are inseparable from solvation

Solana Di Pino, Debarshi Banerjee, Marta Monti, Gonzalo Díaz Mirón, Giuseppe Cassone and Ali Hassanali

The Journal of Chemical Physics, 2025, 163
DOI: 10.1063/5.0288327

Detecting Early-Stage Intermediates of Free-Radical Oxidative Degradation in Charged Aqueous Microdroplets

Pallab Basuri and Dietrich A. Volmer

J. Phys. Chem. A, 2023, 127, 7612
DOI: 10.1021/acs.jpca.3c04143

An Iodide-Mediated Microdroplet for Efficient Ozone Decomposition

Bosheng Chen, Cheng Ni, Lin Ding, Lei Miao, Zhu Luo, Jinlong Wang and Yanbing Guo

J. Am. Chem. Soc., 2026, 148, 12684
DOI: 10.1021/jacs.5c19641

Catalyst-free Ullmann coupling in aqueous microdroplets

Ming-Yang Jia, Yue-Wen Zhou, Jun-Lei Yang, Qinlei Liu and Zhen-Feng Cai

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-62706-w

Capture of Hydroxyl Radicals by Hydronium Cations in Water Microdroplets

Dong Xing, Yifan Meng, Xu Yuan, Shuihui Jin, Xiaowei Song, Richard N. Zare and Xinxing Zhang

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202207587

Size Dependent Uncatalyzed Sulfite Oxidation in Aqueous Microdroplets

Kedong Gong, Sandhya Sethuraman, Adriane Tam, Zifeng Tang, V. Faye McNeill and Vicki H. Grassian

Environ. Sci. Technol., 2025, 59, 19932
DOI: 10.1021/acs.est.5c01509

Interfacial electrostatic charges promoted chemistry: Reactions and mechanisms

Qiangqiang Sun, Boran Xu, Jinyan Du, Yunlong Yu, Yujie Huang and Xu Deng

Advances in Colloid and Interface Science, 2025, 339, 103436
DOI: 10.1016/j.cis.2025.103436

Cavity-Enhanced Catalytic Array for Monitoring Spontaneous Catalytic Dynamics and Applications

Hui Zhu, Guocheng Fang, Po-Hao Tseng, Tian Zhou, Ningyuan Nie, Bowen Fu, Chang-Jie Mao, Dechen Jiang, Jun-Jie Zhu and Yu-Cheng Chen

Nano Lett., 2026, 26, 2907
DOI: 10.1021/acs.nanolett.5c06084

Zwitterions Layer at but Do Not Screen Electrified Interfaces

Muhammad Ghifari Ridwan, Buddha Ratna Shrestha, Nischal Maharjan and Himanshu Mishra

J. Phys. Chem. B, 2022, 126, 1852
DOI: 10.1021/acs.jpcb.1c10388

One-pot HPLC method for simultaneous quantification of hydrogen peroxide and organic peroxides

Alen Gabrič, Žiga Hodnik, Janez Ilaš and Stane Pajk

Microchemical Journal, 2025, 217, 114889
DOI: 10.1016/j.microc.2025.114889

Are Hydroxyl Radicals Spontaneously Generated in Unactivated Water Droplets?

Casey J. Chen and Evan R. Williams

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202407433

Facile Ozonation of Light Alkanes to Oxygenates with High Atom Economy in Tunable Condensed Phase at Ambient Temperature

Hongda Zhu, Timothy A. Jackson and Bala Subramaniam

JACS Au, 2023, 3, 498
DOI: 10.1021/jacsau.2c00631

Water–solid contact electrification causes hydrogen peroxide production from hydroxyl radical recombination in sprayed microdroplets

Bolei Chen, Yu Xia, Rongxiang He, Hongqian Sang, Wenchang Zhang, Juan Li, Lufeng Chen, Pu Wang, Shishang Guo, Yongguang Yin, Ligang Hu, Maoyong Song, Yong Liang, Yawei Wang, Guibin Jiang and Richard N. Zare

Proc. Natl. Acad. Sci. U.S.A., 2022, 119
DOI: 10.1073/pnas.2209056119

Liquid Crystal‐Driven Chemical Feeding Accelerates Condensation Reactions in Droplet Microreactors

Yang Xu, Alan H. Weible, Meng Zhang, Weichen Deng, Jen‐Chun Fang and Xiaoguang Wang

Advanced Science, 2025, 12
DOI: 10.1002/advs.202504133

Is the oxidative potential of components of fine particulate matter surface-mediated?

Karsten Baumann, Marco Wietzoreck, Pourya Shahpoury, Alexander Filippi, Stefanie Hildmann, Steven Lelieveld, Thomas Berkemeier, Haijie Tong, Ulrich Pöschl and Gerhard Lammel

Environ Sci Pollut Res, 2022, 30, 16749
DOI: 10.1007/s11356-022-24897-3

Pd/UiO‐66(Zr)‐2OH as a High‐Performance Catalyst for Hydrogen‐Enhanced Fenton Oxidation of Trimethoprim

Qin‐Qin Chen, Xin‐Hao Shen, Yun‐Dong Wang, Ying Gao, Feng Liu, Jian‐Hua Wu, Xiao‐Wen Wang, Long Jin, San‐Jian Ma, Juan‐Hong Li, Zi‐Xia Lin, Hong‐Wei Yang and Xin Liu

Applied Organom Chemis, 2025, 39
DOI: 10.1002/aoc.7872

Water Microdroplets in Air: A Hitherto Unnoticed Natural Source of Nitrogen Oxides

Anubhav Kumar, Veena Shankar Avadhani, Abhijit Nandy, Supratim Mondal, Barsha Pathak, Vinod Kumar Naidu Pavuluri, Madan Mohan Avulapati and Shibdas Banerjee

Anal. Chem., 2024, 96, 10515
DOI: 10.1021/acs.analchem.4c00371

The role of charge in microdroplet redox chemistry

Joseph P. Heindel, R. Allen LaCour and Teresa Head-Gordon

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-47879-0

Experimental Confirmation of H2O2 Adsorption at the Water–Air Interface

D. James Donaldson

J. Phys. Chem. A, 2022, 126, 5647
DOI: 10.1021/acs.jpca.2c04373

Constructing scalable hydrophobe–water micro-interfaces for catalyst-free generation of H2O2 via macroporous resins

Jia Gao, Kai Zhou, Xiangliang Guo, Kairong Yang, Shuying Yang, Hua Su, Zhibing Zhang and Wei Wang

Nat Commun, 2026, 17
DOI: 10.1038/s41467-026-69085-w

The Effect of Electric Fields on Oxidization Processes at the Air‐Water Interface

Marilia T. C. Martins‐Costa and Manuel F. Ruiz‐López

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202418593

Machine Learning Driven Advances in Molecular Dynamics of Bulk and Interfacial Aqueous Systems

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Chem. Rev., 2026, 126, 3730
DOI: 10.1021/acs.chemrev.5c00708

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ACS Sustainable Chem. Eng., 2022, 10, 8577
DOI: 10.1021/acssuschemeng.2c02070

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DOI: 10.1021/jacs.5c00347

Hydrogen-promoted oxygen reduction Fenton reaction system constructed by Pd/UiO-66(Zr) to efficiently degradate trimethoprim

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Journal of Water Process Engineering, 2024, 64, 105610
DOI: 10.1016/j.jwpe.2024.105610

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DOI: 10.1002/ange.202511594

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J. Phys. Chem. A, 2025, 129, 11414
DOI: 10.1021/acs.jpca.5c07004

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JGR Atmospheres, 2025, 130
DOI: 10.1029/2025JD044379

Ozone-Facilitated Formation of Uranyl Peroxide in Humid Conditions

Savannah E. Benjamin, Jay A. LaVerne, Ginger E. Sigmon and Peter C. Burns

Inorg. Chem., 2022, 61, 20977
DOI: 10.1021/acs.inorgchem.2c03454

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Lingqi Qiu and R. Graham Cooks

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202400118

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Journal of Cleaner Production, 2023, 420, 138444
DOI: 10.1016/j.jclepro.2023.138444

Electronic Excitation and High‐Energy Reactions Originate From Anionic Microdroplets Formed by Electrospray or Pneumatic Nebulization

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Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202424662

Quantification and Mechanistic Investigation of the Spontaneous H2O2 Generation at the Interfaces of Salt-Containing Aqueous Droplets

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DOI: 10.1021/jacs.3c14040

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Shiqi Wei, Qiongqiong Wan, Shibo Zhou, Wenjing Nie and Suming Chen

J. Am. Chem. Soc., 2024, 146, 32777
DOI: 10.1021/jacs.4c13013

Spontaneous Oxidation in Aqueous Microdroplets: Water Radical Cation as Primary Oxidizing Agent

Lingqi Qiu and R. Graham Cooks

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202400118

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DOI: 10.1002/nadc.20224126780

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Marilia T. C. Martins-Costa and Manuel F. Ruiz-López

J. Am. Chem. Soc., 2023, 145, 1400
DOI: 10.1021/jacs.2c12089

Modulation of Electric Field and Interface on Competitive Reaction Mechanisms

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J. Chem. Theory Comput., 2025, 21, 6584
DOI: 10.1021/acs.jctc.5c00705

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DOI: 10.1016/j.chemosphere.2024.143040

Interfacial Curvature, not Simply Size, Controls Spontaneous Hydrogen Peroxide Formation in Water Microdroplets

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DOI: 10.1021/jacs.5c11575

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Sci. Sin.-Chim, 2024, 54, 93
DOI: 10.1360/SSC-2023-0205

Unexpected Spontaneous Photochemical Formation of Hydrogen Peroxide in Water Microdroplets on Silicate Mineral Surfaces

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DOI: 10.1002/anie.9633132

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DOI: 10.1021/jacs.4c15514

Rainwater-Derived Reactive Oxygen Species Diminish Environmental Risk from Arsenic in Paddy Rice Systems

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Environ. Sci. Technol., 2025, 59, 7530
DOI: 10.1021/acs.est.5c00233

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DOI: 10.1021/jacs.4c17760

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DOI: 10.1021/jacs.5c05887

Experimental and Thermodynamic Viewpoints on Claims of a Spontaneous H2O2 Formation at the Air–Water Interface

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